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FOSFAT VE SİLİKAT KAPLANMIŞ ÇİNKONUN KOROZYONUNA ANİLİN VE Ce+3’ÜN ETKİSİ

Year 2017, Volume: 12 Issue: 3, 158 - 167, 07.07.2017

Abstract

Bu çalışmada, fosfat (disodyum fosfat, SP) ve silikat (disodyum silikat, SS) iyonları ile ön işlem yapılmış saf çinkonun klorür
ortamındaki korozyonuna anilin ve Ce3+’ün etkisi araştırılmıştır.
Fosfat ve silikat kaplanmış çinko, Ce3+ ile etkileştirilip ve
oksalat+anilin çözeltisinde dönüşümlü voltametri alındıktan sonra sodyum klorür
ortamındaki korozyonu potansiyelin zamanla değişimi (OCP), AC-empedans (EIS) ve
akım-potansiyel eğrileri alınarak incelenmiştir. Silikat üzerine yüksek
derişimli seryum
kaplama çinkonun korozyon hızının daha düşük
olduğunu ve çinko metalini korozyondan daha fazla koruduğunu (%99) göstermiştir.

References

  • 1. Tallman, D.E., Spinks, G., Dominis, A., and Wallace, G.G., (2002). Electroactive Conducting Polymers for Corrosion Control. Part 1. General Introduction and A Review of Non-Ferrous Metals, Journal of Solid State Electrochemistry, Volume:6, pp:73-84.
  • 2. Karpakam, V., Kamaraj, K., Sathiyanarayanan, S., Venkatachari, G., and Ramu, S., (2011). Electrosynthesis of Polyaniline-Molybdate Coating on Steel and its Corrosion Protection Performance, Electrochimica Acta, Volume:56, pp:2165−2173.
  • 3. Gupta, G., Birbilis, N., Cook, A.B., and Khanna, A.S., (2013). Polyaniline-Lignosulfonate/Epoxy Coating for Corrosion Protection of AA2024-T3, Corrosion Science, Volume:67, pp:256−267.
  • 4. Hosseini, M.G., Sabouri, M., and Shahrabi, T., (2007). Corosion Protection of Mild Steel by Polypyrole Phosphate Composite Coating, Progress in Organic Coatings, Volume:60, pp:178−185.
  • 5. Kamaraj, K., Karpakam, V., Sathiyanarayanan, S., Syed Azim, S., and Venkatachari, G., (2011). Synthesis of Tungstate Doped Polyaniline and its Usefulness in Corrosion Protective Coatings, Electrochimica Acta, Volume:56, pp:9262−9268.
  • 6. Tan, Y. and Ghandi, K., (2013). Kinetics and Mechanism of Pyrrole Chemical Polymerization, Synthetic Metals, Volume:175, pp:183–191.
  • 7. Ateh, D.D., Navsaria, H.A., and Vadgama, P., (2006). Polypyrrole-Based Conducting Polymers and Interactions with Biological Tissues, Journal of The Royal Society Interface, Volume:3(11), pp:741–752.
  • 8. Maksymiuk, K., (2006). Chemical Reactivity of Polypyrrole and its Relevance to Polypyrrole Based Electrochemical Sensors, Electroanalysis, Volume:18, pp:1537–1551.
  • 9. Ansari, R., (2006). Polypyrrole Conducting Electroactive Polymers: Synthesis and Stability Studies, European Journal of Chemistry, Volume:3, pp:186–201.
  • 10. Vernitskaya, T.V. and Efimov, O.N., (1997). Polypyrrole: A Conducting Polymer; its Synthesis, Properties and Applications, Russian Chemical Reviews, Volume:66(5), pp:443–454.
  • 11. Troch-Nagels, G., Winand, R., Weymeersch, A., and Renard, L., (1992). Electron Conducting Organic Coating of Mild Steel by Electropolymerization, Journal Applied Electrochemistry, Volume:22(8), pp:756-764.
  • 12. Wessling, B., (1994). Passivation of Metals by Coating with Polyaniline: Corrosion Potential Shift and Morphological Changes, Advanced Materials, Volume:6, pp:226-228.
