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Synthesis and Structure Characterization of a New Palladium Dithiophosphinato Complex

Year 2024, Volume: 4 Issue: 1, 12 - 19, 22.05.2024
https://doi.org/10.5281/zenodo.11219364

Abstract

A new Pd(II) dithiophosphinato complex was synthesised the ammonium sec-butyl (4-methoxyphenyl) dithiophosphinate ligand previously known. New Pd(II) dithiophosphinato complex’ structure was elucidated by mass spectrometry (ESI), FTIR spectroscopy, NMR (1H-, 13C- and 31P-).

Project Number

1919B012212041

References

  • [1] M. Salavati-Niasari, “Host (nanocavity of zeolite-Y)-guest (tetraaza [14] annulene copper (II) complexes) nanocomposite materials: Synthesis, characterization and liquid phase oxidation of benzyl alcohol”, Journal of Molecular Catalysis A: Chemical, (2006), 245, 192-199.
  • [2] M. Salavati-Niasari, “Zeolite-encapsulated nickel (II) complexes with 14-membered hexaaza macrocycle: synthesis and characterization”, Inorganic Chemistry Communications, (2004), 7, 963-966.
  • [3] M. Salavati-Niasari, Z. Salimi, M. Bazarganipour, F. Davar, “Synthesis, characterization and catalytic oxidation of cyclohexane using a novel host (zeolite-Y)/guest (binuclear transition metal complexes) nanocomposite materials”, Inorganica Chimica Acta, (2009), 362, 3715-3724.
  • [4] M. Salavati-Niasari, “Ship-in-a-bottle synthesis, characterization and catalytic oxidation of styrene by host (nanopores of zeolite-Y)/ guest ([bis (2-hydroxyanil) acetylacetonato manganese (III)]) nanocomposite materials (HGNM)”, Microporous and Mesoporous Materials, (2006), 95, 248-256.
  • [5] M. Salavati-Niasari, “Nanoscale microreactor-encapsulation 14-membered nickel(II) hexamethyl tetraaza: synthesis, characterization and catalytic activity”, Journal of Molecular Catalysis A: Chemical, (2005), 229, 159-164.
  • [6] S. Zinatloo-Ajabshir, M. Salavati-Niasari, M. Hamadanian, “Praseodymium oxide nanostructures: novel solvent-less preparation, characterization and investigation of their optical and photocatalytic properties”, RSC Advances, (2015), 43, 33792-33800.
  • [7] E.G. Sağlam, “Syntheses and structural studies on some new dithiophosphinato complexes of nickel(II), cobalt(II) and mixed pyridino complexes thereof”, Inorganica Chimica Acta, (2015), 434, 188-197.
  • [8] K. Diemert, W. Kuchen, “Zur Kenntnıs Der Organophosphorverbındungen, XVII1 Dithiophosphinsäuren RR'P(S)SH, Ihre Synthese, Derivate und Metallkomplexe”, Phosphorus, Sulfur Silicon Related Elements, (1977), 3, 131-136.
  • [9] S. Arrowsmith, M.D. Irving, US 8,709,988, B2 (2014).
  • [10] J. Chen, S. Wang, C. Xu, X. Wang, X. Feng, “Separation of Americium from Lanthanides by Purified Cyanex 301 Countercurrent Extraction in Miniature Centrifugal Contactors”, Procedia Chemistry, (2012), 7, 172-177.
  • [11] J. Chen, M. Wei, X. Liu, J. Wang, “Back-end of nuclear fuel cycle in China”, Progress in Nuclear Energy, (2012), 54, 46-48.
  • [12] A.V. Artem’ev, S.F. Malysheva, N.K. Gusarova, N.A. Belogorlova, S.V. Fedorov, B.V. Timokhin, V.I. Smirnov, B.A. Trofimov, “Novel quinine, lupinine, and anabasine derivatives containing dithiophosphinate groups”, Chemistry of Heterocyclic Compounds, (2012), 48, 448-452.
  • [13] J.A. McCleverty, R.S.Z. Kowalski, N.A. Bailey, R.Mulvaney, D.A. O'Cleirigh, “Aspects of the inorganic chemistry of rubber vulcanisation. Part 4. Dialkyl- and diaryl-dithiophosphate and -dithiophosphinate complexes of zinc: phosphorus-31 nuclear magnetic resonance spectral studies and structures of [NMe4][Zn{S2P(OC6H4Me-p)2}3] and [NEt4][Zn(S2PPh2)3]” Journal of the Chemical Society, Dalton Transactions, (1983), 4, 627-634.
