SINGLE AND DOUBLE IMPRINTED POLYMER FOR SELECTIVE RECOGNITION OF Cd(II) IONS IN AQUEOUS MEDIA

Ebru Birlik Özkütük; Ebru Ozkutuk; Elif Özalp; Gülgün İşler

SINGLE AND DOUBLE IMPRINTED POLYMER FOR SELECTIVE RECOGNITION OF Cd(II) IONS IN AQUEOUS MEDIA

Year 2010, Volume: 11 Issue: 2, 149 - 161, 24.09.2010

Ebru Birlik Özkütük , Ebru Ozkutuk , Elif Özalp Gülgün İşler

Abstract

In this paper, we have reported the synthesis of a new single and double-imprinted polymer material for the separation of Cd(II) ions in aqueous solutions. Chitosan has choosen as the Cd(II) metal complexing big polymer for single and double imprinted polymer. In the synthesis of single imprinted polymer, Cd(II)-complexed chitosan has crosslinked by epichlorohydrin. In the synthesis of double imprinted polymer, Cd(II)-complexed chitosan was reacted with 3-mercaptopropyl-trimethoxysilane. Then, the polymeric beads have crosslinked with tetraethoxysilane (TEOS). The imprinted cadmium ion has removed from the polymeric matrix by 0.1M HNO₃ (to prepare Cd(II) templates). Optimum pH for rebinding of Cd(II) on the single and double-imprinted polymers was 7.0. Equilibrium binding time and sorbent capacity have been found as 120 and 60 min, 342 and 172 mg g^-1 for single and double imprinted polymer, respectively. In selectivity studies, it has been found that double imprinted results in increased affinity of the material toward Cd(II) ion over other competitor metal ions with the same charge. The prepared single and double-imprinted polymer have repeatedly used and regenerated for thirty times without a significant decrease in polymer binding affinities.