  • 13. Lu, W.K., Elsenbaumer, R.L., and Wessling, B., (1995). Corrosion Protection of Mild Steel by Coatings Containing Polyaniline, Synthetic Metals, Volume:71(1-13), pp:2163.
  • 14. Camalet, J.L., Lacroix, J.C., Aeiyach, S., Chaneching, K., and Lacaze, P.C., (1996). Electrodeposition of Protective PolyanilineFilms on Mild-Steel, Journal of Electroanalytical Chemisty, Volume:416, pp:179-182.
  • 15. Camalet, J.L., Lacroix, J.C., Aeiyach, S., Chaneching, K., and Lacaze, P.C., (1998). Electrosynthesis of Adherent Polyaniline Films on Iron and Mild-Steel Aqueous Oxalic-Acid Medium, Synthetic Metals, Volume:93(2), pp:133-142.
  • 16. Camalet, J.L., Lacroix, J.C., Aeiyach, S., and Lacaze, P.C., (1998). Characterization of Polyaniline Films Electrodeposited on Mild-Steel in Aqueous P-Toluenesulfonic Acid-Solution, Journal of Electroanalytical Chemistry, Volume:445, pp:117-124.
  • 17. Cachia, J.N., Deschanels, X., Den Auwer, Pinet, O., Phalippou, J., Hennig, C., and Scheinost, A., (2006). Enhancing Cerium and Plutonium Solubility by Reduction in Borosilicate Glass, Journal of Nuclear Materials, Volume:352(1-3), pp:182–189.
  • 18. Bolat, E., Yanardağ, T., Küyükoğlu, M., and Aksüt, A.A., (2012). Corrosion of Magnesium Modified with Different Compounds in Cloride Solution, Protection of Metals and Physical Chemistry of Surfaces, Volume:48(2), pp:259-264.
  • 19. Yanardağ, T. and Aksüt, A.A., (2012). Effect of Conversion Coatings and Oxalate ion on Corrosion of Pure Zinc in 1M NaCl Solution, Asian Journal of Chemistry, Volume:24(1), pp:345-349.
  • 20. Topaktaş, M., Yanardağ, T., and Aksüt, A.A., (2008). Inhibiton Effects of Co+2, Ni+2,La+3 and Ce+3 ions on The corrosion of Aluminium and aluminium Alloys in the NaCl Solution, Communuciation Faculty Science University Ankara Series B, Volume:54(1), pp:1-13.
  • 21. Zaid, B., Aeiyach, S., Lacaze, P.C., and Takenouti, H., (1998). A Two-Step Electropolymerisation of Pyrrole on Zn in Aqueous Media, Electrochimica Acta, Volume:43(16-17), pp:2331-2339.
  • 22. Paliwoda-Porebsaka, G., Stratmann, M., Rohwerder, M., Rammelt, U., Minh Duc, L., and Pleith, W., (2006). Release Mechanism of Electrodeposited Polypyrrole Doped with Corrosion Inhibitor Anions, Journal of Solid State Electrochemistry, Volume:10(9), pp:730-736. 23. Mouanga, M., Berçot, P., and Rauch, J.Y., (2010). Comparison of Corrosion Behaviour of Zinc in NaCl and in NaOH Solutions. Part I: Corrosion Layer Characterization, Corrosion Science, Volume:52, 3984-3992.
  • 24. D’Alkaline, C.V. and Boucherit, M.N., (1997). Potentiostatic Growth of ZnO on Zn: Application of an Ohmic Model, Journal of Electrochemical Society, Volume:144(10), pp:3331-3336.
  • 25. Peulon, S. and Lincot, D., (1998). Mechanistic Study of Cathodic Elecfrodeposition of Zinc Oxide and Zinc Hydroxychioride Films from Oxygenated Aqueous Zinc Chloride Solutions, Journal of Electrochemical Society, Volume:145(3), pp:864-874.
  • 26. Kazanskii, L.P., Sokolova, E.M., and Pronin, Y.E., (2013). Adsorption of 1,2,3-Benzotriazole on Zinc Surface from Phosphate Solution, Protection of Metals and Physical Chemistry of Surfaces, Volume:49(7), pp:844–853.
Year 2017, Volume: 12 Issue: 3, 158 - 167, 07.07.2017