  • [14] A. Bara, C. Socaciu, C. Silvestru, I. Haiduc “Antitumor organometallics. I. Activity of some diphenyltin(IV) and diphenylantimony(III) derivatives on in vitro and in vivo Ehrlich ascites tumor” Anticancer Research, (1991), 11, 4, 1651-1655.
  • [15] Jing Chen, Shuwei Wang, Chao Xu, Xinhai Wang, Xiaogui Feng, “Separation of Americium from Lanthanides by Purified Cyanex 301 Countercurrent Extraction in Miniature Centrifugal Contactors” Procedia Chemistry, (2012), 7, 172-177.
  • [16] J. Chen, M. Wei, X. Liu, J. Wang, “Back-end of nuclear fuel cycle in China” Progress in Nuclear Energy (2012), 54, 46.
  • [17] S.M. Ghoreishi, K. Ansari, H.S. Ghaziaskar, “Supercritical extraction of toxic heavy metals from aqueous waste via Cyanex 301 as chelating agent” The Journal of Supercritical Fluids, (2012), 72, 288.
  • [18] M.M. Rouhut, A.H. Currier and V.P. Wystrach, “The Preparation of Dithiophosphinates from Secondary Phosphines and Sulfur under Alkaline Conditions”, The Journal of Organic Chemistry, (1961), 26, 5133-5135.
  • [19] E.G. Sağlam, Ö. Çelik, H. Yılmaz, S. İde, “Synthesis, spectroscopic characterization and X-ray single crystal structures of trans-bis [4-methoxyphenyl (3-methylbutyl) dithiophosphinato] nickel(II) and bis [4-methoxyphenyl (3-methylbutyl) dithiophosphinato]cobalt(II) complexes” Transition Metal Chemistry, (2010), 35, 399-405.
  • [20] R.G. Cavell, W. Byers, E.D. Day, P.M. Watkins, “Metal complexes of substituted dithiophosphinic acids. IV. Complexes of divalent nickel, palladium, and platinum” Inorganic Chemistry, (1972), 11, 1598.
  • [21] R.G. Cavell, E.D. Day, W. Byers, P.M. Watkins, “Metal complexes of substituted dithiophosphinic acids. V. Complexes of manganese, iron, and cobalt” Inorganic Chemistry, (1972), 11, 1759.
  • [22] I. Haiduc, “Supramolecular associations, secondary bonds, quasi-cyclic structures and heterogeometrism in metal derivatives of phosphorus- and arsenic-based thioacids and oxo analogs” Coordination Chemistry Reviews, (1997), 158, 325.
  • [23] A.A. Pinkerton, F.P. Ahlers, H.F. Greiwing, B. Krebs, “Dithiophosphinate complexes of the UO22+ ion containing a coordinated water molecule-solid state structures and stereochemical rigidity in solution” Inorganica Chimica Acta (1997), 257, 77.
  • [24] J.S. Casas, M.S. García-Tasende, A. Sánchez, J. Sordo, E.E. Castellano, J. Zukerman-Schpector, “Synthesis, crystal structure and spectroscopic properties of bis(diphenyldithiophosphinato)cadmium(II)”Inorganica Chimica Acta (1994), 219, 115.
  • [25] C. Byrom, M.A. Malik, P. O’Brien, A. J. P. White, D.J. Williams, “Synthesis and X-ray single crystal structures of bis (diisobutyldithiophosphinato) cadmium(II) or zinc(II): Potential single-source precursors for II/VI materials” Polyhedron, (2000), 19, 211.
  • [26] M. Calligaris, G. Nardin, A. Ripamonti, “Crystal and molecular structure of zinc(II) and cobalt(II) diethyldithiophosphinates” Journal of the Chemical Society A: Inorganic, Physical, Theoretical, (1970), 714-722.
  • [27] H. Keck, W. Kuchen, “Massenspektrometrische Untersuchungen An Organophosphorverbindungen IV. Über den massenspektrometrischen Zerfall von Dithiophosphinsären” Phosphorus, Sulfur Silicon Related Elements, (1983), 14, 225.
  • [28] E.G. Sağlam, H. Yılmaz, H. Dal, T. Hökelek, “Synthesis and Spectroscopic Characterizations of Novel Ni(II) and Co(II) Dithiophosphinate Complexes, and X-Ray Studies on the Ni(II) Complex”, Phosphorus, Sulfur Silicon Related Elements, (2012), 187, 213-224.
  • [29] A. Nimairatan, and N. Saha, "Synthesis and spectroscopic characterization of palladium (II) and platinum (II) complexes with substituted pyrazoles" Asian Journal of Chemistry, (2008), 20, 521-529.
  • [30] M. Karakus, H. Yılmaz, “Synthesis and characterization of Ni(II), Zn(II), and Cd(II) complexes with dithiophosphonate derivatives”, Russian Journal of Coordination Chemistry, (2006), 32, 437–443.