Keywords

Molecular imprinting

References

Andac, M., Say, R. and Denizli, A. (2004). Molecular recognition based cadmium removal from human plasma Journal of Chromatography B 811, 119–126.
Berggren, C., Bayoudh, S., Sherrington, D. and Ensing, K. (2000). Use of molecular imprinted solid phase extraction from calf urine. J. Chromatogr. A 889, 105-110.
Birlik Özkütük, E., Özalp, E., İşler, G., Emir Diltemiz, S. and Ersöz,.A. (2010). Selective Solid-Phase Extraction of Cd(II) Using Double Imprinting Strategy. G.U. Journal of Science 23(1), 19-26.
Birlik, E., Ersöz ,A., Denizli, A. and Say, R. (2006). Preconcentration of Copper Using Double-Imprinted Polymer via Solid Phase Extraction. Anal.Chim.Acta 565, 145-151.
Bodek, I., Lyman, W.J., Reehl, W.F. and Rosenblatt, D.H. (1998). Environmental Inorganic Chemistry: Properties, Processes and Estimation Methods. Pergamon Press, New York.
Candan, N., Tuzmen, N., Andac, M., Andac, C.A., Say, R. and Denizli, A. (2009). Cadmium Removal out of Human Plasma Using Ion-Imprinted Beads in Magnetic Column. Materials Science and Engineering C 29, 144-152.
Denizli, A., Salih, B. and Pis¸kin, E. (1997). New sorbents for removal of heavy metal ions: Daimine glow-discharge treated polyhydroxyethylmethacrylate microspheres. J. Chromatogr. A 773, 169-178.
Denizli, A., Senel, S., Alsancak, G., Tuzmen, N. and Say, R. (2003). Mercury removal from synthetic solutions using poly(2hydroxyethylmethacrylate) gel beads modified with poly(ethyleneimine). Reactive Funct. Polym. 55, 121-130.
Ersöz, A., Say, R. and Denizli, A. (2004). Nickel(II) Ion-Imprinted Solid Phase Extraction and Preconcentration in Aqueous Solutions by Packed-bed Columns. Analytica Chimica Acta 502 (1), 91-97.
Ho, Y.S. and McKay, G. (1999). Pseudo-second order model for sorption processes Proc. Biochem. 34, 451-465.
Ho, Y.S. and Ofomaja, A.E. (2006). Biosorption thermodynamics of cadmium on coconut copra meal as biosorbent, Biochem. Eng. J. 30, 117–123.
Jodlbauer, J., Maier, N.M. and Lindner, W. (2002). Towards ochratoxin A selective molecularly imprinted polymers for solidphase extraction. J. Chromatogr. A 945, 45-63.
Kasuya, M. (2000). Recent epidemiological studies on itai–itai disease as a chronic cadmium poisoning in Japan. Water Sci. Technol. 42, 147–154.
Kesenci, K., Say, R. and Denizli, A. (2002). Removal of Heavy Metal Ions from Water by Poly(Ethylene glycol dimethacrylate/Acrylamide) Beads. Eur. Polym. J. 38, 1443-1448.
Labrou, N.E., Karagouni, A. and Clonis, Y.D. (1995). Biomimetic-dye Affinity Adsorbents for Enzyme Purification. Application to the One-step Purification of Candida boidinii Formate Dehydrogenae. Biotechnol. Bioeng. 48, 278-288.
Li, F., Jiang, Zhang, H.S. (2007). An ionimprinted silica-supported organicinorganic hybrid sorbent prepared by a surface imprinting technique combined with a polysaccharide incorporated sol-gel process for selective separation of cadmium(II) from aqueous solution. Talanta. 71, 1487-1493.
Lu, Yun-Kai and Yan, Xiu-Ping (2004). An Imprinted 406 Organic−Inorganic Hybrid Sorbent for Selective Separation of Cadmium from Aqueous Solution. Anal. Chem. 76, 453-457.
Manohar, D.M., Krishnan, K.A. and Anirudhan, T.S. (2002). Removal of mercury(II) from aqueous solutions and chlor-alkali industry wastewater using 2-mercapto benzimidazole-clay. Water Res. 36, 16091619.
Matsui, J., Fujiwara, K., Ugata, S. and Takeuchi, T. (2000). Solid-Phase Extraction with a Dibutylmelamine-imprinted Polymer as Triazine Herbicide-selective Sorbent. J. Chromatogr. A 889, 25-31.
Mena, M.L., Martinez-Ruiz, P., Reviejo, A.J. and Pingarrón, J.M. (2002). Molecularly imprintedpolymers for on-line preconcentration by solid phase extraction of pirimicarb in water samples. Anal. Chim. Acta 451, 297-304.
Mohan, D. and Sing, K.P. h(2002). Single-and multi-component adsorption of cadmium and zinc using activated carbon derived from bagasse: An agricultural waste. Water Res. 36, 2304–2318.
Mohan, D., Pittman, C.U. and Steele, P.H. (2006). Single, Binary and Multicomponent Adsorption of Copper and Cadmium from Aqueous Solutions on Kraft Lignin-a Biosorbent. J. Colloid Interface Sci. 297, 489–504.
Mullett, ,W.M., Martin, P. and Pawliszyn, J. (2001). In-Tube Molecularly Imprinted Polymer Solid-Phase Microextraction for the Selective Determination of Propranolol. Anal. Chem. 73, 2383- 2389.
Mullett, W.M. and Lai, E.P.C. (1999). Molecularly Imprinted Solid Phase Extraction Micro-column with Differential Pulsed Elution for Theophylline Determination. Microchem. J. 61, 143-155.
Say, R., Birlik, E., Ersoz, A., Yılmaz, F., Gedikbey, T. and Denizli, A. (2003). Preconcentration of Copper on Ion-selective Imprinted Polymeric Beads Anal.Chim.Acta 480, 251-258.
Sellergren, B. (1999). Polymer and templaterelated factors influencing the efficiency in molecularly imprinted solid-phase extractions. Trends Anal. Chem. 18, 164174.
Suzuki, T.M., Tanco, M.L., Tanaka, D.A.P., Matsunaga, H. and Yokoyama, T. (2001). Adsorption characteristics and removal of oxo-anions of arsenic and selenium on the porous polymers loaded with monoclinic hydrous zirconium oxide. Sep. Sci. Technol. 36 (1), 103-111.
Thurman, E.M. and Mills, M.S. (1998). SolidPhase Extraction: Principles and Practice, John Wiley & Sons, Chichester.
Tsezos, M. (2001). Biosorption of metals. The experience accumulated and the outlook for technology development. Hydrometallurgy 59, 241–243.
Zhai, Y., Liu, Chang, YX., Chen, S. and Huang, X. (2007). Selective solid-phase extraction of trace cadmium(II) with an ionic imprinted polymer prepared from a dualligand monomer. Anal. Chim. Acta 593, 123-128

