Araştırma Makalesi
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Çift Kür Olabilen Hidrofob Kaplamaların Mekanik, Yüzey ve Termal Özelliklerinin İncelenmesi

Yıl 2018, Cilt: 30 Sayı: 3, 260 - 268, 30.09.2018
https://doi.org/10.7240/marufbd.439105

Öz

Önemli
kaplama teknolojilerinden biri olan ultraviyole (UV) ışıkla sertleştirme
yöntemi, artan uygulama alanları ve diğer yöntemlere kıyasla var olan
avantajları ile birlikte her geçen gün daha fazla tercih edilmektedir. Bu
makalede, bir izosiyanat akrilat olan ICA (Laromer® LR 9000) reçinesi ile
monoetilen glikol (MEG), dietilen glikol (DEG) ve dialkol ile sonlandırılmış
perfloropolieter türevi olan floro alkol (Fluorolink® E10-H) içeren reçine
sistemleri kullanılarak kaplamalar hazırlanmıştır. Bu reçine sistemlerinin ısı
ve UV ile sertleştirilmesi sonucunda farklı oranlarda flor içeren serbest
filmler elde edilmiş ve ayrıca alüminyum levhalar üzerine de bu formülasyonlar
kaplama yapılmıştır. Elde edilen serbest filmlerin; çekme testi, termogravimetrik
analiz (TGA) ve diferansiyel taramalı kalorimetre (DSC) yardımıyla mekanik ve
termal özellikleri belirlenmiştir. Ayrıca alüminyum levha üzerine yapılan
kaplamaların özellikleri ise; kalem sertlik testi, çapraz kesme testi,
parlaklık testi ve temas açısı testi ile gözlemlenmiştir. Sonuçlar
incelendiğinde hidrofobik ve parlak bir kaplama elde edildiği görülmüştür.
Ayrıca farklı oranlarda eklenen floro alkolün monoetilen glikol içeren yapı ile
dietilen glikol içeren yapının mekanik özelliklerinde farklı etkiler yarattığı
tespit edilmiştir. 

