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AMBIENT CONCENTRATIONS OF ELEMENTAL AND ORGANIC CARBON IN URBAN AND SUBURBAN ATMOSPHERES IN ESKİSEHİR: ESTIMATION OF THE SECONDARY ORGANIC CARBON

Year 2017, Volume: 18 Issue: 2, 429 - 438, 30.06.2017
https://doi.org/10.18038/aubtda.299876

Abstract

Ambient air particulate matter samples were collected from
urban and suburban sites of Eskişehir in 2012. Samples were collected concurrently from both
sites between 26th of February and 20th of December 2012.
Mass concentrations of particulate matter (fine particles-PM2.5, coarse particles-PM2.5-10and total suspended
particulate matter-TSP) were
determined. TSP samples were analyzed by Thermal Optical Carbon Analyzer to
determine elemental carbon (EC), organic carbon (OC) and total carbon (TC)
concentrations.  It was found that 4.9%
of the TSP is composed of EC, and 13.6 % is OC in urban sampling point. EC and
OC contributions in suburban sampling points were 2.7% and 9.6% respectively. OC/EC
ratio was found to be  almost 1.5 times
higher in suburban sampling site compared to urban sampling site. EC tracer
method was used to estimate the contribution of Secondary Organic Carbon (SOC).
The SOC percent of TSP was estimated as 7.1 % and 5.6 % for the urban and
suburban locations respectively.




