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Effect of MAPP on Mechanical and Morphological Properties of Commercial NAFILean Polypropylene/Poppy (papaver somniferum) Stalks Polymer Composite

Year 2024, Volume: 12 Issue: 1, 17 - 24, 25.03.2024
https://doi.org/10.29109/gujsc.1367803

Abstract

In this study; poppy stalks collected from Afyonkarahisar/Sinanpaşa district were added to the polypropylene produced with the trade name NAFILean-PF2 555 (20% hemp added PP) at a rate of 20%. MAPP, which was added as a compatibility agent, was added at 5-10 and 15% ratios, mixed in a twin screw extruder and produced as granules. The effect of the addition of maleic anhydride grafted polypropylene (MAPP) at different rates on its mechanical and morphological properties was investigated. The granules obtained in the extruder were dried and the test samples were molded in the injection machine in accordance with the standards. In order to determine the mechanical values of the obtained polymer composite, modulus of elasticity, tensile strength, breaking strength, elongation at break, impact strength and hardness tests were carried out. In addition, photographs were taken with scanning electron microscopy (SEM) to determine the distribution of hemp and poppy stems. As a result of the analysis, with the addition of poppy stalks and MAPP in 20% hemp added PP (NAFILean-PF2 555); It was determined how the modulus of elasticity, tensile strength, breaking strength, elongation at break, impact strength and hardness values changed. As a result of SEM examination, it was determined that hemp and poppy particles were homogeneously dispersed.

Ethical Statement

Bu çalışmada etik ile ilgili bir durum yoktur.

References

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  • [11] Aslan Y., Albrechtsen Y., Taşdemir M., The effect of foaming on mechanical and morphological properties of polypropylene, Bitlis Eren University Journal of Science, 11(3) (2022) 784-790.
  • [12] Gümüş B.E., Yağcı Ö., Erdogan, C.D., Taşdemir M., Dynamical mechanical properties of polypropylene composites filled with olive pit particles, Journal of Testing and Evaluation, 47 (4), (2019).
  • [13] Küçüktüvek M., (2015) Alkaloid fabrikası katı atıklarından kompozit lenha üretim imkanlarının araştırılması, Doktora Tezi, Gazi Üniversitesi Fen Bilimleri Enstitüsü, Ankara
  • [14]https://arastirma.tarimorman.gov.tr/tokatarastirma/Belgeler/Lifletler/HA%C5%9EHA%C5%9E%20TARIMI.pdf [erişim: 2023]
  • [15] Teke Z., Sırtıkara M., Şahin K.A., Taşdemir M., The Investigation of the effects of carbonized and uncarbonized orange peel powder on the mechanical properties of polypropylene, The Int. Conference on Materials Science, Mechanical and Automotive Eng. and Tech., June 21-23 (2019) Cappadocia Türkiye.
  • [16] Ayrılmış N., Taşdemir M., Akbulut T., Water absorption and mechanical performance of PP/HIPS hybrid composites filled with wood flour, Polymer Composites, 38(5), (2017), 863-869.
  • [17] Ulutaş E., Taşdemir M., Koçak E.D., Investigation of mechanical properties of recycled polypropylene/rice huks polymer composite, The Int. Conference on Materials Science, Mechanical and Automotive Eng. and Tech., June 21-23 (2019), 49-53, Cappadocia Türkiye.
  • [18] Gümüş B.E., Yağcı Ö., Taşdemir M., High-density polyethylene/artichoke leaf powder polymer composites: dynamic mechanical, morphological and thermal properties, Iranian Polymer Journal, 31, (2022), 787-797.
  • [19] Billah M.M., Rabbi M.S., Hasan A., Injection molded discontinuous and continuous rattan fiber reinforced polypropylene composite: Development, experimental and analytical investigations, Results Mater., 13, (2022), 1-12.
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  • [21] Zaini M. J., Fuad M.Y.A., Ismail Z., Mansor M.S., Mustafah J., The effect of filler content and size on the mechanical properties of polypropylene/oil palm wood flour composites, Polymer, Int, 40(1), (1996), 51-55.
  • [22] Bengtsson, M., Oksman K., The use of silane technology in crosslinking polyethylene/wood flour Composites, Composites Part A: applied science and manufacturing, 37(5), (2006), 752-765.