Kaynakça

  • [1] Chattopadhyay, D. K., Panda, S. S., & Raju, K. V. S. N. (2005). Thermal and mechanical properties of epoxy acrylate/methacrylates UV cured coatings. Progress in Organic Coatings, 54(1), 10-19.
  • [2] Yan, R., Yang, D., Zhang, N., Zhao, Q., Liu, B., Xiang, W., ... & Hu, W. (2018). Performance of UV curable lignin based epoxy acrylate coatings. Progress in Organic Coatings, 116, 83-89.
  • [3] Chen, X., Hu, Y., Song, L., & Jiao, C. (2008). Preparation and thermal properties of a novel UV‐cured star polyurethane acrylate coating. Polymers for Advanced Technologies, 19(4), 322-327.
  • [4] Park, C. H., Lee, S. W., Park, J. W., & Kim, H. J. (2013). Preparation and characterization of dual curable adhesives containing epoxy and acrylate functionalities. Reactive and Functional Polymers, 73(4), 641-646.
  • [5] Shen, L., Li, Y., Zheng, J., Lu, M., & Wu, K. (2015). Modified epoxy acrylate resin for photocurable temporary protective coatings. Progress in Organic Coatings, 89, 17-25.
  • [6] Decker, C. (2002). Kinetic study and new applications of UV radiation curing. Macromolecular Rapid Communications, 23(18), 1067-1093.
  • [7] Velankar, S., Pazos, J., & Cooper, S. L. (1996). High-performance UV-curable urethane acrylates via deblocking chemistry. Journal of applied polymer science, 62(9), 1361-1376.
  • [8] Park, Y. J., Lim, D. H., Kim, H. J., Park, D. S., & Sung, I. K. (2009). UV-and thermal-curing behaviors of dual-curable adhesives based on epoxy acrylate oligomers. International Journal of Adhesion and Adhesives, 29(7), 710-717.
  • [9] Zhang, J. Y., Windall, G., & Boyd, I. W. (2002). UV curing of optical fibre coatings using excimer lamps. Applied surface science, 186(1-4), 568-572.
  • [10] Studer, K., Decker, C., Beck, E., & Schwalm, R. (2005). Thermal and photochemical curing of isocyanate and acrylate functionalized oligomers. European polymer journal, 41(1), 157-167.
  • [11] Decker, C., Masson, F., & Schwalm, R. (2003). Dual‐Curing of Waterborne Urethane‐Acrylate Coatings by UV and Thermal Processing. Macromolecular Materials and Engineering, 288(1), 17-28.
  • [12] Jung, T., Simmendinger, P., Studer, K., & Tobisch, W. (2006). Plasma technology: a solution for UV curing on 3-dimensional substrates.
  • [13] Fouassier, J. P., & Rabek, J. F. (Eds.). (1993). Radiation curing in polymer science and technology: Practical aspects and applications (Vol. 4). Springer Science & Business Media.
  • [14] Li, T. X., & Chen, F. (2015). Study of Organic Fluorine Modified Epoxy Acrylic Cathodic Electrodeposition Coatings. In Applied Mechanics and Materials (Vol. 722, pp. 30-33). Trans Tech Publications.
  • [15] Bongiovanni, R., Di Meo, A., Pollicino, A., Priola, A., & Tonelli, C. (2008). New perfluoropolyether urethane methacrylates as surface modifiers: Effect of molecular weight and end group structure. Reactive and Functional Polymers, 68(1), 189-200.
  • [16] Bongiovanni, R., Medici, A., Zompatori, A., Garavaglia, S., & Tonelli, C. (2012). Perfluoropolyether polymers by UV curing: design, synthesis and characterization. Polymer International, 61(1), 65-73.
  • [17] Jeon, J. H., Park, Y. G., Lee, Y. H., Lee, D. J., & Kim, H. D. (2015). Preparation and properties of UV‐curable fluorinated polyurethane acrylates containing crosslinkable vinyl methacrylate for antifouling coatings. Journal of Applied Polymer Science, 132(26).
  • [18] Wu, J., Zhang, R., Ma, G., Hou, C., & Zhang, H. (2017). Preparation and properties of fluorinated oligomer with tertiary amine structure in the UV curable coatings. Journal of Applied Polymer Science, 134(2).
  • [19] Studer, K., Decker, C., Beck, E., & Schwalm, R. (2005). Thermal and photochemical curing of isocyanate and acrylate functionalized oligomers. European polymer journal, 41(1), 157-167.
  • [20] Lei, H., He, D., Guo, Y., Tang, Y., & Huang, H. (2018). Synthesis and characterization of UV-absorbing fluorine-silicone acrylic resin polymer. Applied Surface Science, 442, 71-77.
  • [21] Çakır, M. (2017). Investigation of Coating Performance of UV-Curable Hybrid Polymers Containing 1H, 1H, 2H, 2H-Perfluorooctyltriethoxysilane Coated on Aluminum Substrates. Coatings, 7(3), 37.

Investigation of Mechanical, Surface and Thermal Properties of Dual-Curable Hydrophobic Coatings

Yıl 2018, Cilt: 30 Sayı: 3, 260 - 268, 30.09.2018
https://doi.org/10.7240/marufbd.439105

Öz

One of the important
coating technologies, ultraviolet (UV) light curing, is increasingly preferred
with increasing application areas and advantages that are present compared to
other methods.
In this article, coatings were prepared
using ICA (Laromer® LR 9000) resin, an isocyanate acrylate resin, and resin
systems containing monoethylene glycol (MEG), diethylene glycol (DEG) and
fluoro alcohol (Fluorolink® E10-H), a perfluoropolyether derivative terminated
with dialkol.
As a result of
heat and UV curing of these resin systems, free films were obtained at
different ratios fluorine containing and these formulations were also coated on
aluminum sheets.
Obtained free films;
Mechanical and thermal properties were determined by tensile testing,
thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC).
Furthermore, the properties of the coatings coated on the aluminum sheet
determined by tests as pencil hardness test, cross-cut test, gloss test and
contact angle test.
When the results are
examined, it is seen that a hydrophobic and bright coating is obtained.

