Alcian Blue 8GX Remediation by Fe2+/Persulfate And Heat/Persulfate

Year 2024, Volume: 7 Issue: 2, 73 - 77, 15.12.2024

Ghislain Tayue Tatsenguem , Şifa Doğan

https://doi.org/10.53448/akuumubd.1510551

Abstract

In this work, decolorization of reactive Alcain Blue 8GX dye solution were investigated by persulfate oxidation activated by ferrous ion and heat. Three different temperature (40 °C, 60 °C and 80 °C) were tested during heat activated persulfate and ferrous ion activated persulfate were tested under various molar ratios of dye:Fe2+:persulfate ratio (1:1:1, 1:2:1, 1:1:0.5, 1:4:1). In addition, pH effect has been tested at ambient conditions (5.23) and pH of 3. The results showed that increasing the temperature and persulfate concentration was favorable to the degradation of the dye with decolorization efficiency as high as 91 % observed at 80 ℃ after 90 minutes of reaction at pH 3. The ratio 1:1:1 decolorized AB 8GX 73 % at pH of 3 and 72 % at pH 5.7 after 90 minutes.

Keywords

Alcain Blue 8GX;, Advanced oxidation;, Textile wastewater treatment;, Fe2+/Persulfate;, Heat/Persulfate

Fe2+/Persülfat ve Isı/Persülfat Yöntemleri ile Alcain Mavisi 8GX Giderimi

Abstract

Bu çalışma, Alcain Mavisi 8GX boya çözeltilerinin demir (II) iyonu ve ısı aktivasyonuna dayalı persülfat oksidasyonu ile sulardan arıtımını içermektedir. Giderim çalışmaları üç farklı sıcaklık (40 oC, 60 oC ve 80 oC) ve farklı boya:Fe2+:persülfat molar dozlarında (1:1:1, 1:2:1, 1:1:0.5, 1:4:1) gerçekleştirilmiştir. Buna ilaveten, pH’ın giderime etkisi iki farklı pH koşullarında (3 ve 5.7) test edilmiştir. Sonuçlar, artan sıcaklığın ve persülfat dozunun Alcain Mavisi 8GX giderimini artırdığını göstermiş ve pH 3 koşullarında 90 dakika sonunda 80 oC sıcaklıkta % 91 giderilmiştir. Fe2+/Persülfat yöntemi ise 1:1:1 boya:Fe2+:persülfat molar dozunda pH 3 koşullarında 90 dakika sonunda % 73 boya giderimi sağlamıştır; 1:2:1 koşullarında pH 5.7’de ise % 72 giderim gözlenmiştir.

Keywords

Alcain Mavisi 8GX;, İleri oksidasyon;, Tekstil atıksu arıtımı;, Fe2+/persülfat;, Isı/Persülfat

References

• Abdi, M., Balagabri, M., Karimi, H., Hossini, H., & Rastegar, S. O., 2020. Degradation of crystal violet (CV) from aqueous solutions using ozone, peroxone, electroperoxone, and electrolysis processes: a comparison study. Applied Water Science, 10(7), 1-10.
• Agrawal, K., Verma, P. 2020. Myco-valorization approach using entrapped Myrothecium verrucaria ITCC-8447 on synthetic and natural support via column bioreactor for the detoxification and degradation of anthraquinone dyes. International Biodeterioration & Biodegradation, 153, 105052.
• Ayed, L., Ladhari, N., Achour, S., Chaieb, K. 2021. Decolorization of Reactive Yellow 174 dye in real textile wastewater by active consortium: Experimental factorial design for bioremediation process optimization. The Journal of The Textile Institute, 112(9), 1449-1459.
• Garvasis, J., Prasad, A. R., Shamsheera, K. O., Jaseela, P. K., & Joseph, A. 2020. Efficient removal of Congo red from aqueous solutions using phytogenic aluminum sulfate nano coagulant. Materials Chemistry and Physics, 251, 123040.
• Hayat, H., Mahmood, Q., Pervez, A., Bhatti, Z. A., & Baig, S. A. 2015. Comparative decolorization of dyes in textile wastewater using biological and chemical treatment. Separation and Purification Technology, 154, 149-153.
• Kristianto, H., Tanuarto, M. Y., Prasetyo, S., & Sugih, A. K. 2020. Magnetically assisted coagulation using iron oxide nanoparticles-Leucaena leucocephala seeds’ extract to treat synthetic Congo red wastewater. International journal of environmental science and technology, 17(7), 3561-3570.
• Montañez-Barragán, B., Sanz-Martín, J. L., Gutiérrez-Macías, P., Morato-Cerro, A., Rodríguez-Vázquez, R., & Barragán-Huerta, B. E. 2020. Azo dyes decolorization under high alkalinity and salinity conditions by Halomonas sp. in batch and packed bed reactor. Extremophiles, 24(2), 239-247.
• Muneer, M., Kanjal, M. I., Saeed, M., Javed, T., Haq, A. U., Den, N. Z. U., ... & Iqbal, M. 2020. High energy radiation induced degradation of reactive yellow 145 dye: A mechanistic study. Radiation Physics and Chemistry, 177, 109115.
• Radwan, E. K., Abdel-Aty, A. M., El-Wakeel, S. T., & Abdel Ghafar, H. H. 2020. Bioremediation of potentially toxic metal and reactive dye-contaminated water by pristine and modified Chlorella vulgaris. Environmental Science and Pollution Research, 27(17), 21777-21789.
• Scott, J. E. 1972. Amplification of staining by Alcian Blue and similar ingrain dyes. Journal of Histochemistry & Cytochemistry, 20(9), 750-752.
• Shi J., Wang J., Liang L., Xu Z., Chen Y., Chen S., & Wang S. 2021. Carbothermal synthesis of biochar-supported metallic silver for enhanced photocatalytic removal of methylene blue and antimicrobial efficacy. Journal of Hazardous Materials, 401, 123382.
• Wang, Z., Zhang, Y., Li, K., Sun, Z., & Wang, J. 2020. Enhanced mineralization of reactive brilliant red X-3B by UV driven photocatalytic membrane contact ozonation. Journal of hazardous materials, 391, 122194.
• Zhang, S., Zhong, L., Wang, J., Tang, A., Yang, H. 2021. Porous carbon-based MgAlF5· 1.5 H2O composites derived from carbon-coated clay presenting super high adsorption capacity for Congo Red. Chemical Engineering Journal, 406, 126784.