References

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  • [2] IPCC. Climate Change 1994: radiative forcing of climate change and an evaluation of the IPCC IS92 emission scenarios. Cambridge University Press, New York, 1995.
  • [3] Hildemann LM, Rogge WF, Cass GR, Mazurek MA, Simoneit BRT. Contribution of primary aerosol emissions from vegetation-derived sources to fine particle concentrations in Los Angeles, Journal of Geophysical Research 1996; 101:19541-19549.
  • [4] Castro LM, Pio CA, Harrison, RM, Smith DJT. Carbonaceous aerosol in urban and rural European atmospheres: estimation of secondary organic carbon concentrations. Atmospheric Environment 1999: 33:2771-2781.
  • [5] Huang L, Brook JR, Zhang W, Li SM, Graham, L, Ernst D, Chivulescu A, Lu G. Stable isotope measurements of carbon fractions (OC/EC) in airborne particulate, A new dimension for source characterization and apportionment. Atmospheric Environment 2006; 40: 2690-2705.
  • [6] Jaoui M, Kleindienst E, Lewandowski M, Edney EO. Identification and quantification of aerosol polar oxygenated compounds bearing carboxylic or hydroxyl groups. 1. Method development. Analytical Chemistry 2004;76: 4765 – 4778.
  • [7] Jaoui M, Kleindienst E, Lewandowski M, Offenberg JH, Edney EO. Identification and quantification of aerosol polar oxygenated compounds bearing carboxylic or hydroxyl groups. 2. Organic tracer compounds from monoterpenes. Environmental Science and Technology 2005; 39: 5661-5673.
  • [8] Strader R, Lurmann F, Pandis SN, Evaluation of secondary organic aerosol formation in winter, Atmospheric Environment, 33, 4849 – 4863, (1999).
  • [9] Yu S, Dennis RL, Bhave PV, Eder BK. Primary and secondary organic aerosols over the United States, estimates on the basis of observed organic carbon (OC) and elemental carbon (EC), and air quality modeled primary OC/EC ratios. Atmospheric Environment 2004; 38: 5257 – 5268.
  • [10] Chu SH. Stable estimate of primary OC/EC ratios in the EC tracer method. Atmospheric Environment, 2005;39:1383-1392.
  • [11] Pio C, Cerqueira M, Harrison RM, Nunes T, Mirante F, Alves C, Oliveira C, Sanches de la Campa A, Artinano B, Matos M. OC/EC ratio observed in Europe: re-thinking the approach for apportionment between primary and secondary organic carbon. Atmospheric Environment 2011; 45: 6121-6132.
  • [12] Turpin BJ, Huntzicker JJ. Identification of secondary organic aerosol episodes and quantification of primary and secondary organic aerosol concentrations during SCAQS. Atmospheric Environment 1995; 29:3527-3544.
  • [13] Saffari A, Hasheminassab S, Shafer MM, Schauer JJ, Chatila TA, Sioutas C. Nighttime aqueous-phase secondary organic aerosols in Los Angeles and its implication for fine particulate matter composition and oxidative potential. Atmospheric Environment 2016; 133: 112-122.
  • [14] Saylor RD, Edgerton ES, Hartsell BE. Linear regression techniques for use in the EC tracer method of secondary organic aerosol estimation. Atmospheric Environment 2006; 40: 7546-7556.
  • [15] Clarke AG, Willison MJ, Zeki EM. A comparison of urban and rural aerosol composition using dichotomous samplers. Atmospheric Environment 1967; 18: 1767-1775.
  • [16] Poor N, Clark T, Nye L, Tamanini T, Tate K, Stevens R, Atkeson T. Field performance of dichotomous sequential PM air samplers. Atmospheric Environment 2002; 36:3289-3298.
  • [17] Sharma SK, Mandal TK, Saxena M, Sharma A, Datta A, Saud T. Variation of OC, EC, WSIC and trace metals of PM10 in Delhi, India. Journal of Atmospheric and Solar-Terrestrial Physics 2014; 113:10-22.
  • [18] Tolis EI, Saraga DE, Lytra MK, Papatganasiou ACh, Bougaidis PN, Prekas-Patronakis OE, Ioannidis II, Bartzis JG. Concentration and chemical composition of PM2.5 for a one-year period at Thessaloniki, Greece: A comparison between city and port area. Atmospheric Environment 2015; 113:197-207.
  • [19] Tzimou-Tsitouridou R. Carbonaceous species of TSP in urban and rural sites around coal-fired power stations in northwestern Greece. Talanta 2004; 62: 115-122.
  • [20] Gonçalves C, Figueiredo BR, Alves CA, Cardoso AA, da Silva R, Kanzawa SH, Vicente AM. Chemical characterisation of total suspended particulate matter from a remote area in Amazonia. Atmos Res 2016; 182; 102-113.
  • [21] Ram K, Sarin MM. Spatio-temporal variability in atmospheric abundances of EC, OC and WSOC over Northern India. J Aerosol Sci 2010; 41: 88-98.
  • [22] Cabada JC, Pandis SN, Subramanian R, Robinson AL, Polidori A. Estimating the secondary organic aerosol contribution to PM2.5 using the EC tracer method, Aerosol Science and Technology 2004; 38:140-155.
  • [23] Cabada JC, Pandis SN. Sources of atmospheric carbonaceous particulate matter in Pittsburgh, Pennsylvania. Journal of the Air and Waste Management Association 2002;52: 732–741.
  • [24] Lonati G, Ozgen S, Giugliano M. Primary and secondary carbonaceous species in PM2.5 samples in Milan (Italy). Atmospheric Environment 2007; 41:4599-4610.
  • [25] Keywood M, Guyes H, Selleck P, Gillett R. Quantification of secondary organic aerosol in an Australian urban location. Environmental Chemistry 2011; 8: 115-126.
  • [26] Gaga EO, Ari A, Akyol N, Özden Üzmez Ö, Kara M, Chow JC, Watson JG, Özel E, Döğeroğlu T, Odabasi M. Determination of real-world emission factors of trace metals, EC, OC, BTEX, NO2, and semivolatile organic compounds (PAHs, PCBs and PCNs) in a rural tunnel in Bilecik, Turkey. Atmospheric Environment 2017 (under review)
  • [27] Plaza J, Gomez-Moreno FZ, Nunez L, Pujadas M, Artinano B. Estimation of secondary organic aerosol formation from semicontinuous OC-EC measurements in a Madrid suburban area. Atmospheric Environment 2006; 40:1134–1147.
  • [28] Yang F, He K, Ma Y, Zhang Q. Characterization of carbonaceous species of ambient PM2.5 in Beijing, China.Journal of the Air and Waste Management Association 2005;55: 984–992.
  • [29] Gelencser A, May B, Simpson D, Sanchez-Ochoa A, Kasper-Giebl A, Puxbaum H, Caseiro A, Pio C, Legrand M. Source apportionment of PM2.5 organic aerosol over Europe: primary/secondary, Natural/anthropogenic, and fossil/biogenic origin, J. Geophys. Res 2007;112: D23S04.
  • [30] Day MC, Zhang M, Pandis SN. Evaluation of the ability of the EC tracer method to estimate secondary organic carbon. Atmospheric Environment 2015; 112:317-325.
  • [31] Barthelmie RJ, Pryor SC. Secondary organic aerosols: formation potential and ambient data. Science of theTotal Environment 1997; 205:167-178.
  • [32] Baltensperger U, Kalberer M, Dommen J, Paulsen D, Alfarra MR, Coe H, Fisseha R, Gascho A, Gysel M, Nyeki S, Sax M, Steinbacher M, Prevot ASH, Sjogren S, Weingartner E, Zenobi R. Secondary organic aerosols from anthropogenic and bogenic precursors. Faraday Discussions 2005; 130: 265-278.
Year 2017, Volume: 18 Issue: 2, 429 - 438, 30.06.2017
https://doi.org/10.18038/aubtda.299876