It
has also been found that fluoroalcohol added at different ratios has different
effects on the mechanical properties of the structure containing diethylene
glycol with the structure containing monoethylene glycol.

Kaynakça

  • [1] Chattopadhyay, D. K., Panda, S. S., & Raju, K. V. S. N. (2005). Thermal and mechanical properties of epoxy acrylate/methacrylates UV cured coatings. Progress in Organic Coatings, 54(1), 10-19.
  • [2] Yan, R., Yang, D., Zhang, N., Zhao, Q., Liu, B., Xiang, W., ... & Hu, W. (2018). Performance of UV curable lignin based epoxy acrylate coatings. Progress in Organic Coatings, 116, 83-89.
  • [3] Chen, X., Hu, Y., Song, L., & Jiao, C. (2008). Preparation and thermal properties of a novel UV‐cured star polyurethane acrylate coating. Polymers for Advanced Technologies, 19(4), 322-327.
  • [4] Park, C. H., Lee, S. W., Park, J. W., & Kim, H. J. (2013). Preparation and characterization of dual curable adhesives containing epoxy and acrylate functionalities. Reactive and Functional Polymers, 73(4), 641-646.
  • [5] Shen, L., Li, Y., Zheng, J., Lu, M., & Wu, K. (2015). Modified epoxy acrylate resin for photocurable temporary protective coatings. Progress in Organic Coatings, 89, 17-25.
  • [6] Decker, C. (2002). Kinetic study and new applications of UV radiation curing. Macromolecular Rapid Communications, 23(18), 1067-1093.
  • [7] Velankar, S., Pazos, J., & Cooper, S. L. (1996). High-performance UV-curable urethane acrylates via deblocking chemistry. Journal of applied polymer science, 62(9), 1361-1376.
  • [8] Park, Y. J., Lim, D. H., Kim, H. J., Park, D. S., & Sung, I. K. (2009). UV-and thermal-curing behaviors of dual-curable adhesives based on epoxy acrylate oligomers. International Journal of Adhesion and Adhesives, 29(7), 710-717.
  • [9] Zhang, J. Y., Windall, G., & Boyd, I. W. (2002). UV curing of optical fibre coatings using excimer lamps. Applied surface science, 186(1-4), 568-572.
  • [10] Studer, K., Decker, C., Beck, E., & Schwalm, R. (2005). Thermal and photochemical curing of isocyanate and acrylate functionalized oligomers. European polymer journal, 41(1), 157-167.
  • [11] Decker, C., Masson, F., & Schwalm, R. (2003). Dual‐Curing of Waterborne Urethane‐Acrylate Coatings by UV and Thermal Processing. Macromolecular Materials and Engineering, 288(1), 17-28.
  • [12] Jung, T., Simmendinger, P., Studer, K., & Tobisch, W. (2006). Plasma technology: a solution for UV curing on 3-dimensional substrates.
  • [13] Fouassier, J. P., & Rabek, J. F. (Eds.). (1993). Radiation curing in polymer science and technology: Practical aspects and applications (Vol. 4). Springer Science & Business Media.
  • [14] Li, T. X., & Chen, F. (2015). Study of Organic Fluorine Modified Epoxy Acrylic Cathodic Electrodeposition Coatings. In Applied Mechanics and Materials (Vol. 722, pp. 30-33). Trans Tech Publications.
  • [15] Bongiovanni, R., Di Meo, A., Pollicino, A., Priola, A., & Tonelli, C. (2008). New perfluoropolyether urethane methacrylates as surface modifiers: Effect of molecular weight and end group structure. Reactive and Functional Polymers, 68(1), 189-200.
  • [16] Bongiovanni, R., Medici, A., Zompatori, A., Garavaglia, S., & Tonelli, C. (2012). Perfluoropolyether polymers by UV curing: design, synthesis and characterization. Polymer International, 61(1), 65-73.
  • [17] Jeon, J. H., Park, Y. G., Lee, Y. H., Lee, D. J., & Kim, H. D. (2015). Preparation and properties of UV‐curable fluorinated polyurethane acrylates containing crosslinkable vinyl methacrylate for antifouling coatings. Journal of Applied Polymer Science, 132(26).
  • [18] Wu, J., Zhang, R., Ma, G., Hou, C., & Zhang, H. (2017). Preparation and properties of fluorinated oligomer with tertiary amine structure in the UV curable coatings. Journal of Applied Polymer Science, 134(2).
  • [19] Studer, K., Decker, C., Beck, E., & Schwalm, R. (2005). Thermal and photochemical curing of isocyanate and acrylate functionalized oligomers. European polymer journal, 41(1), 157-167.
  • [20] Lei, H., He, D., Guo, Y., Tang, Y., & Huang, H. (2018). Synthesis and characterization of UV-absorbing fluorine-silicone acrylic resin polymer. Applied Surface Science, 442, 71-77.
  • [21] Çakır, M. (2017). Investigation of Coating Performance of UV-Curable Hybrid Polymers Containing 1H, 1H, 2H, 2H-Perfluorooctyltriethoxysilane Coated on Aluminum Substrates. Coatings, 7(3), 37.
Toplam 21 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Konular Mühendislik
Bölüm Araştırma Makaleleri
Yazarlar

