Research Article
BibTex RIS Cite

PRODUCTION OF BLUE CO-ALUMINATE PIGMENTS FOR INK JET INKS

Year 2015, Volume: 16 Issue: 3, 339 - 349, 30.12.2015
https://doi.org/10.18038/btda.32022

Abstract

In ceramic industry, ink-jet decoration has been became a widespread technique in recent years because of providing high quality decoration and allowing to use standard color inks. The inks used in inkjet printing are prepared by using submicron-sized pigments (<500 nm). In this study, synthesis of blue Co-aluminate (CoAl2O4) pigment by ceramic method with Co3O4ve Al2O3 raw materials, grinding of stable suspensions that were prepared with addition of 0.3 wt.% Darvan C and 1 wt.% STPP as dispersant in attrition and planetary ball mill and color properties were investigated. In the suspension containing Darvan C in planetary ball mill, higher grinding efficiency were obtained comparing to attrition milling. Blue Co-aluminate pigment was ground successfully to 230 nm after 240 min in planetary ball mill. Although, contamination of ZrO2 comes from balls and grinder, surface charge and isoelectric point of pigments were not affected. It was determined that colour shade changes from blue to turquoise blue with degreasing of particle size of pigments. However, this alteration did not affect the colour shade of pigments after firing. As a result, it was revealed that there is no negative effect of grinding proses on chemical and thermal colour stability on Co-aluminate pigments and Co-aluminate pigments have a using potential in ceramic ink-jet inks by grinding to submicron size. 

References

  • Akdemir, S., Ozel E., and Suvaci, E. (2011) Solubility of Blue CoAl2O4 Ceramic Pigments in Water and DEG, Ceramics International 37, 863-870.
  • Atkinson, A., Doorbar, J., Hudd, A., Segal, D.L. ve White P.J. (1997) Continuous Ink-Jet Printing using Sol-Gel Journal of Sol-Gel Science and Technology 8, 1093–1097.
  • Berns, R.S. (2000) Billmeyer and Saltzman’s Principles of Color Technology, John Wiley & Sons, Inc. USA.
  • Burns, R.G. (1970) Mineralogical application of crystal field theory, Cambridge yayınları, Cambridge.
  • Busca, G., Lorenzelli, V., Bolis, V. (1992) Preparation, Bulk Characterization and Surface-Chemistry of High-Surface-Area Cobalt Aluminate, Materials Chemistry and Physics 31(3) 221-228.
  • Chen, Z., Shi, E., Li, W., Zheng, Y., ve Zhong, W. (2002) Hydrothermal Synthesis and Optical Property of Nano-Sized CoAlO4 Pigment, Materials Letters 55, 281– 284.
  • Coste, S., Bertrand, G., Coddet, C., Gaffet, E., Hahn, H., Sieger, H. (2007) High-Energy Ball Milling of AlO3-TiO2 Powders, Journal of Alloys and Compounds, 434- 435, 489-492.
  • Cullity (1956) Elements of x-ray diffraction, Addison-Wesley Publishing Company, USA.
  • Eser, O., Kurama, S. (2010) The Effect of the Wet-milling Process on Sintering Temperature and the Amount of Additive of International 36 (4)1283-1288. Ceramics
  • Hassibi, M., Rogers, K.J., ve Yang, M. (1999) Advances in Fine Grinding and Mill System Application in the FGD Industry, Atlanta, Georgia, USA.
  • Hogg, R. ve Cho, H. (2000) A Review of Breakage Behavior in Fine Grinding by Stirred Media Milling, Powder Science and Technology in Japan, Kona, 18, 9-19.
  • Hoppert, H. (1996) Do All Grinding Balls Have The Same Quality, Interceram, 45, 166- 173.
  • ICS (2003) Colour, Pigments and Colouring in Ceramics, Italian Ceramic Society, SALA, Italia.
  • Nassau, K. (2001) The Physics and Chemistry of Color, JohnWilley and Sons. Inc.USA.
  • Raimando, M., ve Baldi, G. (2009) Colour Performance of Ceramic Nano-Pigments, Dyes and Pigments, 80, 226-232.
  • Reed, J. (1995) Principals of Ceramic Processing, John Wiley & Sons, Inc. (US).
  • Shaw, D.J. (1992) Introduction to Colloid and Surface Heizemenn, Oxford. Butterworth
  • Sommer, M., Stenger, F., Peukert, W., Wagner, N.J. (2006) Agglomeration and Breakage of Nanoparticles in Stirred Media Mills-a Comparison of Different Methods and Models, Chemical Engineering Science 61, 135-148.
  • Szegvarı, A., Yang, M. (1999) Attrition Grinding and Dispersing Equipment, Union Process Inc.
  • Tusseau-nenez, S., Ganne, J.P., Maglione, M., Morell, A., Niepce, J.C and Pate, M. (2004) BST: Effect of Attrition Milling on Dielectric Properties, Journal of European Ceramic Society, 24, 3003-3011.
  • Vari, A. (2004) Raw Materials Preparation and Forming of Ceramic Tiles, Sala, Italy.
  • Varinot, C., Hiltgun, S., Pons, M., ve Dodds, J. (1997) Identification of the Fragmentation Mechanisms in Wet-Phase Fine Grinding in A Stirred Bead Mill, Chemical Engineering Science, 52, 3605-3612.
  • Yungevis, H and Ozel, E. (2013), Effect of the Milling Process on the Properties of CoFe2O4 Pigment, Ceramics International 39, 5503-5511.
  • Zheng, J., Colin, C., Harris, S. P. (1997) The Effect of Additives on Stirred Media Milling Technology, 91, 173-179. Powder