Yeni Palladyum Ditiyofosfinato Kompleksi Sentezi ve Yapısının Aydınlatılması

Year 2024, Volume: 4 Issue: 1, 12 - 19, 22.05.2024
https://doi.org/10.5281/zenodo.11219364

Abstract

Bilinen amonyum sek-bütil(4-metoksifenil) ditiyofosfinat ligandından, yeni Pd(II) ditiyofosfinato kompleksi sentezlendi. Sentezlenen Pd(II) ditiyofosfinato kompleksinin yapısı kütle spektrometrisi (ESI), FTIR spektroskopisi, NMR (1H-, 13C- ve 31P-) ile karakterize edilmiştir.

Supporting Institution

TÜBİTAK, 2209-A Üniversite Öğrencileri Araştırma Projeleri Destekleme Programı

Project Number

1919B012212041

Thanks

Yazarlar bu çalışmaya “Üniversite Öğrencileri Araştırma Projeleri Destekleme Programı” kapsamında finansal destekte bulunan “TÜBİTAK 2209-A” projesine teşekkür ederler.

References

  • [1] M. Salavati-Niasari, “Host (nanocavity of zeolite-Y)-guest (tetraaza [14] annulene copper (II) complexes) nanocomposite materials: Synthesis, characterization and liquid phase oxidation of benzyl alcohol”, Journal of Molecular Catalysis A: Chemical, (2006), 245, 192-199.
  • [2] M. Salavati-Niasari, “Zeolite-encapsulated nickel (II) complexes with 14-membered hexaaza macrocycle: synthesis and characterization”, Inorganic Chemistry Communications, (2004), 7, 963-966.
  • [3] M. Salavati-Niasari, Z. Salimi, M. Bazarganipour, F. Davar, “Synthesis, characterization and catalytic oxidation of cyclohexane using a novel host (zeolite-Y)/guest (binuclear transition metal complexes) nanocomposite materials”, Inorganica Chimica Acta, (2009), 362, 3715-3724.
  • [4] M. Salavati-Niasari, “Ship-in-a-bottle synthesis, characterization and catalytic oxidation of styrene by host (nanopores of zeolite-Y)/ guest ([bis (2-hydroxyanil) acetylacetonato manganese (III)]) nanocomposite materials (HGNM)”, Microporous and Mesoporous Materials, (2006), 95, 248-256.
  • [5] M. Salavati-Niasari, “Nanoscale microreactor-encapsulation 14-membered nickel(II) hexamethyl tetraaza: synthesis, characterization and catalytic activity”, Journal of Molecular Catalysis A: Chemical, (2005), 229, 159-164.
  • [6] S. Zinatloo-Ajabshir, M. Salavati-Niasari, M. Hamadanian, “Praseodymium oxide nanostructures: novel solvent-less preparation, characterization and investigation of their optical and photocatalytic properties”, RSC Advances, (2015), 43, 33792-33800.
  • [7] E.G. Sağlam, “Syntheses and structural studies on some new dithiophosphinato complexes of nickel(II), cobalt(II) and mixed pyridino complexes thereof”, Inorganica Chimica Acta, (2015), 434, 188-197.
  • [8] K. Diemert, W. Kuchen, “Zur Kenntnıs Der Organophosphorverbındungen, XVII1 Dithiophosphinsäuren RR'P(S)SH, Ihre Synthese, Derivate und Metallkomplexe”, Phosphorus, Sulfur Silicon Related Elements, (1977), 3, 131-136.
  • [9] S. Arrowsmith, M.D. Irving, US 8,709,988, B2 (2014).
  • [10] J. Chen, S. Wang, C. Xu, X. Wang, X. Feng, “Separation of Americium from Lanthanides by Purified Cyanex 301 Countercurrent Extraction in Miniature Centrifugal Contactors”, Procedia Chemistry, (2012), 7, 172-177.
  • [11] J. Chen, M. Wei, X. Liu, J. Wang, “Back-end of nuclear fuel cycle in China”, Progress in Nuclear Energy, (2012), 54, 46-48.
  • [12] A.V. Artem’ev, S.F. Malysheva, N.K. Gusarova, N.A. Belogorlova, S.V. Fedorov, B.V. Timokhin, V.I. Smirnov, B.A. Trofimov, “Novel quinine, lupinine, and anabasine derivatives containing dithiophosphinate groups”, Chemistry of Heterocyclic Compounds, (2012), 48, 448-452.
  • [13] J.A. McCleverty, R.S.Z. Kowalski, N.A. Bailey, R.Mulvaney, D.A. O'Cleirigh, “Aspects of the inorganic chemistry of rubber vulcanisation. Part 4. Dialkyl- and diaryl-dithiophosphate and -dithiophosphinate complexes of zinc: phosphorus-31 nuclear magnetic resonance spectral studies and structures of [NMe4][Zn{S2P(OC6H4Me-p)2}3] and [NEt4][Zn(S2PPh2)3]” Journal of the Chemical Society, Dalton Transactions, (1983), 4, 627-634.