SULU ORTAMDA Cd(II) İYONLARININ SEÇİCİ TANIMLANMASI İÇİN TEK VE ÇİFT BASKILI POLİMERLER

Year 2010, Volume: 11 Issue: 2, 149 - 161, 24.09.2010

Ebru Birlik Özkütük , Ebru Ozkutuk , Elif Özalp Gülgün İşler

Abstract

Bu çalışmada, sulu ortamda Cd(II) iyonlarının ayrımı için yeni tek ve çift baskılı polimerik materyal sentezi gerçekleştirilmiştir. Kitosan, tek ve çift baskılı polimer için metal kompleksleyici, büyük polimer olarak seçilmiştir. Tek baskılı polimerin sentezinde, Cd(II)-kitosan kompleksi epiklorohidrin ile çapraz bağlandı. Çift baskılı polimerin sentezinde ise, Cd(II)- kitosan kompleksi 3merkaptopropiltrimetoksisilan ile reaksiyona sokuldu. Daha sonra polimerik tanecikler, tetrametoksisilan (TEOS) ile çapraz bağlandı. Polimerik matrikste Cd(II) iyonlarına uygun yuva oluşturmak için, baskılı Cd(II) iyonları polimerden 0,1M HNO3 ile uzaklaştırıldı. Tek ve çift baskılı polimerlerde, Cd(II) iyonlarının tekrar bağlanmsı için, optimum pH 7’dir. Tek ve çift baskılı polimerler için bağlanma denge zamanları, sırasıyla 120 ve 60 dak. Olarak; Cd(II) sorbent kapasitesi ise sırasıyla 342 ve 172 mgg-1 olarak bulundu. Seçicilik çalışmalarında; çift baskılama sonuçları, Cd(II) iyonlarının diğer benzer yüklü yarışmacı iyonlara göre afinitesinin yüksek olduğunu göstermiştir. Hazırlanmış tek ve çift baskılı polimerlerin bağlanma kapasitelerinde kayda değer bir değişklik olmaksızın 30 kez tekrar kullanıldı

Keywords

İyon baskılanmış polimer, Çift baskılanmış polimer, Kadmiyum tayini, Kitosan, sol-jel, Katı faz ekstraksiyonu