Ticari NAFILean Polipropilen/Haşhaş (Papaver Somniferum) Sapı Polimer Kompozitinin Mekanik ve Morfolojik Özelliklerine MAPP’nin Etkisi

Year 2024, Volume: 12 Issue: 1, 17 - 24, 25.03.2024
https://doi.org/10.29109/gujsc.1367803

Abstract

Bu çalışmada; NAFILean-PF2 555 (%20 kenevir katkılı PP) ticari ismi ile üretilen polipropilene Afyonkarahisar/Sinanpaşa ilçesinden temin edilen haşhaş sapları %20 oranında katılmıştır. Uyumluluk maddesi olarak maleik anhidrit aşılı polipropilen (MAPP) %5-10 ve 15 oranlarında katılarak çift vidalı ekstruderde karıştırılmış ve granül halinde üretilmiştir. Mekanik ve morfolojik özelliklerine değişik oranlarda MAPP ilavesinin etkisi araştırılmıştır. Ekstrüzyon makinesinde elde edilen granüller kurutulmuş ve enjeksiyon makinesinde standartlara uygun şekilde test numuneleri basılmıştır. Elde edilen polimer kompozitinin mekanik değerlerinin belirlenmesi için elastiklik modülü, çekme mukavemeti, kopma mukavemeti, kopma uzaması, darbe mukavemeti ve sertlik testleri yapılmıştır. Ayrıca kenevir ve haşhaş saplarının dağılımlarını belirlemek için taramalı elektron mikroskobisi (SEM) ile fotoğrafları çekilmiştir. Analizler sonucunda %20 kenevir katkılı PP (NAFILean-PF2 555) içerisinde haşhaş ve MAPP ilavesiyle; elastiklik modülü, çekme mukavemeti, kopma mukavemeti, kopma uzaması, darbe mukavemeti ve sertlik değerlerinin nasıl değiştiği belirlenmiştir. SEM incelemesi sonucunda kenevir ve haşhaş partiküllerinin homojen dağıldığı tespit edilmiştir.