İNKJET MÜREKKEPLERİ İÇİN MAVİ CO-ALÜMİNAT PİGMENTLERİNİN ÜRETİLMESİ

Year 2015, Volume: 16 Issue: 3, 339 - 349, 30.12.2015
https://doi.org/10.18038/btda.32022

Abstract

Seramik endüstrisinde inkjet baskılama tekniği, yüksek kalitede dekorlama ve standart renkte mürekkeplerin kullanımına olanak sağlaması açısından gün geçtikçe yaygınlaşan bir dekorlama tekniğidir. Bu teknikte kullanılan mürekkepler mikron altı ( < 500 nm) pigmentler ile hazırlanmaktadır. Bu çalışmada inkjet mürekkep renklerinden biri olan mavi Co-aluminat pigmentinin Co3O4 ve Al2O3 hammaddeleri kullanılarak geleneksel yöntemle sentezlenmesi, tozlardan ağırlıkça % 0,3 oranında Darvan C veya % 1 STPP ilavesiyle kararlı süspansiyonlar hazırlanarak atritör ve eksenel değirmenlerde öğütülebilirliği ve renk özellikleri araştırılmıştır. Darvan C içeren pigment süspansiyonlarının eksenel değirmenle öğütülmesi sonucunda atritör değirmenle öğütülmeye kıyasla daha yüksek öğütme verimi sağlamıştır. Mavi renkli Co-aluminat pigmenti, eksenel değirmenle 240 dak sonunda 230 nm tane boyutuna başarıyla öğütülmüştür. Öğütücü hazne ve bilyelerden ZrO2 kirliliği gelmesine rağmen pigmentlerin yüzey yükü ve izoelektrik noktası etkilenmemiştir. Pigment tozlarının tane boyutu azaldıkça renk tonunda mavi renkten mavi-turkuvaz renge doğru değişim olduğu tespit edilmiştir. Ancak bu değişim, pişirim sonrasında rengin kromasını önemli derecede etkilememiştir. Sonuç olarak öğütme sürecinin, Co-Alüminat pigmentinin kimyasal ve termal renk kararlılığı üzerine olumsuz yönde bir etkisinin bulunmadığı ve Co-aluminat pigmentinin mikron altı boyutlara öğütülerek inkjet mürekkeplerinde kullanılabileceği ortaya çıkartılmıştır.

