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Degradation of ethylparaben using photo-Fenton-like oxidation over BiFeO3

Year 2016, Volume: 17 Issue: 5, 915 - 925, 20.12.2016
https://doi.org/10.18038/aubtda.279859

Abstract

The degradation of ethylparaben using photo-Fenton-like oxidation was investigated in the presence of a BiFeO3 catalyst. Firstly, the catalyst was synthesized using the sol-gel method and then, a parametric study was carried out in order to determine the optimum reaction conditions for the degradation of ethylparaben. In this context, the effects of catalyst loading, [H2O2]o, pH, and temperature on the degradation were investigated. According to the results, the optimum reaction conditions were determined for a 5 ppm ethylparaben solution as 0.25 g/L catalyst loading, a pH of 3, and 2 mM [H2O2]oand a 97.7% degradation of ethylparaben was accomplished. Iron leaching at the optimum conditions was evaluated as 1.53 ppm and it is lower than the E.U. iron concentration limitation (2 ppm) in the water. The kinetic study was carried out at the optimum reaction conditions at three different temperatures (25, 35, and 45 °C). The degradation of ethylparaben using photo-Fenton-like oxidation fitted the first order reaction kinetic model. The reaction rate constants were determined as 0.041, 0.050, and 0.069 min-1 for 25, 35, and 45 °C, respectively. The activation energy was found as 20.4 kJ/mol. 

Year 2016, Volume: 17 Issue: 5, 915 - 925, 20.12.2016
https://doi.org/10.18038/aubtda.279859

Abstract

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Details

Subjects Engineering
Journal Section Articles
Authors

Ceren Orak

Süheyda Atalay

Gülin Ersöz

Publication Date December 20, 2016
Published in Issue Year 2016 Volume: 17 Issue: 5

Cite

APA Orak, C., Atalay, S., & Ersöz, G. (2016). Degradation of ethylparaben using photo-Fenton-like oxidation over BiFeO3. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, 17(5), 915-925. https://doi.org/10.18038/aubtda.279859
AMA Orak C, Atalay S, Ersöz G. Degradation of ethylparaben using photo-Fenton-like oxidation over BiFeO3. AUJST-A. December 2016;17(5):915-925. doi:10.18038/aubtda.279859
Chicago Orak, Ceren, Süheyda Atalay, and Gülin Ersöz. “Degradation of Ethylparaben Using Photo-Fenton-Like Oxidation over BiFeO3”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 17, no. 5 (December 2016): 915-25. https://doi.org/10.18038/aubtda.279859.
EndNote Orak C, Atalay S, Ersöz G (December 1, 2016) Degradation of ethylparaben using photo-Fenton-like oxidation over BiFeO3. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 17 5 915–925.
IEEE C. Orak, S. Atalay, and G. Ersöz, “Degradation of ethylparaben using photo-Fenton-like oxidation over BiFeO3”, AUJST-A, vol. 17, no. 5, pp. 915–925, 2016, doi: 10.18038/aubtda.279859.
ISNAD Orak, Ceren et al. “Degradation of Ethylparaben Using Photo-Fenton-Like Oxidation over BiFeO3”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 17/5 (December 2016), 915-925. https://doi.org/10.18038/aubtda.279859.
JAMA Orak C, Atalay S, Ersöz G. Degradation of ethylparaben using photo-Fenton-like oxidation over BiFeO3. AUJST-A. 2016;17:915–925.
MLA Orak, Ceren et al. “Degradation of Ethylparaben Using Photo-Fenton-Like Oxidation over BiFeO3”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, vol. 17, no. 5, 2016, pp. 915-2, doi:10.18038/aubtda.279859.
Vancouver Orak C, Atalay S, Ersöz G. Degradation of ethylparaben using photo-Fenton-like oxidation over BiFeO3. AUJST-A. 2016;17(5):915-2.