Photoluminescence properties of Gd(III) and Ce(III) lanthanide based metal organic frameworks

Yasemin Acar

doi:10.18038/aubtda.267272

EN

Photoluminescence properties of Gd(III) and Ce(III) lanthanide based metal organic frameworks

Abstract

The Gd(III) and Ce(III) based-MOFs (metal organic frameworks) have been synthesized by hydrothermal method using 1,2,4,5benzenetetracarboxylate (btec) ligand and characterized by elemental analysis, FT-IR, UV-visible and single-crystal X-ray diffraction. The crystal structure analysis of Gd(III) complex [C₁₀H₉GdO₁₁] (1) and Ce (III) complex [C₁₀H₅CeO₉] (2) show that the central lanthanide ions are coordinated by nine oxygen atoms in which eight O atoms from btec ligands and one O atom from water molecule for both structures. The nearest non-bonding Gd···Gd distance is 3.928 Å while Ce···Ce distance is 4.392 Å. Complex 1 and 2 bridged by oxygen atoms of btec ligands are formed in 3D networks via strong hydrogen bonds. Additionally, solid state photoluminescence properties of 1 and 2 at room temperature have been investigated. Under the excitation of UV light, intense cyan-blue emission for complex 1 and blue emission for complex 2 are exhibited in the visible regions.

Keywords

Metal-Organic Frameworks,Lanthanide Complexes,Structural Analysis,Photoluminescence Properties

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Details

Primary Language

English

Subjects

Engineering

Journal Section

Research Article

Authors

Yasemin Acar
Balıkesir Üniversitesi, Balıkesir, Türkiye
Türkiye

Publication Date

December 1, 2016

Submission Date

November 21, 2016

Acceptance Date

November 22, 2016

Published in Issue

Year 2016 Volume: 17 Number: 4

DOI

https://doi.org/10.18038/aubtda.267272

IZ

https://izlik.org/JA53RX79TG

APA

Acar, Y. (2016). Photoluminescence properties of Gd(III) and Ce(III) lanthanide based metal organic frameworks. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, 17(4), 754-765. https://doi.org/10.18038/aubtda.267272

AMA

1.Acar Y. Photoluminescence properties of Gd(III) and Ce(III) lanthanide based metal organic frameworks. AUJST-A. 2016;17(4):754-765. doi:10.18038/aubtda.267272

Chicago

Acar, Yasemin. 2016. “Photoluminescence Properties of Gd(III) and Ce(III) Lanthanide Based Metal Organic Frameworks”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 17 (4): 754-65. https://doi.org/10.18038/aubtda.267272.

EndNote

Acar Y (December 1, 2016) Photoluminescence properties of Gd(III) and Ce(III) lanthanide based metal organic frameworks. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 17 4 754–765.

IEEE

[1]Y. Acar, “Photoluminescence properties of Gd(III) and Ce(III) lanthanide based metal organic frameworks”, AUJST-A, vol. 17, no. 4, pp. 754–765, Dec. 2016, doi: 10.18038/aubtda.267272.

ISNAD

Acar, Yasemin. “Photoluminescence Properties of Gd(III) and Ce(III) Lanthanide Based Metal Organic Frameworks”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 17/4 (December 1, 2016): 754-765. https://doi.org/10.18038/aubtda.267272.

JAMA

1.Acar Y. Photoluminescence properties of Gd(III) and Ce(III) lanthanide based metal organic frameworks. AUJST-A. 2016;17:754–765.

MLA

Acar, Yasemin. “Photoluminescence Properties of Gd(III) and Ce(III) Lanthanide Based Metal Organic Frameworks”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, vol. 17, no. 4, Dec. 2016, pp. 754-65, doi:10.18038/aubtda.267272.

Vancouver

1.Yasemin Acar. Photoluminescence properties of Gd(III) and Ce(III) lanthanide based metal organic frameworks. AUJST-A. 2016 Dec. 1;17(4):754-65. doi:10.18038/aubtda.267272

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