Abstract

References

  • 1. Tallman, D.E., Spinks, G., Dominis, A., and Wallace, G.G., (2002). Electroactive Conducting Polymers for Corrosion Control. Part 1. General Introduction and A Review of Non-Ferrous Metals, Journal of Solid State Electrochemistry, Volume:6, pp:73-84.
  • 2. Karpakam, V., Kamaraj, K., Sathiyanarayanan, S., Venkatachari, G., and Ramu, S., (2011). Electrosynthesis of Polyaniline-Molybdate Coating on Steel and its Corrosion Protection Performance, Electrochimica Acta, Volume:56, pp:2165−2173.
  • 3. Gupta, G., Birbilis, N., Cook, A.B., and Khanna, A.S., (2013). Polyaniline-Lignosulfonate/Epoxy Coating for Corrosion Protection of AA2024-T3, Corrosion Science, Volume:67, pp:256−267.
  • 4. Hosseini, M.G., Sabouri, M., and Shahrabi, T., (2007). Corosion Protection of Mild Steel by Polypyrole Phosphate Composite Coating, Progress in Organic Coatings, Volume:60, pp:178−185.
  • 5. Kamaraj, K., Karpakam, V., Sathiyanarayanan, S., Syed Azim, S., and Venkatachari, G., (2011). Synthesis of Tungstate Doped Polyaniline and its Usefulness in Corrosion Protective Coatings, Electrochimica Acta, Volume:56, pp:9262−9268.
  • 6. Tan, Y. and Ghandi, K., (2013). Kinetics and Mechanism of Pyrrole Chemical Polymerization, Synthetic Metals, Volume:175, pp:183–191.
  • 7. Ateh, D.D., Navsaria, H.A., and Vadgama, P., (2006). Polypyrrole-Based Conducting Polymers and Interactions with Biological Tissues, Journal of The Royal Society Interface, Volume:3(11), pp:741–752.
  • 8. Maksymiuk, K., (2006). Chemical Reactivity of Polypyrrole and its Relevance to Polypyrrole Based Electrochemical Sensors, Electroanalysis, Volume:18, pp:1537–1551.
  • 9. Ansari, R., (2006). Polypyrrole Conducting Electroactive Polymers: Synthesis and Stability Studies, European Journal of Chemistry, Volume:3, pp:186–201.
  • 10. Vernitskaya, T.V. and Efimov, O.N., (1997). Polypyrrole: A Conducting Polymer; its Synthesis, Properties and Applications, Russian Chemical Reviews, Volume:66(5), pp:443–454.
  • 11. Troch-Nagels, G., Winand, R., Weymeersch, A., and Renard, L., (1992). Electron Conducting Organic Coating of Mild Steel by Electropolymerization, Journal Applied Electrochemistry, Volume:22(8), pp:756-764.
  • 12. Wessling, B., (1994). Passivation of Metals by Coating with Polyaniline: Corrosion Potential Shift and Morphological Changes, Advanced Materials, Volume:6, pp:226-228.
  • 13. Lu, W.K., Elsenbaumer, R.L., and Wessling, B., (1995). Corrosion Protection of Mild Steel by Coatings Containing Polyaniline, Synthetic Metals, Volume:71(1-13), pp:2163.
  • 14. Camalet, J.L., Lacroix, J.C., Aeiyach, S., Chaneching, K., and Lacaze, P.C., (1996). Electrodeposition of Protective PolyanilineFilms on Mild-Steel, Journal of Electroanalytical Chemisty, Volume:416, pp:179-182.
  • 15. Camalet, J.L., Lacroix, J.C., Aeiyach, S., Chaneching, K., and Lacaze, P.C., (1998). Electrosynthesis of Adherent Polyaniline Films on Iron and Mild-Steel Aqueous Oxalic-Acid Medium, Synthetic Metals, Volume:93(2), pp:133-142.
  • 16. Camalet, J.L., Lacroix, J.C., Aeiyach, S., and Lacaze, P.C., (1998). Characterization of Polyaniline Films Electrodeposited on Mild-Steel in Aqueous P-Toluenesulfonic Acid-Solution, Journal of Electroanalytical Chemistry, Volume:445, pp:117-124.
  • 17. Cachia, J.N., Deschanels, X., Den Auwer, Pinet, O., Phalippou, J., Hennig, C., and Scheinost, A., (2006). Enhancing Cerium and Plutonium Solubility by Reduction in Borosilicate Glass, Journal of Nuclear Materials, Volume:352(1-3), pp:182–189.
  • 18. Bolat, E., Yanardağ, T., Küyükoğlu, M., and Aksüt, A.A., (2012). Corrosion of Magnesium Modified with Different Compounds in Cloride Solution, Protection of Metals and Physical Chemistry of Surfaces, Volume:48(2), pp:259-264.
  • 19. Yanardağ, T. and Aksüt, A.A., (2012). Effect of Conversion Coatings and Oxalate ion on Corrosion of Pure Zinc in 1M NaCl Solution, Asian Journal of Chemistry, Volume:24(1), pp:345-349.
  • 20. Topaktaş, M., Yanardağ, T., and Aksüt, A.A., (2008). Inhibiton Effects of Co+2, Ni+2,La+3 and Ce+3 ions on The corrosion of Aluminium and aluminium Alloys in the NaCl Solution, Communuciation Faculty Science University Ankara Series B, Volume:54(1), pp:1-13.
  • 21. Zaid, B., Aeiyach, S., Lacaze, P.C., and Takenouti, H., (1998). A Two-Step Electropolymerisation of Pyrrole on Zn in Aqueous Media, Electrochimica Acta, Volume:43(16-17), pp:2331-2339.
  • 22. Paliwoda-Porebsaka, G., Stratmann, M., Rohwerder, M., Rammelt, U., Minh Duc, L., and Pleith, W., (2006). Release Mechanism of Electrodeposited Polypyrrole Doped with Corrosion Inhibitor Anions, Journal of Solid State Electrochemistry, Volume:10(9), pp:730-736. 23. Mouanga, M., Berçot, P., and Rauch, J.Y., (2010). Comparison of Corrosion Behaviour of Zinc in NaCl and in NaOH Solutions. Part I: Corrosion Layer Characterization, Corrosion Science, Volume:52, 3984-3992.
  • 24. D’Alkaline, C.V. and Boucherit, M.N., (1997). Potentiostatic Growth of ZnO on Zn: Application of an Ohmic Model, Journal of Electrochemical Society, Volume:144(10), pp:3331-3336.
  • 25. Peulon, S. and Lincot, D., (1998). Mechanistic Study of Cathodic Elecfrodeposition of Zinc Oxide and Zinc Hydroxychioride Films from Oxygenated Aqueous Zinc Chloride Solutions, Journal of Electrochemical Society, Volume:145(3), pp:864-874.
  • 26. Kazanskii, L.P., Sokolova, E.M., and Pronin, Y.E., (2013). Adsorption of 1,2,3-Benzotriazole on Zinc Surface from Phosphate Solution, Protection of Metals and Physical Chemistry of Surfaces, Volume:49(7), pp:844–853.
There are 25 citations in total.