  • [14] A. Bara, C. Socaciu, C. Silvestru, I. Haiduc “Antitumor organometallics. I. Activity of some diphenyltin(IV) and diphenylantimony(III) derivatives on in vitro and in vivo Ehrlich ascites tumor” Anticancer Research, (1991), 11, 4, 1651-1655.
  • [15] Jing Chen, Shuwei Wang, Chao Xu, Xinhai Wang, Xiaogui Feng, “Separation of Americium from Lanthanides by Purified Cyanex 301 Countercurrent Extraction in Miniature Centrifugal Contactors” Procedia Chemistry, (2012), 7, 172-177.
  • [16] J. Chen, M. Wei, X. Liu, J. Wang, “Back-end of nuclear fuel cycle in China” Progress in Nuclear Energy (2012), 54, 46.
  • [17] S.M. Ghoreishi, K. Ansari, H.S. Ghaziaskar, “Supercritical extraction of toxic heavy metals from aqueous waste via Cyanex 301 as chelating agent” The Journal of Supercritical Fluids, (2012), 72, 288.
  • [18] M.M. Rouhut, A.H. Currier and V.P. Wystrach, “The Preparation of Dithiophosphinates from Secondary Phosphines and Sulfur under Alkaline Conditions”, The Journal of Organic Chemistry, (1961), 26, 5133-5135.
  • [19] E.G. Sağlam, Ö. Çelik, H. Yılmaz, S. İde, “Synthesis, spectroscopic characterization and X-ray single crystal structures of trans-bis [4-methoxyphenyl (3-methylbutyl) dithiophosphinato] nickel(II) and bis [4-methoxyphenyl (3-methylbutyl) dithiophosphinato]cobalt(II) complexes” Transition Metal Chemistry, (2010), 35, 399-405.
  • [20] R.G. Cavell, W. Byers, E.D. Day, P.M. Watkins, “Metal complexes of substituted dithiophosphinic acids. IV. Complexes of divalent nickel, palladium, and platinum” Inorganic Chemistry, (1972), 11, 1598.
  • [21] R.G. Cavell, E.D. Day, W. Byers, P.M. Watkins, “Metal complexes of substituted dithiophosphinic acids. V. Complexes of manganese, iron, and cobalt” Inorganic Chemistry, (1972), 11, 1759.
  • [22] I. Haiduc, “Supramolecular associations, secondary bonds, quasi-cyclic structures and heterogeometrism in metal derivatives of phosphorus- and arsenic-based thioacids and oxo analogs” Coordination Chemistry Reviews, (1997), 158, 325.
  • [23] A.A. Pinkerton, F.P. Ahlers, H.F. Greiwing, B. Krebs, “Dithiophosphinate complexes of the UO22+ ion containing a coordinated water molecule-solid state structures and stereochemical rigidity in solution” Inorganica Chimica Acta (1997), 257, 77.
  • [24] J.S. Casas, M.S. García-Tasende, A. Sánchez, J. Sordo, E.E. Castellano, J. Zukerman-Schpector, “Synthesis, crystal structure and spectroscopic properties of bis(diphenyldithiophosphinato)cadmium(II)”Inorganica Chimica Acta (1994), 219, 115.
  • [25] C. Byrom, M.A. Malik, P. O’Brien, A. J. P. White, D.J. Williams, “Synthesis and X-ray single crystal structures of bis (diisobutyldithiophosphinato) cadmium(II) or zinc(II): Potential single-source precursors for II/VI materials” Polyhedron, (2000), 19, 211.
  • [26] M. Calligaris, G. Nardin, A. Ripamonti, “Crystal and molecular structure of zinc(II) and cobalt(II) diethyldithiophosphinates” Journal of the Chemical Society A: Inorganic, Physical, Theoretical, (1970), 714-722.
  • [27] H. Keck, W. Kuchen, “Massenspektrometrische Untersuchungen An Organophosphorverbindungen IV. Über den massenspektrometrischen Zerfall von Dithiophosphinsären” Phosphorus, Sulfur Silicon Related Elements, (1983), 14, 225.
  • [28] E.G. Sağlam, H. Yılmaz, H. Dal, T. Hökelek, “Synthesis and Spectroscopic Characterizations of Novel Ni(II) and Co(II) Dithiophosphinate Complexes, and X-Ray Studies on the Ni(II) Complex”, Phosphorus, Sulfur Silicon Related Elements, (2012), 187, 213-224.
  • [29] A. Nimairatan, and N. Saha, "Synthesis and spectroscopic characterization of palladium (II) and platinum (II) complexes with substituted pyrazoles" Asian Journal of Chemistry, (2008), 20, 521-529.
  • [30] M. Karakus, H. Yılmaz, “Synthesis and characterization of Ni(II), Zn(II), and Cd(II) complexes with dithiophosphonate derivatives”, Russian Journal of Coordination Chemistry, (2006), 32, 437–443.
There are 30 citations in total.