References

Andac, M., Say, R. and Denizli, A. (2004). Molecular recognition based cadmium removal from human plasma Journal of Chromatography B 811, 119–126.
Berggren, C., Bayoudh, S., Sherrington, D. and Ensing, K. (2000). Use of molecular imprinted solid phase extraction from calf urine. J. Chromatogr. A 889, 105-110.
Birlik Özkütük, E., Özalp, E., İşler, G., Emir Diltemiz, S. and Ersöz,.A. (2010). Selective Solid-Phase Extraction of Cd(II) Using Double Imprinting Strategy. G.U. Journal of Science 23(1), 19-26.
Birlik, E., Ersöz ,A., Denizli, A. and Say, R. (2006). Preconcentration of Copper Using Double-Imprinted Polymer via Solid Phase Extraction. Anal.Chim.Acta 565, 145-151.
Bodek, I., Lyman, W.J., Reehl, W.F. and Rosenblatt, D.H. (1998). Environmental Inorganic Chemistry: Properties, Processes and Estimation Methods. Pergamon Press, New York.
Candan, N., Tuzmen, N., Andac, M., Andac, C.A., Say, R. and Denizli, A. (2009). Cadmium Removal out of Human Plasma Using Ion-Imprinted Beads in Magnetic Column. Materials Science and Engineering C 29, 144-152.
Denizli, A., Salih, B. and Pis¸kin, E. (1997). New sorbents for removal of heavy metal ions: Daimine glow-discharge treated polyhydroxyethylmethacrylate microspheres. J. Chromatogr. A 773, 169-178.
Denizli, A., Senel, S., Alsancak, G., Tuzmen, N. and Say, R. (2003). Mercury removal from synthetic solutions using poly(2hydroxyethylmethacrylate) gel beads modified with poly(ethyleneimine). Reactive Funct. Polym. 55, 121-130.
Ersöz, A., Say, R. and Denizli, A. (2004). Nickel(II) Ion-Imprinted Solid Phase Extraction and Preconcentration in Aqueous Solutions by Packed-bed Columns. Analytica Chimica Acta 502 (1), 91-97.
Ho, Y.S. and McKay, G. (1999). Pseudo-second order model for sorption processes Proc. Biochem. 34, 451-465.
Ho, Y.S. and Ofomaja, A.E. (2006). Biosorption thermodynamics of cadmium on coconut copra meal as biosorbent, Biochem. Eng. J. 30, 117–123.
Jodlbauer, J., Maier, N.M. and Lindner, W. (2002). Towards ochratoxin A selective molecularly imprinted polymers for solidphase extraction. J. Chromatogr. A 945, 45-63.
Kasuya, M. (2000). Recent epidemiological studies on itai–itai disease as a chronic cadmium poisoning in Japan. Water Sci. Technol. 42, 147–154.
Kesenci, K., Say, R. and Denizli, A. (2002). Removal of Heavy Metal Ions from Water by Poly(Ethylene glycol dimethacrylate/Acrylamide) Beads. Eur. Polym. J. 38, 1443-1448.
Labrou, N.E., Karagouni, A. and Clonis, Y.D. (1995). Biomimetic-dye Affinity Adsorbents for Enzyme Purification. Application to the One-step Purification of Candida boidinii Formate Dehydrogenae. Biotechnol. Bioeng. 48, 278-288.
Li, F., Jiang, Zhang, H.S. (2007). An ionimprinted silica-supported organicinorganic hybrid sorbent prepared by a surface imprinting technique combined with a polysaccharide incorporated sol-gel process for selective separation of cadmium(II) from aqueous solution. Talanta. 71, 1487-1493.
Lu, Yun-Kai and Yan, Xiu-Ping (2004). An Imprinted 406 Organic−Inorganic Hybrid Sorbent for Selective Separation of Cadmium from Aqueous Solution. Anal. Chem. 76, 453-457.
Manohar, D.M., Krishnan, K.A. and Anirudhan, T.S. (2002). Removal of mercury(II) from aqueous solutions and chlor-alkali industry wastewater using 2-mercapto benzimidazole-clay. Water Res. 36, 16091619.
Matsui, J., Fujiwara, K., Ugata, S. and Takeuchi, T. (2000). Solid-Phase Extraction with a Dibutylmelamine-imprinted Polymer as Triazine Herbicide-selective Sorbent. J. Chromatogr. A 889, 25-31.
Mena, M.L., Martinez-Ruiz, P., Reviejo, A.J. and Pingarrón, J.M. (2002). Molecularly imprintedpolymers for on-line preconcentration by solid phase extraction of pirimicarb in water samples. Anal. Chim. Acta 451, 297-304.
Mohan, D. and Sing, K.P. h(2002). Single-and multi-component adsorption of cadmium and zinc using activated carbon derived from bagasse: An agricultural waste. Water Res. 36, 2304–2318.
Mohan, D., Pittman, C.U. and Steele, P.H. (2006). Single, Binary and Multicomponent Adsorption of Copper and Cadmium from Aqueous Solutions on Kraft Lignin-a Biosorbent. J. Colloid Interface Sci. 297, 489–504.
Mullett, ,W.M., Martin, P. and Pawliszyn, J. (2001). In-Tube Molecularly Imprinted Polymer Solid-Phase Microextraction for the Selective Determination of Propranolol. Anal. Chem. 73, 2383- 2389.
Mullett, W.M. and Lai, E.P.C. (1999). Molecularly Imprinted Solid Phase Extraction Micro-column with Differential Pulsed Elution for Theophylline Determination. Microchem. J. 61, 143-155.
Say, R., Birlik, E., Ersoz, A., Yılmaz, F., Gedikbey, T. and Denizli, A. (2003). Preconcentration of Copper on Ion-selective Imprinted Polymeric Beads Anal.Chim.Acta 480, 251-258.
Sellergren, B. (1999). Polymer and templaterelated factors influencing the efficiency in molecularly imprinted solid-phase extractions. Trends Anal. Chem. 18, 164174.
Suzuki, T.M., Tanco, M.L., Tanaka, D.A.P., Matsunaga, H. and Yokoyama, T. (2001). Adsorption characteristics and removal of oxo-anions of arsenic and selenium on the porous polymers loaded with monoclinic hydrous zirconium oxide. Sep. Sci. Technol. 36 (1), 103-111.
Thurman, E.M. and Mills, M.S. (1998). SolidPhase Extraction: Principles and Practice, John Wiley & Sons, Chichester.
Tsezos, M. (2001). Biosorption of metals. The experience accumulated and the outlook for technology development. Hydrometallurgy 59, 241–243.
Zhai, Y., Liu, Chang, YX., Chen, S. and Huang, X. (2007). Selective solid-phase extraction of trace cadmium(II) with an ionic imprinted polymer prepared from a dualligand monomer. Anal. Chim. Acta 593, 123-128

