Araştırma Makalesi
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COMPARISON OF SOLVOTHERMAL AND IONOTHERMAL METHODS ON CATALYTIC ACTIVITY OF MIL-53 (Fe)

Yıl 2017, Cilt: 18 Sayı: 5, 1107 - 1117, 18.12.2017
https://doi.org/10.18038/aubtda.328791

Öz

Iron based MIL-53 (Fe) was
synthesized by solvothermal and ionothermal methods. Then the synthesized
materials were sulfated to increase the acidic property. Characterization of
synthesized and sulfated materials were performed by FT-IR, BET, XRD and TGA
methods. The sulfated materials were used in esterification reaction of acetic
acid to test the catalytic activity. The effect of synthesis method on the
structure of MIL-53 (Fe) and also effects of temperature, time and sulfation of
samples on the conversion of acetic acid were studied. Also reusability of
sulfated samples was achieved by washing with pure water. In ionothermal
synthesis of iron based metal organic framework, deep eutectic solvent formed
by choline chloride and dimethyl urea was used as solvent.

Kaynakça

  • Reference 1 Millange F, Guillou N, Medina ME. Férey G, Carlin-Sinclair A, Golden KM, et al., Selective sorption of organic molecules by the flexible porous hybrid metal-organic framework MIL-53(Fe) controlled by various host-guest interactions, Chem Mater 2010; 22: 4237–4245.
  • Reference 2 Llewellyn PL, Horcajada P, Maurin G, Devic T, Rosenbach N, Bourrelly S, et al., Complex adsorption of short linear alkanes in the flexible metal-organic-framework MIL-53(Fe), J Am Chem Soc 2009; 131: 13002–13008.
  • Reference 3 Osta RE, Carlin-Sinclair A, Guillou N, Walton RI, Vermoortele F, Maes M, et al., Liquid-phase adsorption and separation of xylene isomers by the flexible porous metal-organic framework MIL-53(Fe), Chem Mater 2012; 24: 2781–2791.
  • Reference 4 Du JJ, Yuan YP, Sun JX, Peng FM, Jiang X, Qiu LG, et al., New photocatalysts based on MIL-53 metal-organic frameworks for the decolorization of methylene blue dye, J. Hazard. Mater. 2011, 190 945–951.
  • Reference 5 Lee YR, Kim J, Ahn WS, Synthesis of metal-organic frameworks: A mini review, Korean J Chem Eng 2013; 30:1667–1680.
  • Reference 6 Jhung SH, Lee,JH Yoon,JW, Serre C, Férey G, Chang JS, Microwave synthesis of chromium terephthalate MIL-101 and its benzene sorption ability, Adv Mater 2007; 19: 121–124.
  • Reference 7 Zhang Q, De Oliveira Vigier K, Royer S, Jérôme F, Deep eutectic solvents: syntheses, properties and applications, Chem Soc Rev 2012; 41: 7108.
  • Reference 8 Tan B, Xie ZL, Huang XY, Xiao XR, Ionothermal synthesis, crystal structure, and properties of an anionic two-dimensional cadmium metal organic framework based on paddle wheel-like cluster, Inorg Chem Commun 2011; 14: 1001–1003.
  • Reference 9 Nickerl G, Notzon A, Heitbaum M, Senkovska I, Glorius F, Kaskel S, Selective Adsorption Properties of Cationic Metal − Organic Frameworks Based on Imidazolic Linker, Cryst Growth Des 2013; 13: 198–203.
  • Reference 10 Parnham ER, Morris RE, Ionothermal synthesis of zeolites, metal-organic frameworks, and inorganic-organic hybrids, Acc Chem Res 2007; 40: 1005–1013.
  • Reference 11 Yusof R, Abdulmalek E, Sirat K, Rahman MBA, Tetrabutylammonium bromide (TBABr)-Based deep eutectic solvents (DESs) and their physical properties, Molecules 2014; 19: 8011–8026.
  • Reference 12 Abbott AP, Boothby D, Capper G, Davies DL, Rasheed RK, Deep Eutectic Solvents formed between choline chloride and carboxylic acids: Versatile alternatives to ionic liquids, J Am Chem Soc 2004; 126: 9142–9147.
  • Reference 13 Yılmaz E, Sert E, Atalay FS, Characterization of a metal organic framework : MIL-53(Fe) Synthesis and adsorption mechanisms of methyl red onto MIL-53 ( Fe ), J Taiwan Ins Chem Engineers 2016; 65: 323–330.
  • Reference 14 Goesten MG, Juan-Alcañiz J, Ramos-Fernandez EV, Sai Sankar Gupta KB, Stavitski E, Van Bekkum H, et al., Sulfation of metal-organic frameworks: Opportunities for acid catalysis and proton conductivity, J Catal 2011; 281: 177–187.
  • Reference 15 Combarieu GD, Morcrette M, Millange F, Guillou N, Cabana J, Grey CP, et al., Influence of the Benzoquinone sorption on the structure and electrochemical performance of the MIL-53 (Fe) hybrid porous material in a lithium-ion battery, Chem Mater 2009; 21: 1602–1611.
  • Reference 16 Xie L, Liu D, Huang H, Yang Q, Zhong C, Efficient capture of nitrobenzene from waste water using metal-organic frameworks, Chem Eng J 2014; 246: 142–149.
Yıl 2017, Cilt: 18 Sayı: 5, 1107 - 1117, 18.12.2017
https://doi.org/10.18038/aubtda.328791

