Everzol Yellow 3RS Boyar Maddesinin Gidya Üzerine Adsorpsiyonu: Kinetik ve İzoterm Çalışmaları

Yıl 2024, Cilt: 14 Sayı: 1, 194 - 210, 15.03.2024

Fulya Aydın Temel

https://doi.org/10.31466/kfbd.1374988

Öz

Bu çalışmada, Gidya kullanılarak Everzol Yellow 3RS boyar maddesinin adsorpsiyon prosesi ile giderimi araştırılmıştır. Adsorpsiyon sürecine pH’ın (3–11), temas süresinin (5–300 dakika), adsorban dozunun (2–16 g/L), başlangıç konsantrasyonunun (10-50 mg/L) ve sıcaklığın (25-60°C) etkisi incelenmiştir. Adsorpsiyon prosesinde 10 g/L adsorbent dozu, orijinal pH değeri, 90 dakika temas süresi, 10 mg/L boyar madde konsantrasyonu ve ortam sıcaklığı optimum maksimum giderim veriminin (%90.96) sağlandığı koşullar olarak belirlenmiştir. Gidya üzerindeki adsorpsiyon sürecinin mekanizmasını anlamak için kinetik ve denge modelleri uygulanmıştır. Kinetik ve izoterm deneylerinden elde edilen sonuçlara göre, Everzol Yellow 3RS boyar maddesinin Gidya üzerine adsorpsiyonu için adsorpsiyon kinetiği ikinci derece reaksiyon modeli modeli ile adsorpsiyon dengesi ise Freundlich izoterm modeli ile iyi bir şekilde tanımlanmıştır. Bu, hız sınırlayıcı adımın difüzyondan ziyade kemisorpsiyon olabileceği ve hem film difüzyonu hem de parçacık içi difüzyon süreçlerinin kayda değer olduğu anlamına gelmektedir. Ayrıca, adsorpsiyon mekanizmasının düzgün bir dağılım göstermediğini ve tek bir katmanla sınırlı olmadığını göstermiştir. Sonuç olarak, Gidya’nın potansiyel bir adsorbent olarak boyar madde gideriminde kullanılabilir olduğu görülmüştür.

Anahtar Kelimeler

Everzol Yellow 3RS, Gidya, Adsorpsiyon, Kinetik, İzoterm, Arıtım.

Etik Beyan

Yapılan çalışmada araştırma ve yayın etiğine uyulmuştur.

Destekleyen Kurum

Giresun Üniversitesi - Bilimsel Araştırma Projeleri Koordinasyon Birimi

Proje Numarası

FEN-BAP-A-250620-63

Teşekkür

Bu çalışma, Giresun Üniversitesi Bilimsel Araştırma Projeleri Koordinasyon Birimi (Proje FEN-BAP-A-250620-63) tarafından finanse edilmiştir. Araştırma olanağını sağladığı için Giresun Üniversitesi’ne teşekkür ediyorum.

Adsorption of Everzol Yellow 3RS dyestuff onto Gyttja: Kinetic and Isotherm Studies

Öz

In this study, the removal of Everzol Yellow 3RS dye by adsorption process was investigated by using Gyttja. The effects of pH (3–11), contact time (5–300 min), adsorbent dose (2–16 g/L), initial concentration (10–50 mg/L), and temperature (25–60°C) on the adsorption process were investigated. In the adsorption process, 10 g/L adsorbent dose, original pH value, 90 minutes contact time, 10 mg/L dye concentration, and ambient temperature were determined as the conditions where the maximum removal efficiency (90.96%) was achieved. To understand the mechanism of the adsorption process on Gyttja, kinetic and equilibrium models were applied. According to the results obtained from the kinetic and isotherm experiments, the adsorption kinetics for the adsorption of Everzol Yellow 3RS dye onto Gyttja were well described by the pseudo-second-order reaction model and the adsorption equilibrium by the Freundlich isotherm model. This means that the rate-limiting step may be chemisorption rather than diffusion, and both film diffusion and intra-particle diffusion processes are significant. It also showed that the adsorption mechanism is not uniformly distributed and is not limited to a single layer. As a result, it was observed that Gyttja can be used as a potential adsorbent in dyestuff removal.

Anahtar Kelimeler

Everzol Yellow 3RS, Gyttja, Adsorption, Kinetic, Isotherm, Treatment

Proje Numarası

FEN-BAP-A-250620-63

Kaynakça

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