References

  • [1] Aguele F.O., Madufor C.I., Adekunle K.F., Comparative study of physical properties of polymer composites reinforced with uncarbonised and carbonised coir, Open Journal of Polymer Chemistry, 4(3), (2014), 73-82.
  • [2] Tholiya P., Deshmukh S.P., Property evaluation of hemp bagasse fiber composite- A review, International Journal of Engineering Applied Sciences and Technology, 6(1), (2021), 376-382.
  • [3] Kaştan A., Yalçın Y., Talaş Ş., Nano katkıların polimerlerin sürtünme katsayısına etkisi, Afyon Kocatepe Üniversitesi Fen ve Müh. Bilimleri Dergisi, 16 (2016) 231-243.
  • [4] Thakur V.K., Thakur M.K., Processing and characterization of natural cellulose fibers/thermoset polymer composites, Carbohydrate Polymers,109 (2014) 102–117.
  • [5] Mishra S., Mohanty A.K., Drzal L.T., Misra M., Parija S., Nayak S.K., Tripathy S.S. Studies on mechanical performance of biofibre/glass reinforced polyester hybrid composites, Composite Science Technolgy, 63 (2003) 1377–1385.
  • [6] Holbery J., Houston D., Natural-fibre-reinforced polymer composites in automotive applications, Journal of the Minerals Metals & Materials Society (JOM), 58 (2006) 80–86.
  • [7] Bodros E., Baley C., Study of the tensile properties of stinging nettle fibres, Materials Letters, 62(14) (2008) 2143-2145.
  • [8] Alam M.M., Ahmed, T., Haaque M.M., Gafur M.A., Kabir A.H., Mechanical properties of natural fiber containing polymer composites, Polymer-Plastics Technology and Engineering, 48(1) (2009) 110-113.
  • [9] Sui G., Fuqua, M.A., Ulven C.A., Zhong W.H., A plant fiber reinforced polymer composite prepared by a twin-screw extruder, Bioresource Technology, 100(3) (2009) 1246-1251.
  • [10] Joshi S.V., Drzal L.T., Mohanty A.K., Arora S., Are natural fiber composites environmentally superior to glass fiber reinforced composites ?, Composites Part A: Applied Science and Manufacturing, 35(3) (2004) 371-376.
  • [11] Aslan Y., Albrechtsen Y., Taşdemir M., The effect of foaming on mechanical and morphological properties of polypropylene, Bitlis Eren University Journal of Science, 11(3) (2022) 784-790.
  • [12] Gümüş B.E., Yağcı Ö., Erdogan, C.D., Taşdemir M., Dynamical mechanical properties of polypropylene composites filled with olive pit particles, Journal of Testing and Evaluation, 47 (4), (2019).
  • [13] Küçüktüvek M., (2015) Alkaloid fabrikası katı atıklarından kompozit lenha üretim imkanlarının araştırılması, Doktora Tezi, Gazi Üniversitesi Fen Bilimleri Enstitüsü, Ankara
  • [14]https://arastirma.tarimorman.gov.tr/tokatarastirma/Belgeler/Lifletler/HA%C5%9EHA%C5%9E%20TARIMI.pdf [erişim: 2023]
  • [15] Teke Z., Sırtıkara M., Şahin K.A., Taşdemir M., The Investigation of the effects of carbonized and uncarbonized orange peel powder on the mechanical properties of polypropylene, The Int. Conference on Materials Science, Mechanical and Automotive Eng. and Tech., June 21-23 (2019) Cappadocia Türkiye.
  • [16] Ayrılmış N., Taşdemir M., Akbulut T., Water absorption and mechanical performance of PP/HIPS hybrid composites filled with wood flour, Polymer Composites, 38(5), (2017), 863-869.
  • [17] Ulutaş E., Taşdemir M., Koçak E.D., Investigation of mechanical properties of recycled polypropylene/rice huks polymer composite, The Int. Conference on Materials Science, Mechanical and Automotive Eng. and Tech., June 21-23 (2019), 49-53, Cappadocia Türkiye.
  • [18] Gümüş B.E., Yağcı Ö., Taşdemir M., High-density polyethylene/artichoke leaf powder polymer composites: dynamic mechanical, morphological and thermal properties, Iranian Polymer Journal, 31, (2022), 787-797.
  • [19] Billah M.M., Rabbi M.S., Hasan A., Injection molded discontinuous and continuous rattan fiber reinforced polypropylene composite: Development, experimental and analytical investigations, Results Mater., 13, (2022), 1-12.
  • [20] Zulkifli N.I., Samat N., Anuar H., Zainuddin N., Mechanical properties and failure modes of recycled polypropylene/microcrystalline cellulose composites, Mater. Des. 69, (2015), 114-123.
  • [21] Zaini M. J., Fuad M.Y.A., Ismail Z., Mansor M.S., Mustafah J., The effect of filler content and size on the mechanical properties of polypropylene/oil palm wood flour composites, Polymer, Int, 40(1), (1996), 51-55.
  • [22] Bengtsson, M., Oksman K., The use of silane technology in crosslinking polyethylene/wood flour Composites, Composites Part A: applied science and manufacturing, 37(5), (2006), 752-765.
There are 22 citations in total.

Details

Primary Language Turkish
Subjects Polymers and Plastics
Journal Section Tasarım ve Teknoloji
Authors

Gizem Karadirek 0000-0003-0272-5825

Münir Taşdemir 0000-0001-8635-7251

Early Pub Date December 26, 2023
Publication Date March 25, 2024
Submission Date September 28, 2023
Published in Issue Year 2024 Volume: 12 Issue: 1

Cite

APA Karadirek, G., & Taşdemir, M. (2024). Ticari NAFILean Polipropilen/Haşhaş (Papaver Somniferum) Sapı Polimer Kompozitinin Mekanik ve Morfolojik Özelliklerine MAPP’nin Etkisi. Gazi University Journal of Science Part C: Design and Technology, 12(1), 17-24. https://doi.org/10.29109/gujsc.1367803

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