Öz

Kaynakça

  • Reference 1 Millange F, Guillou N, Medina ME. Férey G, Carlin-Sinclair A, Golden KM, et al., Selective sorption of organic molecules by the flexible porous hybrid metal-organic framework MIL-53(Fe) controlled by various host-guest interactions, Chem Mater 2010; 22: 4237–4245.
  • Reference 2 Llewellyn PL, Horcajada P, Maurin G, Devic T, Rosenbach N, Bourrelly S, et al., Complex adsorption of short linear alkanes in the flexible metal-organic-framework MIL-53(Fe), J Am Chem Soc 2009; 131: 13002–13008.
  • Reference 3 Osta RE, Carlin-Sinclair A, Guillou N, Walton RI, Vermoortele F, Maes M, et al., Liquid-phase adsorption and separation of xylene isomers by the flexible porous metal-organic framework MIL-53(Fe), Chem Mater 2012; 24: 2781–2791.
  • Reference 4 Du JJ, Yuan YP, Sun JX, Peng FM, Jiang X, Qiu LG, et al., New photocatalysts based on MIL-53 metal-organic frameworks for the decolorization of methylene blue dye, J. Hazard. Mater. 2011, 190 945–951.
  • Reference 5 Lee YR, Kim J, Ahn WS, Synthesis of metal-organic frameworks: A mini review, Korean J Chem Eng 2013; 30:1667–1680.
  • Reference 6 Jhung SH, Lee,JH Yoon,JW, Serre C, Férey G, Chang JS, Microwave synthesis of chromium terephthalate MIL-101 and its benzene sorption ability, Adv Mater 2007; 19: 121–124.
  • Reference 7 Zhang Q, De Oliveira Vigier K, Royer S, Jérôme F, Deep eutectic solvents: syntheses, properties and applications, Chem Soc Rev 2012; 41: 7108.
  • Reference 8 Tan B, Xie ZL, Huang XY, Xiao XR, Ionothermal synthesis, crystal structure, and properties of an anionic two-dimensional cadmium metal organic framework based on paddle wheel-like cluster, Inorg Chem Commun 2011; 14: 1001–1003.
  • Reference 9 Nickerl G, Notzon A, Heitbaum M, Senkovska I, Glorius F, Kaskel S, Selective Adsorption Properties of Cationic Metal − Organic Frameworks Based on Imidazolic Linker, Cryst Growth Des 2013; 13: 198–203.
  • Reference 10 Parnham ER, Morris RE, Ionothermal synthesis of zeolites, metal-organic frameworks, and inorganic-organic hybrids, Acc Chem Res 2007; 40: 1005–1013.
  • Reference 11 Yusof R, Abdulmalek E, Sirat K, Rahman MBA, Tetrabutylammonium bromide (TBABr)-Based deep eutectic solvents (DESs) and their physical properties, Molecules 2014; 19: 8011–8026.
  • Reference 12 Abbott AP, Boothby D, Capper G, Davies DL, Rasheed RK, Deep Eutectic Solvents formed between choline chloride and carboxylic acids: Versatile alternatives to ionic liquids, J Am Chem Soc 2004; 126: 9142–9147.
  • Reference 13 Yılmaz E, Sert E, Atalay FS, Characterization of a metal organic framework : MIL-53(Fe) Synthesis and adsorption mechanisms of methyl red onto MIL-53 ( Fe ), J Taiwan Ins Chem Engineers 2016; 65: 323–330.
  • Reference 14 Goesten MG, Juan-Alcañiz J, Ramos-Fernandez EV, Sai Sankar Gupta KB, Stavitski E, Van Bekkum H, et al., Sulfation of metal-organic frameworks: Opportunities for acid catalysis and proton conductivity, J Catal 2011; 281: 177–187.
  • Reference 15 Combarieu GD, Morcrette M, Millange F, Guillou N, Cabana J, Grey CP, et al., Influence of the Benzoquinone sorption on the structure and electrochemical performance of the MIL-53 (Fe) hybrid porous material in a lithium-ion battery, Chem Mater 2009; 21: 1602–1611.
  • Reference 16 Xie L, Liu D, Huang H, Yang Q, Zhong C, Efficient capture of nitrobenzene from waste water using metal-organic frameworks, Chem Eng J 2014; 246: 142–149.
Toplam 16 adet kaynakça vardır.