There are 30 citations in total.

Details

Primary Language	English
Journal Section	Articles
Authors	Ebru Birlik Özkütük Ebru Ozkutuk Elif Özalp This is me Gülgün İşler This is me
Publication Date	September 24, 2010
Published in Issue	Year 2010 Volume: 11 Issue: 2

Cite

APA	Birlik Özkütük, E., Ozkutuk, E., Özalp, E., İşler, G. (2010). SINGLE AND DOUBLE IMPRINTED POLYMER FOR SELECTIVE RECOGNITION OF Cd(II) IONS IN AQUEOUS MEDIA. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, 11(2), 149-161.
AMA	Birlik Özkütük E, Ozkutuk E, Özalp E, İşler G. SINGLE AND DOUBLE IMPRINTED POLYMER FOR SELECTIVE RECOGNITION OF Cd(II) IONS IN AQUEOUS MEDIA. AUJST-A. December 2010;11(2):149-161.
Chicago	Birlik Özkütük, Ebru, Ebru Ozkutuk, Elif Özalp, and Gülgün İşler. “SINGLE AND DOUBLE IMPRINTED POLYMER FOR SELECTIVE RECOGNITION OF Cd(II) IONS IN AQUEOUS MEDIA”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 11, no. 2 (December 2010): 149-61.
EndNote	Birlik Özkütük E, Ozkutuk E, Özalp E, İşler G (December 1, 2010) SINGLE AND DOUBLE IMPRINTED POLYMER FOR SELECTIVE RECOGNITION OF Cd(II) IONS IN AQUEOUS MEDIA. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 11 2 149–161.
IEEE	E. Birlik Özkütük, E. Ozkutuk, E. Özalp, and G. İşler, “SINGLE AND DOUBLE IMPRINTED POLYMER FOR SELECTIVE RECOGNITION OF Cd(II) IONS IN AQUEOUS MEDIA”, AUJST-A, vol. 11, no. 2, pp. 149–161, 2010.
ISNAD	Birlik Özkütük, Ebru et al. “SINGLE AND DOUBLE IMPRINTED POLYMER FOR SELECTIVE RECOGNITION OF Cd(II) IONS IN AQUEOUS MEDIA”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 11/2 (December 2010), 149-161.
JAMA	Birlik Özkütük E, Ozkutuk E, Özalp E, İşler G. SINGLE AND DOUBLE IMPRINTED POLYMER FOR SELECTIVE RECOGNITION OF Cd(II) IONS IN AQUEOUS MEDIA. AUJST-A. 2010;11:149–161.
MLA	Birlik Özkütük, Ebru et al. “SINGLE AND DOUBLE IMPRINTED POLYMER FOR SELECTIVE RECOGNITION OF Cd(II) IONS IN AQUEOUS MEDIA”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, vol. 11, no. 2, 2010, pp. 149-61.
Vancouver	Birlik Özkütük E, Ozkutuk E, Özalp E, İşler G. SINGLE AND DOUBLE IMPRINTED POLYMER FOR SELECTIVE RECOGNITION OF Cd(II) IONS IN AQUEOUS MEDIA. AUJST-A. 2010;11(2):149-61.

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