Details

Subjects Engineering
Journal Section Articles
Authors

DERYA Altuğ This is me

TURAN Yanardağ

ALİ ABBAS Aksüt

Publication Date July 7, 2017
Published in Issue Year 2017 Volume: 12 Issue: 3

Cite

APA Altuğ, D., Yanardağ, T., & Aksüt, A. A. (2017). FOSFAT VE SİLİKAT KAPLANMIŞ ÇİNKONUN KOROZYONUNA ANİLİN VE Ce+3’ÜN ETKİSİ. Engineering Sciences, 12(3), 158-167.
AMA Altuğ D, Yanardağ T, Aksüt AA. FOSFAT VE SİLİKAT KAPLANMIŞ ÇİNKONUN KOROZYONUNA ANİLİN VE Ce+3’ÜN ETKİSİ. Engineering Sciences. July 2017;12(3):158-167.
Chicago Altuğ, DERYA, TURAN Yanardağ, and ALİ ABBAS Aksüt. “FOSFAT VE SİLİKAT KAPLANMIŞ ÇİNKONUN KOROZYONUNA ANİLİN VE Ce+3’ÜN ETKİSİ”. Engineering Sciences 12, no. 3 (July 2017): 158-67.
EndNote Altuğ D, Yanardağ T, Aksüt AA (July 1, 2017) FOSFAT VE SİLİKAT KAPLANMIŞ ÇİNKONUN KOROZYONUNA ANİLİN VE Ce+3’ÜN ETKİSİ. Engineering Sciences 12 3 158–167.
IEEE D. Altuğ, T. Yanardağ, and A. A. Aksüt, “FOSFAT VE SİLİKAT KAPLANMIŞ ÇİNKONUN KOROZYONUNA ANİLİN VE Ce+3’ÜN ETKİSİ”, Engineering Sciences, vol. 12, no. 3, pp. 158–167, 2017.
ISNAD Altuğ, DERYA et al. “FOSFAT VE SİLİKAT KAPLANMIŞ ÇİNKONUN KOROZYONUNA ANİLİN VE Ce+3’ÜN ETKİSİ”. Engineering Sciences 12/3 (July 2017), 158-167.
JAMA Altuğ D, Yanardağ T, Aksüt AA. FOSFAT VE SİLİKAT KAPLANMIŞ ÇİNKONUN KOROZYONUNA ANİLİN VE Ce+3’ÜN ETKİSİ. Engineering Sciences. 2017;12:158–167.
MLA Altuğ, DERYA et al. “FOSFAT VE SİLİKAT KAPLANMIŞ ÇİNKONUN KOROZYONUNA ANİLİN VE Ce+3’ÜN ETKİSİ”. Engineering Sciences, vol. 12, no. 3, 2017, pp. 158-67.
Vancouver Altuğ D, Yanardağ T, Aksüt AA. FOSFAT VE SİLİKAT KAPLANMIŞ ÇİNKONUN KOROZYONUNA ANİLİN VE Ce+3’ÜN ETKİSİ. Engineering Sciences. 2017;12(3):158-67.