Research Article

A Novel Azo-Schiff Base Ligand and Its Cobalt, Copper, Nickel Complexes: Synthesis, Characterization, Antimicrobial, Catalytic and Electrochemical Features

Volume: 17 Number: 2 July 14, 2016
TR EN

A Novel Azo-Schiff Base Ligand and Its Cobalt, Copper, Nickel Complexes: Synthesis, Characterization, Antimicrobial, Catalytic and Electrochemical Features

Abstract

A new azo containing Schiff base were synthesized using 3-amino-3-azabicyclo[3.3.0]octane hydrochloride, salicylaldehyde and aniline. The synthesized ligand were reacted with acetate salts of Cobalt (II), Copper (II) and Nickel (II). Synthesized compounds were characterized using spectral techniques. Metal coordination compounds gave good/moderate results as catalysts in the oxidation reactions of styrene and cyclohexene. Antimicrobial activities of the synthesized compounds showed good suppressor effects on a number of Gram (-) and Gram (+) bacteria. Electronic features of all the compounds were also reported.

Keywords

Azoimine, Coordination, Catalysis, Antimicrobial, Electronic

References

  1. Eren T, Kose M, Sayin K, McKee V, Kurtoglu M. A novel azo-aldehyde and its Ni(II) chelate; synthesis, characterization, crystal structure and computational studies of 2-hydroxy-5-{(E)-[4- (propan-2-yl)phenyl]diazenyl}benzaldehyde. J Mol Struct 2014; 1065-1066: 191-198.
  2. Coelho PJ, Castro MCR, Fonseca AMC, Raposo MMM.Photoswitching in azo dyes bearing thienylpyrrole and benzothiazole heterocyclic systems. Dyes Pigments 2012; 92(1): 745–748.
  3. Sridev S, Hiremath SU, Yelamaggad CV, Prasad SK, Marinov YG, Hadjichristov GB, Petrov AG. Behaviour of photosensitive soft materials: Thermo-optical, dielectric and elastic constant studies on azo-dye doped nematic liquid crystals. Mater Chem Phys 2011; 130: 1329-1335.
  4. Bal M, Ceyhan G, Avar B, Kose M, Kayraldız A, Kurtoglu M. Synthesis and X-ray powder diffraction, electrochemical, and genotoxic properties of a new azo-Schiff base and its metal complexes. Turk J Chem 2014; 38: 222-241.
  5. Kurtoglu M, Ispir E, Kurtoglu N, Serin S. Novel vic-dioximes: Synthesis, complexation with transition metal ions, spectral studies and biological activity. Dyes Pigments 2008; 77: 75-80.
  6. Dimiza F, Papadopoulos AN, Tangoulis V, Psycharis V, Raptopoulou CP, Kessissoglou DP, Psomas G. Biological evaluation of non-steroidal anti-inflammatory drugs-cobalt(II) complexes. Dalton Trans 2010; 39: 4517-4528.
  7. Abd-Elzaher MM, Moustafa SA, Labib AA, Ali MM. Synthesis, characterization, and anticancer properties of ferrocenyl complexes containing a salicylaldehyde moiety. Monatsh Chem 2010; 141: 387-393.
  8. Ispir E. The synthesis, characterization, electrochemical character, catalytic and antimicrobial activity of novel, azo-containing schiff bases and their metal complexes. Dyes Pigments 2009; 82: 13- 19.
  9. Ozdemir M. Catalytic activities of novel silica-supported multifunctional Schiff base ligand & metal complexes under microwave irradiation. Inorg Chim Acta 2014; 421: 1-9.
  10. Urus S, Dolaz M, Tumer M. Synthesis and Catalytic Activities of Silica-Supported Multifunctional Azo-Containing Schiff Base Complexes with Cu(II), Co(II), Ni(II) and Mn(II). J Inorg Organomet Polym 2010; 20: 706-713.
APA
Bal, S. (2016). A Novel Azo-Schiff Base Ligand and Its Cobalt, Copper, Nickel Complexes: Synthesis, Characterization, Antimicrobial, Catalytic and Electrochemical Features. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, 17(2), 315-326. https://doi.org/10.18038/btda.42413
AMA
1.Bal S. A Novel Azo-Schiff Base Ligand and Its Cobalt, Copper, Nickel Complexes: Synthesis, Characterization, Antimicrobial, Catalytic and Electrochemical Features. AUJST-A. 2016;17(2):315-326. doi:10.18038/btda.42413
Chicago
Bal, Selma. 2016. “A Novel Azo-Schiff Base Ligand and Its Cobalt, Copper, Nickel Complexes: Synthesis, Characterization, Antimicrobial, Catalytic and Electrochemical Features”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 17 (2): 315-26. https://doi.org/10.18038/btda.42413.
EndNote
Bal S (August 1, 2016) A Novel Azo-Schiff Base Ligand and Its Cobalt, Copper, Nickel Complexes: Synthesis, Characterization, Antimicrobial, Catalytic and Electrochemical Features. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 17 2 315–326.
IEEE
[1]S. Bal, “A Novel Azo-Schiff Base Ligand and Its Cobalt, Copper, Nickel Complexes: Synthesis, Characterization, Antimicrobial, Catalytic and Electrochemical Features”, AUJST-A, vol. 17, no. 2, pp. 315–326, Aug. 2016, doi: 10.18038/btda.42413.
ISNAD
Bal, Selma. “A Novel Azo-Schiff Base Ligand and Its Cobalt, Copper, Nickel Complexes: Synthesis, Characterization, Antimicrobial, Catalytic and Electrochemical Features”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 17/2 (August 1, 2016): 315-326. https://doi.org/10.18038/btda.42413.
JAMA
1.Bal S. A Novel Azo-Schiff Base Ligand and Its Cobalt, Copper, Nickel Complexes: Synthesis, Characterization, Antimicrobial, Catalytic and Electrochemical Features. AUJST-A. 2016;17:315–326.
MLA
Bal, Selma. “A Novel Azo-Schiff Base Ligand and Its Cobalt, Copper, Nickel Complexes: Synthesis, Characterization, Antimicrobial, Catalytic and Electrochemical Features”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, vol. 17, no. 2, Aug. 2016, pp. 315-26, doi:10.18038/btda.42413.
Vancouver
1.Selma Bal. A Novel Azo-Schiff Base Ligand and Its Cobalt, Copper, Nickel Complexes: Synthesis, Characterization, Antimicrobial, Catalytic and Electrochemical Features. AUJST-A. 2016 Aug. 1;17(2):315-26. doi:10.18038/btda.42413