Abstract

References

  • [1] US EPA. Air Quality Criteria for Particulate Matter, Office of Research and Development, Research Triangle Park, NC.1996. vols. 1–3.
  • [2] IPCC. Climate Change 1994: radiative forcing of climate change and an evaluation of the IPCC IS92 emission scenarios. Cambridge University Press, New York, 1995.
  • [3] Hildemann LM, Rogge WF, Cass GR, Mazurek MA, Simoneit BRT. Contribution of primary aerosol emissions from vegetation-derived sources to fine particle concentrations in Los Angeles, Journal of Geophysical Research 1996; 101:19541-19549.
  • [4] Castro LM, Pio CA, Harrison, RM, Smith DJT. Carbonaceous aerosol in urban and rural European atmospheres: estimation of secondary organic carbon concentrations. Atmospheric Environment 1999: 33:2771-2781.
  • [5] Huang L, Brook JR, Zhang W, Li SM, Graham, L, Ernst D, Chivulescu A, Lu G. Stable isotope measurements of carbon fractions (OC/EC) in airborne particulate, A new dimension for source characterization and apportionment. Atmospheric Environment 2006; 40: 2690-2705.
  • [6] Jaoui M, Kleindienst E, Lewandowski M, Edney EO. Identification and quantification of aerosol polar oxygenated compounds bearing carboxylic or hydroxyl groups. 1. Method development. Analytical Chemistry 2004;76: 4765 – 4778.
  • [7] Jaoui M, Kleindienst E, Lewandowski M, Offenberg JH, Edney EO. Identification and quantification of aerosol polar oxygenated compounds bearing carboxylic or hydroxyl groups. 2. Organic tracer compounds from monoterpenes. Environmental Science and Technology 2005; 39: 5661-5673.
  • [8] Strader R, Lurmann F, Pandis SN, Evaluation of secondary organic aerosol formation in winter, Atmospheric Environment, 33, 4849 – 4863, (1999).
  • [9] Yu S, Dennis RL, Bhave PV, Eder BK. Primary and secondary organic aerosols over the United States, estimates on the basis of observed organic carbon (OC) and elemental carbon (EC), and air quality modeled primary OC/EC ratios. Atmospheric Environment 2004; 38: 5257 – 5268.
  • [10] Chu SH. Stable estimate of primary OC/EC ratios in the EC tracer method. Atmospheric Environment, 2005;39:1383-1392.
  • [11] Pio C, Cerqueira M, Harrison RM, Nunes T, Mirante F, Alves C, Oliveira C, Sanches de la Campa A, Artinano B, Matos M. OC/EC ratio observed in Europe: re-thinking the approach for apportionment between primary and secondary organic carbon. Atmospheric Environment 2011; 45: 6121-6132.
  • [12] Turpin BJ, Huntzicker JJ. Identification of secondary organic aerosol episodes and quantification of primary and secondary organic aerosol concentrations during SCAQS. Atmospheric Environment 1995; 29:3527-3544.
  • [13] Saffari A, Hasheminassab S, Shafer MM, Schauer JJ, Chatila TA, Sioutas C. Nighttime aqueous-phase secondary organic aerosols in Los Angeles and its implication for fine particulate matter composition and oxidative potential. Atmospheric Environment 2016; 133: 112-122.
  • [14] Saylor RD, Edgerton ES, Hartsell BE. Linear regression techniques for use in the EC tracer method of secondary organic aerosol estimation. Atmospheric Environment 2006; 40: 7546-7556.
  • [15] Clarke AG, Willison MJ, Zeki EM. A comparison of urban and rural aerosol composition using dichotomous samplers. Atmospheric Environment 1967; 18: 1767-1775.
  • [16] Poor N, Clark T, Nye L, Tamanini T, Tate K, Stevens R, Atkeson T. Field performance of dichotomous sequential PM air samplers. Atmospheric Environment 2002; 36:3289-3298.