Mustafa Çakır 0000-0002-9409-2684

Yayımlanma Tarihi 30 Eylül 2018
Kabul Tarihi 26 Eylül 2018
Yayımlandığı Sayı Yıl 2018 Cilt: 30 Sayı: 3

Kaynak Göster

APA Çakır, M. (2018). Çift Kür Olabilen Hidrofob Kaplamaların Mekanik, Yüzey ve Termal Özelliklerinin İncelenmesi. Marmara Fen Bilimleri Dergisi, 30(3), 260-268. https://doi.org/10.7240/marufbd.439105
AMA Çakır M. Çift Kür Olabilen Hidrofob Kaplamaların Mekanik, Yüzey ve Termal Özelliklerinin İncelenmesi. MFBD. Eylül 2018;30(3):260-268. doi:10.7240/marufbd.439105
Chicago Çakır, Mustafa. “Çift Kür Olabilen Hidrofob Kaplamaların Mekanik, Yüzey Ve Termal Özelliklerinin İncelenmesi”. Marmara Fen Bilimleri Dergisi 30, sy. 3 (Eylül 2018): 260-68. https://doi.org/10.7240/marufbd.439105.
EndNote Çakır M (01 Eylül 2018) Çift Kür Olabilen Hidrofob Kaplamaların Mekanik, Yüzey ve Termal Özelliklerinin İncelenmesi. Marmara Fen Bilimleri Dergisi 30 3 260–268.
IEEE M. Çakır, “Çift Kür Olabilen Hidrofob Kaplamaların Mekanik, Yüzey ve Termal Özelliklerinin İncelenmesi”, MFBD, c. 30, sy. 3, ss. 260–268, 2018, doi: 10.7240/marufbd.439105.
ISNAD Çakır, Mustafa. “Çift Kür Olabilen Hidrofob Kaplamaların Mekanik, Yüzey Ve Termal Özelliklerinin İncelenmesi”. Marmara Fen Bilimleri Dergisi 30/3 (Eylül 2018), 260-268. https://doi.org/10.7240/marufbd.439105.
JAMA Çakır M. Çift Kür Olabilen Hidrofob Kaplamaların Mekanik, Yüzey ve Termal Özelliklerinin İncelenmesi. MFBD. 2018;30:260–268.
MLA Çakır, Mustafa. “Çift Kür Olabilen Hidrofob Kaplamaların Mekanik, Yüzey Ve Termal Özelliklerinin İncelenmesi”. Marmara Fen Bilimleri Dergisi, c. 30, sy. 3, 2018, ss. 260-8, doi:10.7240/marufbd.439105.
Vancouver Çakır M. Çift Kür Olabilen Hidrofob Kaplamaların Mekanik, Yüzey ve Termal Özelliklerinin İncelenmesi. MFBD. 2018;30(3):260-8.

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