Year 2017, Volume 18, Issue 5, Pages 1000 - 1007 2017-12-31

SYNTHESIS AND CHARACTERIZATION OF NOVEL 4-CYNANOPHENYL-FUNCTIONALIZED N4,N4,N4′,N4′-TERAPHENYLBENZIDINE (TPB) AS HOLE TRANSPORTING MOLECULAR MATERIALS

Kamuran Gorgun [1]

174 278

In this study, a new cyanophenyl-functionalized N4,N4,N4′,N4′-tetraphenylbenzidine (TPB) containing employable hole-transporting components has been synthesized with Pd-catalyzed Suzuki-Miyaura cross coupling reaction. N4,N4,N4′,N4′tetrakis-(4′-cynobiphenyl-4-yl)-biphenyl-4,4′-diamine (TPB-CN)  was well characterized by 1H NMR, 13C NMR and CHN elemental analysis. The compound TPB-CN exhibited good thermal stability and luminescence properties. Time Dependent Density Functional Theory (TDDFT) computation was carried out to investigate the structural parameters and to understand the photophysical properties of the novel TPB-CN compound. The experimental and theoretical calculations performed to calculate absorption maxima in DCM by UV-Vis and TD-B3LYP/6-31g(d,p) were compared with each other. To identify crystal structure and to determine optical band gap of TPB-CN compound, its film form, which was coated on the glass substrate by spin coating, was used. The band gap of TPB-CN compound both in film and in solution was determined from the optical absorption measurements.

N4N4N4′N4′-tetraphenylbenzidine (TPB), Suzuki-Miyaura cross-coupling, Organic semiconductor, TDDFT
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Subjects Engineering
Journal Section Articles
Authors

Author: Kamuran Gorgun
Country: Turkey


Dates

Publication Date: December 31, 2017

Bibtex @research article { aubtda332785, journal = {ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY A - Applied Sciences and Engineering}, issn = {1302-3160}, eissn = {2146-0205}, address = {Eskişehir Teknik Üniversitesi}, year = {2017}, volume = {18}, pages = {1000 - 1007}, doi = {10.18038/aubtda.332785}, title = {SYNTHESIS AND CHARACTERIZATION OF NOVEL 4-CYNANOPHENYL-FUNCTIONALIZED N4,N4,N4′,N4′-TERAPHENYLBENZIDINE (TPB) AS HOLE TRANSPORTING MOLECULAR MATERIALS}, key = {cite}, author = {Gorgun, Kamuran} }
APA Gorgun, K . (2017). SYNTHESIS AND CHARACTERIZATION OF NOVEL 4-CYNANOPHENYL-FUNCTIONALIZED N4,N4,N4′,N4′-TERAPHENYLBENZIDINE (TPB) AS HOLE TRANSPORTING MOLECULAR MATERIALS. ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY A - Applied Sciences and Engineering, 18 (5), 1000-1007. DOI: 10.18038/aubtda.332785
MLA Gorgun, K . "SYNTHESIS AND CHARACTERIZATION OF NOVEL 4-CYNANOPHENYL-FUNCTIONALIZED N4,N4,N4′,N4′-TERAPHENYLBENZIDINE (TPB) AS HOLE TRANSPORTING MOLECULAR MATERIALS". ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY A - Applied Sciences and Engineering 18 (2017): 1000-1007 <http://dergipark.org.tr/aubtda/issue/31308/332785>
Chicago Gorgun, K . "SYNTHESIS AND CHARACTERIZATION OF NOVEL 4-CYNANOPHENYL-FUNCTIONALIZED N4,N4,N4′,N4′-TERAPHENYLBENZIDINE (TPB) AS HOLE TRANSPORTING MOLECULAR MATERIALS". ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY A - Applied Sciences and Engineering 18 (2017): 1000-1007
RIS TY - JOUR T1 - SYNTHESIS AND CHARACTERIZATION OF NOVEL 4-CYNANOPHENYL-FUNCTIONALIZED N4,N4,N4′,N4′-TERAPHENYLBENZIDINE (TPB) AS HOLE TRANSPORTING MOLECULAR MATERIALS AU - Kamuran Gorgun Y1 - 2017 PY - 2017 N1 - doi: 10.18038/aubtda.332785 DO - 10.18038/aubtda.332785 T2 - ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY A - Applied Sciences and Engineering JF - Journal JO - JOR SP - 1000 EP - 1007 VL - 18 IS - 5 SN - 1302-3160-2146-0205 M3 - doi: 10.18038/aubtda.332785 UR - https://doi.org/10.18038/aubtda.332785 Y2 - 2017 ER -
EndNote %0 ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY A - Applied Sciences and Engineering SYNTHESIS AND CHARACTERIZATION OF NOVEL 4-CYNANOPHENYL-FUNCTIONALIZED N4,N4,N4′,N4′-TERAPHENYLBENZIDINE (TPB) AS HOLE TRANSPORTING MOLECULAR MATERIALS %A Kamuran Gorgun %T SYNTHESIS AND CHARACTERIZATION OF NOVEL 4-CYNANOPHENYL-FUNCTIONALIZED N4,N4,N4′,N4′-TERAPHENYLBENZIDINE (TPB) AS HOLE TRANSPORTING MOLECULAR MATERIALS %D 2017 %J ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY A - Applied Sciences and Engineering %P 1302-3160-2146-0205 %V 18 %N 5 %R doi: 10.18038/aubtda.332785 %U 10.18038/aubtda.332785
ISNAD Gorgun, Kamuran . "SYNTHESIS AND CHARACTERIZATION OF NOVEL 4-CYNANOPHENYL-FUNCTIONALIZED N4,N4,N4′,N4′-TERAPHENYLBENZIDINE (TPB) AS HOLE TRANSPORTING MOLECULAR MATERIALS". ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY A - Applied Sciences and Engineering 18 / 5 (December 2018): 1000-1007. https://doi.org/10.18038/aubtda.332785
AMA Gorgun K . SYNTHESIS AND CHARACTERIZATION OF NOVEL 4-CYNANOPHENYL-FUNCTIONALIZED N4,N4,N4′,N4′-TERAPHENYLBENZIDINE (TPB) AS HOLE TRANSPORTING MOLECULAR MATERIALS. AUJST-A. 2017; 18(5): 1000-1007.
Vancouver Gorgun K . SYNTHESIS AND CHARACTERIZATION OF NOVEL 4-CYNANOPHENYL-FUNCTIONALIZED N4,N4,N4′,N4′-TERAPHENYLBENZIDINE (TPB) AS HOLE TRANSPORTING MOLECULAR MATERIALS. ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY A - Applied Sciences and Engineering. 2017; 18(5): 1007-1000.