  • [17] Sharma SK, Mandal TK, Saxena M, Sharma A, Datta A, Saud T. Variation of OC, EC, WSIC and trace metals of PM10 in Delhi, India. Journal of Atmospheric and Solar-Terrestrial Physics 2014; 113:10-22.
  • [18] Tolis EI, Saraga DE, Lytra MK, Papatganasiou ACh, Bougaidis PN, Prekas-Patronakis OE, Ioannidis II, Bartzis JG. Concentration and chemical composition of PM2.5 for a one-year period at Thessaloniki, Greece: A comparison between city and port area. Atmospheric Environment 2015; 113:197-207.
  • [19] Tzimou-Tsitouridou R. Carbonaceous species of TSP in urban and rural sites around coal-fired power stations in northwestern Greece. Talanta 2004; 62: 115-122.
  • [20] Gonçalves C, Figueiredo BR, Alves CA, Cardoso AA, da Silva R, Kanzawa SH, Vicente AM. Chemical characterisation of total suspended particulate matter from a remote area in Amazonia. Atmos Res 2016; 182; 102-113.
  • [21] Ram K, Sarin MM. Spatio-temporal variability in atmospheric abundances of EC, OC and WSOC over Northern India. J Aerosol Sci 2010; 41: 88-98.
  • [22] Cabada JC, Pandis SN, Subramanian R, Robinson AL, Polidori A. Estimating the secondary organic aerosol contribution to PM2.5 using the EC tracer method, Aerosol Science and Technology 2004; 38:140-155.
  • [23] Cabada JC, Pandis SN. Sources of atmospheric carbonaceous particulate matter in Pittsburgh, Pennsylvania. Journal of the Air and Waste Management Association 2002;52: 732–741.
  • [24] Lonati G, Ozgen S, Giugliano M. Primary and secondary carbonaceous species in PM2.5 samples in Milan (Italy). Atmospheric Environment 2007; 41:4599-4610.
  • [25] Keywood M, Guyes H, Selleck P, Gillett R. Quantification of secondary organic aerosol in an Australian urban location. Environmental Chemistry 2011; 8: 115-126.
  • [26] Gaga EO, Ari A, Akyol N, Özden Üzmez Ö, Kara M, Chow JC, Watson JG, Özel E, Döğeroğlu T, Odabasi M. Determination of real-world emission factors of trace metals, EC, OC, BTEX, NO2, and semivolatile organic compounds (PAHs, PCBs and PCNs) in a rural tunnel in Bilecik, Turkey. Atmospheric Environment 2017 (under review)
  • [27] Plaza J, Gomez-Moreno FZ, Nunez L, Pujadas M, Artinano B. Estimation of secondary organic aerosol formation from semicontinuous OC-EC measurements in a Madrid suburban area. Atmospheric Environment 2006; 40:1134–1147.
  • [28] Yang F, He K, Ma Y, Zhang Q. Characterization of carbonaceous species of ambient PM2.5 in Beijing, China.Journal of the Air and Waste Management Association 2005;55: 984–992.
  • [29] Gelencser A, May B, Simpson D, Sanchez-Ochoa A, Kasper-Giebl A, Puxbaum H, Caseiro A, Pio C, Legrand M. Source apportionment of PM2.5 organic aerosol over Europe: primary/secondary, Natural/anthropogenic, and fossil/biogenic origin, J. Geophys. Res 2007;112: D23S04.
  • [30] Day MC, Zhang M, Pandis SN. Evaluation of the ability of the EC tracer method to estimate secondary organic carbon. Atmospheric Environment 2015; 112:317-325.
  • [31] Barthelmie RJ, Pryor SC. Secondary organic aerosols: formation potential and ambient data. Science of theTotal Environment 1997; 205:167-178.
  • [32] Baltensperger U, Kalberer M, Dommen J, Paulsen D, Alfarra MR, Coe H, Fisseha R, Gascho A, Gysel M, Nyeki S, Sax M, Steinbacher M, Prevot ASH, Sjogren S, Weingartner E, Zenobi R. Secondary organic aerosols from anthropogenic and bogenic precursors. Faraday Discussions 2005; 130: 265-278.
There are 32 citations in total.

