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The Synthesis, Characterization of a Novel Schiff Base Ligand and Investigation of Its Transition Metal Complexes

Year 2017, Volume: 7 Issue: 1, 47 - 59, 21.06.2017

Burak Oğuzhan Erdal Canpolat , Hakan Şahal Mehmet Kaya

Abstract

In this study, one new Schiff base ligand and its
transition metal complexes were synthesized. Schiff
base was found to be bidentate ligand involving the imino nitrogen and carboxyl
oxygen atoms in the complexes. Metal to ligand ratio were found 1:2 for all of
the complexes. Co(II), Ni(II), Cu(II) and
Zn(II) complexes have been found tetrahedral geometry. The complexes are found
to have the formulae [M(L)2]. The structure of these
compounds were characterized by using elemental analysis, IR, 1H-
and 13C-NMR and UV spectroscopy, magnetic susceptibility
measurements. In addition, the thermal characterization of the ligand and its
complexes were carried out by using TGA technique.

Keywords

Schiff Bases Transition Metal Complexes Synthesis

References

  • -Prof. Dr. Nevin Gürbüz (nevin.gurbuz@inonu.edu.tr) -Doç. Dr. Cumhur Kırılmış (ckirilmis@gmail.com) -Doç. Dr. Ömer Faruk Öztürk (ofozturk@comu.edu.tr)

Yeni Bir Schiff Baz Ligandının Sentezi, Karakterizasyonu ve Geçiş Metal Komplekslerinin İncelenmesi

Year 2017, Volume: 7 Issue: 1, 47 - 59, 21.06.2017

Burak Oğuzhan Erdal Canpolat , Hakan Şahal Mehmet Kaya

Abstract

Bu çalışmada, bir yeni
Schiff bazı ligandı ve onun geçiş metal kompleksleri sentezlenmiştir. Komplekslerde Schiff bazlarının metal iyonuna imin
azotu ve fenolik oksijeninden
bağlanarak iki dişli şelat olarak davrandığı bulunmuştur. Metal-ligand oranı, tüm kompleksler için 1: 2 bulundu. Co
(II), Ni (II), Cu (II) ve Zn (II) kompleksleri tetrahedral geometriye sahiptir.
Komplekslerin formülleri [M(L)2] olduğu bulunmuştur. Bileşiklerin
yapıları elemental analiz, IR, 1H- ve 13C-NMR ve UV
spektroskopisi, manyetik duyarlılık ölçümleri kullanılarak karakterize edildi.
Ek olarak, ligand ve komplekslerinin termal karakterizasyonu TGA tekniği
kullanılarak gerçekleştirildi.

Keywords

Schiff Bazı Geçiş Metal Kompleksleri Sentez

References

  • -Prof. Dr. Nevin Gürbüz (nevin.gurbuz@inonu.edu.tr) -Doç. Dr. Cumhur Kırılmış (ckirilmis@gmail.com) -Doç. Dr. Ömer Faruk Öztürk (ofozturk@comu.edu.tr)
There are 1 citations in total.

Details

Subjects Engineering
Journal Section Chemistry
Authors

Burak Oğuzhan This is me

Erdal Canpolat

Hakan Şahal This is me

Mehmet Kaya This is me

Publication Date June 21, 2017
Submission Date April 7, 2017
Acceptance Date June 5, 2017
Published in Issue Year 2017 Volume: 7 Issue: 1

Cite

APA Oğuzhan, B., Canpolat, E., Şahal, H., Kaya, M. (2017). The Synthesis, Characterization of a Novel Schiff Base Ligand and Investigation of Its Transition Metal Complexes. Adıyaman University Journal of Science, 7(1), 47-59.
AMA Oğuzhan B, Canpolat E, Şahal H, Kaya M. The Synthesis, Characterization of a Novel Schiff Base Ligand and Investigation of Its Transition Metal Complexes. ADYU J SCI. June 2017;7(1):47-59.
Chicago Oğuzhan, Burak, Erdal Canpolat, Hakan Şahal, and Mehmet Kaya. “The Synthesis, Characterization of a Novel Schiff Base Ligand and Investigation of Its Transition Metal Complexes”. Adıyaman University Journal of Science 7, no. 1 (June 2017): 47-59.
EndNote Oğuzhan B, Canpolat E, Şahal H, Kaya M (June 1, 2017) The Synthesis, Characterization of a Novel Schiff Base Ligand and Investigation of Its Transition Metal Complexes. Adıyaman University Journal of Science 7 1 47–59.
IEEE B. Oğuzhan, E. Canpolat, H. Şahal, and M. Kaya, “The Synthesis, Characterization of a Novel Schiff Base Ligand and Investigation of Its Transition Metal Complexes”, ADYU J SCI, vol. 7, no. 1, pp. 47–59, 2017.
ISNAD Oğuzhan, Burak et al. “The Synthesis, Characterization of a Novel Schiff Base Ligand and Investigation of Its Transition Metal Complexes”. Adıyaman University Journal of Science 7/1 (June 2017), 47-59.
JAMA Oğuzhan B, Canpolat E, Şahal H, Kaya M. The Synthesis, Characterization of a Novel Schiff Base Ligand and Investigation of Its Transition Metal Complexes. ADYU J SCI. 2017;7:47–59.
MLA Oğuzhan, Burak et al. “The Synthesis, Characterization of a Novel Schiff Base Ligand and Investigation of Its Transition Metal Complexes”. Adıyaman University Journal of Science, vol. 7, no. 1, 2017, pp. 47-59.
Vancouver Oğuzhan B, Canpolat E, Şahal H, Kaya M. The Synthesis, Characterization of a Novel Schiff Base Ligand and Investigation of Its Transition Metal Complexes. ADYU J SCI. 2017;7(1):47-59.

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