Details

Primary Language Turkish
Subjects Transition Metal Chemistry, Organometallic Chemistry
Journal Section Research Articles
Authors

Ahsen Albaş 0009-0006-6118-2364

Elif Bulat 0000-0002-2164-3641

Ertuğrul Gazi Sağlam 0000-0002-7719-3934

Project Number 1919B012212041
Publication Date May 22, 2024
Submission Date November 17, 2023
Acceptance Date January 31, 2024
Published in Issue Year 2024 Volume: 4 Issue: 1

Cite

APA Albaş, A., Bulat, E., & Sağlam, E. G. (2024). Yeni Palladyum Ditiyofosfinato Kompleksi Sentezi ve Yapısının Aydınlatılması. Ata-Kimya Dergisi, 4(1), 12-19. https://doi.org/10.5281/zenodo.11219364
AMA Albaş A, Bulat E, Sağlam EG. Yeni Palladyum Ditiyofosfinato Kompleksi Sentezi ve Yapısının Aydınlatılması. J Ata-Chem. May 2024;4(1):12-19. doi:10.5281/zenodo.11219364
Chicago Albaş, Ahsen, Elif Bulat, and Ertuğrul Gazi Sağlam. “Yeni Palladyum Ditiyofosfinato Kompleksi Sentezi Ve Yapısının Aydınlatılması”. Ata-Kimya Dergisi 4, no. 1 (May 2024): 12-19. https://doi.org/10.5281/zenodo.11219364.
EndNote Albaş A, Bulat E, Sağlam EG (May 1, 2024) Yeni Palladyum Ditiyofosfinato Kompleksi Sentezi ve Yapısının Aydınlatılması. Ata-Kimya Dergisi 4 1 12–19.
IEEE A. Albaş, E. Bulat, and E. G. Sağlam, “Yeni Palladyum Ditiyofosfinato Kompleksi Sentezi ve Yapısının Aydınlatılması”, J Ata-Chem, vol. 4, no. 1, pp. 12–19, 2024, doi: 10.5281/zenodo.11219364.
ISNAD Albaş, Ahsen et al. “Yeni Palladyum Ditiyofosfinato Kompleksi Sentezi Ve Yapısının Aydınlatılması”. Ata-Kimya Dergisi 4/1 (May 2024), 12-19. https://doi.org/10.5281/zenodo.11219364.
JAMA Albaş A, Bulat E, Sağlam EG. Yeni Palladyum Ditiyofosfinato Kompleksi Sentezi ve Yapısının Aydınlatılması. J Ata-Chem. 2024;4:12–19.
MLA Albaş, Ahsen et al. “Yeni Palladyum Ditiyofosfinato Kompleksi Sentezi Ve Yapısının Aydınlatılması”. Ata-Kimya Dergisi, vol. 4, no. 1, 2024, pp. 12-19, doi:10.5281/zenodo.11219364.
Vancouver Albaş A, Bulat E, Sağlam EG. Yeni Palladyum Ditiyofosfinato Kompleksi Sentezi ve Yapısının Aydınlatılması. J Ata-Chem. 2024;4(1):12-9.

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