Year 2017, Volume 18, Issue 5, Pages 973 - 987 2017-12-31

NOVEL CYCLOMATRIX-TYPE POLYPHOSPHAZENE MICROSPHERES CROSSLINKED WITH OCTACHLOROCYCLOTETRAPHOSPHAZENE: PREPARATION AND CHARACTERIZATION

Yasemin Süzen [1] , Simge Metinoğlu [2]

213 458

In this article, highly cross-linked inorganic and organic hybrid polyphosphazene microspheres including amino groups on the surface have been successfully obtained via self-assembly polycondensation approach using 4,4ʹ-diaminodiphenylmethane and octachlorocyclotetraphosphazene which is a new crosslinker. Experiments were performed without adding a surfactant or stabilizer, using only an ultrasonic bath. Otherwise, effect of different molar ratios of the reactants, reaction time and ultrasonic power were investigated on preparing morphologically good spheres. The reactivity of octachlorocyclotetraphosphazene was investigated comparing with hexachlorocyclotriphosphazene which is the most popular crosslinker cyclic phosphazene molecule. The size of acquired microspheres were approximately same, and 1.00μm. The novel microspheres were characterized by SEM, FTIR, ZETA, UV, Fluorescense, XRD and TGA.

Octachlorocyclotetraphosphazene, 4 4′-diaminodiphenylmethane, microspheres, self-assembly, polyphosphazene
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Subjects Engineering
Journal Section Articles
Authors

Author: Yasemin Süzen
Institution: ANADOLU ÜNİVERSİTESİ
Country: Turkey


Author: Simge Metinoğlu
Country: Turkey


Dates

Publication Date: December 31, 2017

Bibtex @research article { aubtda312012, journal = {ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY A - Applied Sciences and Engineering}, issn = {1302-3160}, eissn = {2146-0205}, address = {Eskişehir Teknik Üniversitesi}, year = {2017}, volume = {18}, pages = {973 - 987}, doi = {10.18038/aubtda.312012}, title = {NOVEL CYCLOMATRIX-TYPE POLYPHOSPHAZENE MICROSPHERES CROSSLINKED WITH OCTACHLOROCYCLOTETRAPHOSPHAZENE: PREPARATION AND CHARACTERIZATION}, key = {cite}, author = {Süzen, Yasemin and Metinoğlu, Simge} }
APA Süzen, Y , Metinoğlu, S . (2017). NOVEL CYCLOMATRIX-TYPE POLYPHOSPHAZENE MICROSPHERES CROSSLINKED WITH OCTACHLOROCYCLOTETRAPHOSPHAZENE: PREPARATION AND CHARACTERIZATION. ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY A - Applied Sciences and Engineering, 18 (5), 973-987. DOI: 10.18038/aubtda.312012
MLA Süzen, Y , Metinoğlu, S . "NOVEL CYCLOMATRIX-TYPE POLYPHOSPHAZENE MICROSPHERES CROSSLINKED WITH OCTACHLOROCYCLOTETRAPHOSPHAZENE: PREPARATION AND CHARACTERIZATION". ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY A - Applied Sciences and Engineering 18 (2017): 973-987 <http://dergipark.org.tr/aubtda/issue/31308/312012>
Chicago Süzen, Y , Metinoğlu, S . "NOVEL CYCLOMATRIX-TYPE POLYPHOSPHAZENE MICROSPHERES CROSSLINKED WITH OCTACHLOROCYCLOTETRAPHOSPHAZENE: PREPARATION AND CHARACTERIZATION". ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY A - Applied Sciences and Engineering 18 (2017): 973-987
RIS TY - JOUR T1 - NOVEL CYCLOMATRIX-TYPE POLYPHOSPHAZENE MICROSPHERES CROSSLINKED WITH OCTACHLOROCYCLOTETRAPHOSPHAZENE: PREPARATION AND CHARACTERIZATION AU - Yasemin Süzen , Simge Metinoğlu Y1 - 2017 PY - 2017 N1 - doi: 10.18038/aubtda.312012 DO - 10.18038/aubtda.312012 T2 - ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY A - Applied Sciences and Engineering JF - Journal JO - JOR SP - 973 EP - 987 VL - 18 IS - 5 SN - 1302-3160-2146-0205 M3 - doi: 10.18038/aubtda.312012 UR - https://doi.org/10.18038/aubtda.312012 Y2 - 2017 ER -
EndNote %0 ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY A - Applied Sciences and Engineering NOVEL CYCLOMATRIX-TYPE POLYPHOSPHAZENE MICROSPHERES CROSSLINKED WITH OCTACHLOROCYCLOTETRAPHOSPHAZENE: PREPARATION AND CHARACTERIZATION %A Yasemin Süzen , Simge Metinoğlu %T NOVEL CYCLOMATRIX-TYPE POLYPHOSPHAZENE MICROSPHERES CROSSLINKED WITH OCTACHLOROCYCLOTETRAPHOSPHAZENE: PREPARATION AND CHARACTERIZATION %D 2017 %J ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY A - Applied Sciences and Engineering %P 1302-3160-2146-0205 %V 18 %N 5 %R doi: 10.18038/aubtda.312012 %U 10.18038/aubtda.312012
ISNAD Süzen, Yasemin , Metinoğlu, Simge . "NOVEL CYCLOMATRIX-TYPE POLYPHOSPHAZENE MICROSPHERES CROSSLINKED WITH OCTACHLOROCYCLOTETRAPHOSPHAZENE: PREPARATION AND CHARACTERIZATION". ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY A - Applied Sciences and Engineering 18 / 5 (December 2018): 973-987. https://doi.org/10.18038/aubtda.312012
AMA Süzen Y , Metinoğlu S . NOVEL CYCLOMATRIX-TYPE POLYPHOSPHAZENE MICROSPHERES CROSSLINKED WITH OCTACHLOROCYCLOTETRAPHOSPHAZENE: PREPARATION AND CHARACTERIZATION. AUJST-A. 2017; 18(5): 973-987.
Vancouver Süzen Y , Metinoğlu S . NOVEL CYCLOMATRIX-TYPE POLYPHOSPHAZENE MICROSPHERES CROSSLINKED WITH OCTACHLOROCYCLOTETRAPHOSPHAZENE: PREPARATION AND CHARACTERIZATION. ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY A - Applied Sciences and Engineering. 2017; 18(5): 987-973.