References

  • Akdemir, S., Ozel E., and Suvaci, E. (2011) Solubility of Blue CoAl2O4 Ceramic Pigments in Water and DEG, Ceramics International 37, 863-870.
  • Atkinson, A., Doorbar, J., Hudd, A., Segal, D.L. ve White P.J. (1997) Continuous Ink-Jet Printing using Sol-Gel Journal of Sol-Gel Science and Technology 8, 1093–1097.
  • Berns, R.S. (2000) Billmeyer and Saltzman’s Principles of Color Technology, John Wiley & Sons, Inc. USA.
  • Burns, R.G. (1970) Mineralogical application of crystal field theory, Cambridge yayınları, Cambridge.
  • Busca, G., Lorenzelli, V., Bolis, V. (1992) Preparation, Bulk Characterization and Surface-Chemistry of High-Surface-Area Cobalt Aluminate, Materials Chemistry and Physics 31(3) 221-228.
  • Chen, Z., Shi, E., Li, W., Zheng, Y., ve Zhong, W. (2002) Hydrothermal Synthesis and Optical Property of Nano-Sized CoAlO4 Pigment, Materials Letters 55, 281– 284.
  • Coste, S., Bertrand, G., Coddet, C., Gaffet, E., Hahn, H., Sieger, H. (2007) High-Energy Ball Milling of AlO3-TiO2 Powders, Journal of Alloys and Compounds, 434- 435, 489-492.
  • Cullity (1956) Elements of x-ray diffraction, Addison-Wesley Publishing Company, USA.
  • Eser, O., Kurama, S. (2010) The Effect of the Wet-milling Process on Sintering Temperature and the Amount of Additive of International 36 (4)1283-1288. Ceramics
  • Hassibi, M., Rogers, K.J., ve Yang, M. (1999) Advances in Fine Grinding and Mill System Application in the FGD Industry, Atlanta, Georgia, USA.
  • Hogg, R. ve Cho, H. (2000) A Review of Breakage Behavior in Fine Grinding by Stirred Media Milling, Powder Science and Technology in Japan, Kona, 18, 9-19.
  • Hoppert, H. (1996) Do All Grinding Balls Have The Same Quality, Interceram, 45, 166- 173.
  • ICS (2003) Colour, Pigments and Colouring in Ceramics, Italian Ceramic Society, SALA, Italia.
  • Nassau, K. (2001) The Physics and Chemistry of Color, JohnWilley and Sons. Inc.USA.
  • Raimando, M., ve Baldi, G. (2009) Colour Performance of Ceramic Nano-Pigments, Dyes and Pigments, 80, 226-232.
  • Reed, J. (1995) Principals of Ceramic Processing, John Wiley & Sons, Inc. (US).
  • Shaw, D.J. (1992) Introduction to Colloid and Surface Heizemenn, Oxford. Butterworth
  • Sommer, M., Stenger, F., Peukert, W., Wagner, N.J. (2006) Agglomeration and Breakage of Nanoparticles in Stirred Media Mills-a Comparison of Different Methods and Models, Chemical Engineering Science 61, 135-148.
  • Szegvarı, A., Yang, M. (1999) Attrition Grinding and Dispersing Equipment, Union Process Inc.
  • Tusseau-nenez, S., Ganne, J.P., Maglione, M., Morell, A., Niepce, J.C and Pate, M. (2004) BST: Effect of Attrition Milling on Dielectric Properties, Journal of European Ceramic Society, 24, 3003-3011.
  • Vari, A. (2004) Raw Materials Preparation and Forming of Ceramic Tiles, Sala, Italy.
  • Varinot, C., Hiltgun, S., Pons, M., ve Dodds, J. (1997) Identification of the Fragmentation Mechanisms in Wet-Phase Fine Grinding in A Stirred Bead Mill, Chemical Engineering Science, 52, 3605-3612.
  • Yungevis, H and Ozel, E. (2013), Effect of the Milling Process on the Properties of CoFe2O4 Pigment, Ceramics International 39, 5503-5511.
  • Zheng, J., Colin, C., Harris, S. P. (1997) The Effect of Additives on Stirred Media Milling Technology, 91, 173-179. Powder
There are 24 citations in total.

Details

Primary Language Turkish
Subjects Engineering
Journal Section Articles
Authors

Sema Akdemir This is me

Emel Özel

Publication Date December 30, 2015
Published in Issue Year 2015 Volume: 16 Issue: 3

Cite

APA Akdemir, S., & Özel, E. (2015). İNKJET MÜREKKEPLERİ İÇİN MAVİ CO-ALÜMİNAT PİGMENTLERİNİN ÜRETİLMESİ. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, 16(3), 339-349. https://doi.org/10.18038/btda.32022
AMA Akdemir S, Özel E. İNKJET MÜREKKEPLERİ İÇİN MAVİ CO-ALÜMİNAT PİGMENTLERİNİN ÜRETİLMESİ. AUJST-A. December 2015;16(3):339-349. doi:10.18038/btda.32022
Chicago Akdemir, Sema, and Emel Özel. “İNKJET MÜREKKEPLERİ İÇİN MAVİ CO-ALÜMİNAT PİGMENTLERİNİN ÜRETİLMESİ”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 16, no. 3 (December 2015): 339-49. https://doi.org/10.18038/btda.32022.
EndNote Akdemir S, Özel E (December 1, 2015) İNKJET MÜREKKEPLERİ İÇİN MAVİ CO-ALÜMİNAT PİGMENTLERİNİN ÜRETİLMESİ. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 16 3 339–349.
IEEE S. Akdemir and E. Özel, “İNKJET MÜREKKEPLERİ İÇİN MAVİ CO-ALÜMİNAT PİGMENTLERİNİN ÜRETİLMESİ”, AUJST-A, vol. 16, no. 3, pp. 339–349, 2015, doi: 10.18038/btda.32022.
ISNAD Akdemir, Sema - Özel, Emel. “İNKJET MÜREKKEPLERİ İÇİN MAVİ CO-ALÜMİNAT PİGMENTLERİNİN ÜRETİLMESİ”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 16/3 (December 2015), 339-349. https://doi.org/10.18038/btda.32022.
JAMA Akdemir S, Özel E. İNKJET MÜREKKEPLERİ İÇİN MAVİ CO-ALÜMİNAT PİGMENTLERİNİN ÜRETİLMESİ. AUJST-A. 2015;16:339–349.
MLA Akdemir, Sema and Emel Özel. “İNKJET MÜREKKEPLERİ İÇİN MAVİ CO-ALÜMİNAT PİGMENTLERİNİN ÜRETİLMESİ”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, vol. 16, no. 3, 2015, pp. 339-4, doi:10.18038/btda.32022.
Vancouver Akdemir S, Özel E. İNKJET MÜREKKEPLERİ İÇİN MAVİ CO-ALÜMİNAT PİGMENTLERİNİN ÜRETİLMESİ. AUJST-A. 2015;16(3):339-4.