Year 2016, Volume 4, Issue 1, Pages 11 - 28 2016-03-19

SYNTHESIS, CHARACTERIZATION AND SPECTROSCOPIC STUDIES ON AZO-HYDRAZONE TAUTOMERISM AND ACIDITY CONSTANTS OF CERTAIN 4-(PHENYLDIAZENYL) BENZENE-1,3-DIOL DERIVATIVES
SYNTHESIS, CHARACTERIZATION AND SPECTROSCOPIC STUDIES ON TAUTOMERISM AND ACIDITY CONSTANTS OF CERTAIN 4- (PHENYLDIAZENYL) BENZENE-1,3-DIOL DERIVATIVES

Halil Berber [1] , Nilüfer Aksu Ateş [2] , Müjgan Yaman Özkütük [3]

1190 866

In this study, monoazo dyes were synthesized through the diazotization of several substituted aminobenzenes and couplings with benzene-1,3-diols. The chemical structures of these compounds were characterized using spectroscopic techniques. The tautomeric properties of the 4-(phenyldiazenyl)benzene-1,3-diol derivative compounds were examined using UV-Vis. spectrophotometry in pure polar or apolar media (dimethyl sulfoxide, ethanol, chloroform, benzene and cyclohexane) under acidic and basic conditions at 25 ± 1 °C, 35 ± 1 °C and 45 ± 1 °C. The percentage of the azo-hydrazone tautomers was calculated for all of the compounds. The UV-Vis. analysis reveals that the azo form is dominant in the presence of azo-hydrazone tautomerism for all azo dyes. Concurrently, the acidity constants for these derivatives were determined using a UV-Vis. spectroscopic technique at 25 °C (± 0.1 °C).
Bu çalışmada, benzen-1,3-triol ve bazı sübstitüe amino benzen ile monoazo boyar maddeleri sentezlendi. Kimyasal yapıları spektroskopik teknikler ile aydınlatıldı. 4-(fenildiazenil)benzen-1,3-diol türevi bileşiklerinin tautomerik özellikleri saf polar ve apolar çözücülerde (dimetil sülfoksit, etanol, kloroform, benzen ve siklohekzan) asidik ve bazik ortamlarda 25±1 °C, 35±1 °C ve 45±1 °C UV-Vis. Spektrometresinde ölçüldü. Sentezlenen bileşiklerin azo-hidrazon tautomerleri hesaplandı. Bütün azo boyar madde bileşiklerinde azo tautomer formunun baskın olduğu belirlendi. Aynı bileşiklerin asitlik sabitleri 25 °C (0,1 °C) UV-Vis. Spektroskopik teknik ile belirlendi
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Journal Section Articles
Authors

Author: Halil Berber

Author: Nilüfer Aksu Ateş

Author: Müjgan Yaman Özkütük

Bibtex @ { aubtdb262701, journal = {ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY –B Theoretical Sciences}, issn = {2146-0272}, eissn = {2146-0191}, address = {Eskişehir Teknik Üniversitesi}, year = {2016}, volume = {4}, pages = {11 - 28}, doi = {10.20290/btdb.01190}, title = {SYNTHESIS, CHARACTERIZATION AND SPECTROSCOPIC STUDIES ON AZO-HYDRAZONE TAUTOMERISM AND ACIDITY CONSTANTS OF CERTAIN 4-(PHENYLDIAZENYL) BENZENE-1,3-DIOL DERIVATIVES}, key = {cite}, author = {Berber, Halil and Ateş, Nilüfer Aksu and Özkütük, Müjgan Yaman} }
APA Berber, H , Ateş, N , Özkütük, M . (2016). SYNTHESIS, CHARACTERIZATION AND SPECTROSCOPIC STUDIES ON AZO-HYDRAZONE TAUTOMERISM AND ACIDITY CONSTANTS OF CERTAIN 4-(PHENYLDIAZENYL) BENZENE-1,3-DIOL DERIVATIVES. ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY –B Theoretical Sciences, 4 (1), 11-28. DOI: 10.20290/btdb.01190
MLA Berber, H , Ateş, N , Özkütük, M . "SYNTHESIS, CHARACTERIZATION AND SPECTROSCOPIC STUDIES ON AZO-HYDRAZONE TAUTOMERISM AND ACIDITY CONSTANTS OF CERTAIN 4-(PHENYLDIAZENYL) BENZENE-1,3-DIOL DERIVATIVES". ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY –B Theoretical Sciences 4 (2016): 11-28 <http://dergipark.org.tr/aubtdb/issue/24861/262701>
Chicago Berber, H , Ateş, N , Özkütük, M . "SYNTHESIS, CHARACTERIZATION AND SPECTROSCOPIC STUDIES ON AZO-HYDRAZONE TAUTOMERISM AND ACIDITY CONSTANTS OF CERTAIN 4-(PHENYLDIAZENYL) BENZENE-1,3-DIOL DERIVATIVES". ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY –B Theoretical Sciences 4 (2016): 11-28
RIS TY - JOUR T1 - SYNTHESIS, CHARACTERIZATION AND SPECTROSCOPIC STUDIES ON AZO-HYDRAZONE TAUTOMERISM AND ACIDITY CONSTANTS OF CERTAIN 4-(PHENYLDIAZENYL) BENZENE-1,3-DIOL DERIVATIVES AU - Halil Berber , Nilüfer Aksu Ateş , Müjgan Yaman Özkütük Y1 - 2016 PY - 2016 N1 - doi: 10.20290/btdb.01190 DO - 10.20290/btdb.01190 T2 - ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY –B Theoretical Sciences JF - Journal JO - JOR SP - 11 EP - 28 VL - 4 IS - 1 SN - 2146-0272-2146-0191 M3 - doi: 10.20290/btdb.01190 UR - https://doi.org/10.20290/btdb.01190 Y2 - 2019 ER -
EndNote %0 ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY –B Theoretical Sciences SYNTHESIS, CHARACTERIZATION AND SPECTROSCOPIC STUDIES ON AZO-HYDRAZONE TAUTOMERISM AND ACIDITY CONSTANTS OF CERTAIN 4-(PHENYLDIAZENYL) BENZENE-1,3-DIOL DERIVATIVES %A Halil Berber , Nilüfer Aksu Ateş , Müjgan Yaman Özkütük %T SYNTHESIS, CHARACTERIZATION AND SPECTROSCOPIC STUDIES ON AZO-HYDRAZONE TAUTOMERISM AND ACIDITY CONSTANTS OF CERTAIN 4-(PHENYLDIAZENYL) BENZENE-1,3-DIOL DERIVATIVES %D 2016 %J ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY –B Theoretical Sciences %P 2146-0272-2146-0191 %V 4 %N 1 %R doi: 10.20290/btdb.01190 %U 10.20290/btdb.01190
ISNAD Berber, Halil , Ateş, Nilüfer Aksu , Özkütük, Müjgan Yaman . "SYNTHESIS, CHARACTERIZATION AND SPECTROSCOPIC STUDIES ON AZO-HYDRAZONE TAUTOMERISM AND ACIDITY CONSTANTS OF CERTAIN 4-(PHENYLDIAZENYL) BENZENE-1,3-DIOL DERIVATIVES". ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY –B Theoretical Sciences 4 / 1 (March 2016): 11-28. https://doi.org/10.20290/btdb.01190