Farklı Anamateryaller Üzerinde Oluşmuş Toprakların Cu, Pb ve Zn İçeriklerinin Belirlenmesi (Çanakkale, Türkiye)

Year 2024, Volume: 11 Issue: 1, 216 - 225, 28.01.2024

Erdem Temel Timuçin Everest Ali Sungur Hasan Özcan

https://doi.org/10.30910/turkjans.1326951

Abstract

Bu çalışma, Çanakkale ili Ezine ilçesinde üç farklı anamateryal (bazalt, kireçli ve karbonatlı kayaçlar ve granit) üzerinde oluşan topraklardaki ağır metal (Cu, Pb ve Zn) içeriklerini ve bunların farklılıklarını ortaya koymak için yapılmıştır. Bu amaçla, farklı jeolojik materyaller üzerinde doğal ortam koşullarında oluşmuş topraklarda yüzey örneklemesi yapılmıştır. Örneklerin ağır metal içerikleri Aqua regia yaş yakma yöntemi kullanılarak alevli atomik absorpsiyon spektrometresi ile belirlenmiştir Toprak örneklerinde elementler arası farklılaşmayı belirlemek için varyans analizi (ANOVA) kullanılmıştır. Farklı anamateryaller üzerinde oluşmuş topraklardan alınan örneklerin ağır metal ve fiziko-kimyasal özellikleri arasındaki ilişkiyi ortaya koymak için Pearson korelasyon analizi uygulanmıştır. Değerlendirme neticesinde, örneklerdeki ortalama Cu konsantrasyonları bazalt üzerinde oluşmuş topraklar (40.8 ± 3.8 μg/g)> kireçli ve karbonatlı kayaçlar üzerinde oluşmuş topraklar (24.8 ± 1.5 μg/g)> granit üzerinde oluşmuş topraklar (22.5 ± 2.8 μg/g) sıralamasını; ortalama Pb konsantrasyonları granit üzerinde oluşmuş topraklar (37.50 ± 3.30 μg/g)> kireçli ve karbonatlı kayaçlar üzerinde oluşmuş topraklar (35.67 ± 2.74 μg/g)> bazalt üzerinde oluşmuş topraklar (21.6 ± 6.7 μg/g) sıralamasını izlemiştir. Toprak örneklerinin ortalama Zn konsantrasyonları ise bazalt üzerinde oluşmuş topraklar (80.9 ± 8.7 μg/g)> kireçli ve karbonatlı kayaçlar üzerinde oluşmuş topraklar (44.1 ± 3.7 μg/g)> granit üzerinde oluşmuş topraklar (37.0 ± 9.4 μg/g) olarak belirlenmiştir. Tüm toprak örneklerinin Pb konsantrasyonlarının, yer kabuğu ortalamasından daha yüksek olduğu tespit edilmiştir.

Keywords

Ağır metal, kireçli ve karbonatlı kayaçlar, granit, bazalt

Determination of Cu, Pb, and Zn Contents of Soils Formed on Different Parent Materials (Çanakkale, Türkiye)

Abstract

This study was carried out to determine the heavy metal (Cu, Pb, and Zn) contents and their differences in soils formed on three different parent materials (basalt, clastic and carbonate rocks and granite) in the Ezine district of Çanakkale province. For this purpose, surface sampling was conducted in soils formed under natural conditions on different geological materials. Heavy metal contents of the soil samples were determined using flame atomic absorption spectrometry using the wet digestion Aqua regia method. Analysis of variance (ANOVA) was used to determine the elemental differences in soil samples. Pearson correlation analysis was applied to reveal the relationship between heavy metals and the physicochemical properties of soils taken from different parent materials. As a result of the evaluation, the mean Cu concentrations in the samples ranged from soils formed on basalt (40.8 ± 3.8 μg/g)> soils formed on clastic and carbonate rocks (24.8 ± 1.5 μg/g)> soils formed on granite (22.5 ± 2. 8 μg/g); mean Pb concentrations followed the order of soils formed on granite (37.50 ± 3.30 μg/g)> soils formed on clastic and carbonate rocks (35.67 ± 2.74 μg/g)> soils formed on basalt (21.6 ± 6.7 μg/g). The mean Zn concentrations of the soil samples were as follows: soils formed on basalt (80.9 ± 8.7 μg/g)> soils formed on clastic and carbonate rocks (44.1 ± 3.7 μg/g)> soils formed on granite (37.0 ± 9.4 μg/g). Pb concentrations of all soil samples were found to be higher than the average of the earth's crust.

Keywords

Heavy metals, clastic and carbonate rocks, granite, basalt

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