Ayrıntılar

Konular Mühendislik
Bölüm Araştırma Makalesi
Yazarlar

Emine Sert

Esra Yılmaz Bu kişi benim

Ferhan Sami Atalay

Yayımlanma Tarihi 18 Aralık 2017
Yayımlandığı Sayı Yıl 2017 Cilt: 18 Sayı: 5

Kaynak Göster

APA Sert, E., Yılmaz, E., & Atalay, F. S. (2017). COMPARISON OF SOLVOTHERMAL AND IONOTHERMAL METHODS ON CATALYTIC ACTIVITY OF MIL-53 (Fe). Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, 18(5), 1107-1117. https://doi.org/10.18038/aubtda.328791
AMA Sert E, Yılmaz E, Atalay FS. COMPARISON OF SOLVOTHERMAL AND IONOTHERMAL METHODS ON CATALYTIC ACTIVITY OF MIL-53 (Fe). AUBTD-A. Aralık 2017;18(5):1107-1117. doi:10.18038/aubtda.328791
Chicago Sert, Emine, Esra Yılmaz, ve Ferhan Sami Atalay. “COMPARISON OF SOLVOTHERMAL AND IONOTHERMAL METHODS ON CATALYTIC ACTIVITY OF MIL-53 (Fe)”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 18, sy. 5 (Aralık 2017): 1107-17. https://doi.org/10.18038/aubtda.328791.
EndNote Sert E, Yılmaz E, Atalay FS (01 Aralık 2017) COMPARISON OF SOLVOTHERMAL AND IONOTHERMAL METHODS ON CATALYTIC ACTIVITY OF MIL-53 (Fe). Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 18 5 1107–1117.
IEEE E. Sert, E. Yılmaz, ve F. S. Atalay, “COMPARISON OF SOLVOTHERMAL AND IONOTHERMAL METHODS ON CATALYTIC ACTIVITY OF MIL-53 (Fe)”, AUBTD-A, c. 18, sy. 5, ss. 1107–1117, 2017, doi: 10.18038/aubtda.328791.
ISNAD Sert, Emine vd. “COMPARISON OF SOLVOTHERMAL AND IONOTHERMAL METHODS ON CATALYTIC ACTIVITY OF MIL-53 (Fe)”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 18/5 (Aralık 2017), 1107-1117. https://doi.org/10.18038/aubtda.328791.
JAMA Sert E, Yılmaz E, Atalay FS. COMPARISON OF SOLVOTHERMAL AND IONOTHERMAL METHODS ON CATALYTIC ACTIVITY OF MIL-53 (Fe). AUBTD-A. 2017;18:1107–1117.
MLA Sert, Emine vd. “COMPARISON OF SOLVOTHERMAL AND IONOTHERMAL METHODS ON CATALYTIC ACTIVITY OF MIL-53 (Fe)”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, c. 18, sy. 5, 2017, ss. 1107-1, doi:10.18038/aubtda.328791.
Vancouver Sert E, Yılmaz E, Atalay FS. COMPARISON OF SOLVOTHERMAL AND IONOTHERMAL METHODS ON CATALYTIC ACTIVITY OF MIL-53 (Fe). AUBTD-A. 2017;18(5):1107-1.