Details

Subjects Engineering
Journal Section Articles
Authors

Eftade Gaga

Publication Date June 30, 2017
Published in Issue Year 2017 Volume: 18 Issue: 2

Cite

APA Gaga, E. (2017). AMBIENT CONCENTRATIONS OF ELEMENTAL AND ORGANIC CARBON IN URBAN AND SUBURBAN ATMOSPHERES IN ESKİSEHİR: ESTIMATION OF THE SECONDARY ORGANIC CARBON. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, 18(2), 429-438. https://doi.org/10.18038/aubtda.299876
AMA Gaga E. AMBIENT CONCENTRATIONS OF ELEMENTAL AND ORGANIC CARBON IN URBAN AND SUBURBAN ATMOSPHERES IN ESKİSEHİR: ESTIMATION OF THE SECONDARY ORGANIC CARBON. AUJST-A. June 2017;18(2):429-438. doi:10.18038/aubtda.299876
Chicago Gaga, Eftade. “AMBIENT CONCENTRATIONS OF ELEMENTAL AND ORGANIC CARBON IN URBAN AND SUBURBAN ATMOSPHERES IN ESKİSEHİR: ESTIMATION OF THE SECONDARY ORGANIC CARBON”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 18, no. 2 (June 2017): 429-38. https://doi.org/10.18038/aubtda.299876.
EndNote Gaga E (June 1, 2017) AMBIENT CONCENTRATIONS OF ELEMENTAL AND ORGANIC CARBON IN URBAN AND SUBURBAN ATMOSPHERES IN ESKİSEHİR: ESTIMATION OF THE SECONDARY ORGANIC CARBON. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 18 2 429–438.
IEEE E. Gaga, “AMBIENT CONCENTRATIONS OF ELEMENTAL AND ORGANIC CARBON IN URBAN AND SUBURBAN ATMOSPHERES IN ESKİSEHİR: ESTIMATION OF THE SECONDARY ORGANIC CARBON”, AUJST-A, vol. 18, no. 2, pp. 429–438, 2017, doi: 10.18038/aubtda.299876.
ISNAD Gaga, Eftade. “AMBIENT CONCENTRATIONS OF ELEMENTAL AND ORGANIC CARBON IN URBAN AND SUBURBAN ATMOSPHERES IN ESKİSEHİR: ESTIMATION OF THE SECONDARY ORGANIC CARBON”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 18/2 (June 2017), 429-438. https://doi.org/10.18038/aubtda.299876.
JAMA Gaga E. AMBIENT CONCENTRATIONS OF ELEMENTAL AND ORGANIC CARBON IN URBAN AND SUBURBAN ATMOSPHERES IN ESKİSEHİR: ESTIMATION OF THE SECONDARY ORGANIC CARBON. AUJST-A. 2017;18:429–438.
MLA Gaga, Eftade. “AMBIENT CONCENTRATIONS OF ELEMENTAL AND ORGANIC CARBON IN URBAN AND SUBURBAN ATMOSPHERES IN ESKİSEHİR: ESTIMATION OF THE SECONDARY ORGANIC CARBON”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, vol. 18, no. 2, 2017, pp. 429-38, doi:10.18038/aubtda.299876.
Vancouver Gaga E. AMBIENT CONCENTRATIONS OF ELEMENTAL AND ORGANIC CARBON IN URBAN AND SUBURBAN ATMOSPHERES IN ESKİSEHİR: ESTIMATION OF THE SECONDARY ORGANIC CARBON. AUJST-A. 2017;18(2):429-38.