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SELECTIVE REMOVAL OF Cd(II) USING DOUBLE IMPRINTED POLYMER FROM SYNTHETIC WATER

Year 2015, Volume: 16 Issue: 1, 15 - 22, 11.05.2015
https://doi.org/10.18038/btd-a.59620

Abstract

The aim of this study is to prepare ion-imprinted polymers which can be used for the selective removal of Cd(II) from synthetic water. Ion-imprinted polymer particles have prepared by molecular imprinting technique using 3-mercaptopropyl-trimethoxysilane as monomer, tetraethoxysilane as crosslinking agent in the presence of Cd(II) and dodecylamine. After that, the template ions have removed using 0.1M HNO3/ethanol. A batch procedure has used for the determination of the characteristics of the Cd(II) solid phase. The results obtained have shown that the IIP has the greatest adsorption capacity (98.2 mgg-1). Optimum pH and adsorption time have found as pH 5.0 and 2h. In selectivity study, it has found that imprinting results in increased affinity of the material toward Cd(II) ion over other competitor metal ions with the same charge. The selectivity of Cd(II)/Zn(II), Cd(II)/Cu(II) and Cd(II)/Hg(II) have found as 2.73, 8.83 and 112.8, respectively

References

  • Amorim, F. A. C., Ferreira, S. L. C., (2005) Determination of cadmium and lead in table salt by sequential multi-element flame atomic absorption spectrometry. Talanta, 65, 960- 964
  • Andac, M., Say, R., A. Denizli, (2004). Molecular recognition based cadmium removal from human plasma Journal of Chromatography B., 811, 119-126.
  • Andac, M., Ozyapi, E., Senel, S., Say, R., A.Denizli, (2006). Ion-Selective Imprinted Beads for Aluminum Removal from Aqueous Solutions Industrial Research., 45(5), 1780-1786. Chemistry
  • Araki, K., Maruyama, T., Kamiya, N., Goto M., (2005) prepared by surface molecular imprinting.J. Chromatography B., 818, 141-145.
  • Bae, S. Y., Southard G. L., Murray, G. M., (1999).
  • Molecularly imprinted ion exchange resin for
  • purification preconcentration and determination
  • of UO22+ by spectrophotometry and plasma
  • spectrometry Analytica Chimica Acta 397 (1-3), 173-181.
  • Biju, V. M., Gladis, J. M., Rao T. P., (2003) Ion imprinted polymer particles: synthesis, characterization and dysprosium ion uptake properties suitable for analytical applications Analytica Chimica Acta 478, 43-51.
  • Birlik, E., Ersöz A., Denizli A., Say, R., (2006). Preconcentration of Copper usind Double- Imprinted Polymer via Solid Phase Extraction Analytica Chimica Acta 565, 145-151.
  • Büyüktiryaki, S., Say, R., Ersöz, A., Birlik, E., Denizli, preconcentration of thorium in the presence of UO22+, Ce3+ and La3+ using Th(IV)-imprinted polymer ,Talanta., 67 640-645. Selective
  • Daniel, S., Babu, P. E. J., Rao, T. P., (2005) Preconcentrative Separation of Palladium(II) Using ... of Binding Parameters Based on Adsorption Isotherm Models, Talanta, 65(2): 441-452 .
  • Davis, A. C., Wu, P., Zhang, X. F., Hou, X. D., Jones B. T., (2006). Determination of cadmium in biological samples, Applied Spectroscopy Reviews 41, 35-75.
  • Ersöz, A., Say, R., Denizli A., (2004). Nickel(II) Ion- Imprinted Solid Phase Extraction and Preconcentration In Aqueous Solutions in Packed-Bed Columns, Analytica Chimica Acta, 502, 91-97
  • Fang, G. Z., Tan, J., Yan X. P., (2005). An ion- imprinted functionalized silica gel sorbent prepared techniquecombined with a sol–gel process for selective cadmium(II). Analytical Chemistry 77:1734– 1739 surface imprinting
  • solid-phaseextraction of
  • Gladis, J. M., Rao, T. P., (2003) Synthesis and analytical applications of uranyl ion imprinted polymer particles, Analytical Letters, 36, 2107-2121 .
  • Kala, R., Gladis, J. M., Rao, T. P., (2004). Preconcentrative separation of erbium from Y, Dy, Ho, Tb and Tm by using ion imprinted polymer particles viasolid phase extraction . Analytica Chimica Acta, 518: 143-150.
  • Karabork, M., Ersoz, A., Denizli, A., Say, R., (2008). Polymer-Clay Nanocomposite Iron Traps Based Industrial Research, 47, 2258-2264 .
  • Ion-Imprinting & Engineering Chemistry
  • Hg(II)-imprinted Chimica Acta, 538
  • Lu, Y. K., Yan, X. P., (2004). An imprinted organic- inorganic hybrid sorbent for selective separation of cadmium from aqueous solution Analytical Chemistry,76, 453-457.
  • Makote, R. D., Dai, S., (2001). Matrix-induced modification of imprinting effect for Cu2+ adsorption in hybrid silica matrices Analytica Chimica Acta, 435, 169-176.
  • Prasad, K., Kala, R., Rao, T. P., Naidu, G. R. K., (2006). Ion imprinted polymer based ion- selective electrode for the trace determination of dysprosium(III) ions Analytica Chimica Acta, 566, 69-74
  • Prasad, K., Gopikrishna, P., Kala, R., Rao, T. P., Naidu, G. R. K., (2006). Solid phase extraction preconcentration of cadmium and lead from soils embedded benzophenone and determination by FAAS, Talanta., 69, 938-945.
  • Ramstrom, O., Ye, L., Mosbach, K., (1996). Artificial prepared by molecular imprinting, Chemistry and Biology, 3, 471-477. to corticosteroids
  • Rosatzin, T., Andersson, L. I., Simon, W., Mosbach K., (1991). Preparation of Ca2+ selective sorbents by molecular imprinting using polymerizable ionophores, Journal of the Chemical Society, Perkin Transactions 2, 1261-1265 .
  • Saunders, G. D., Foxon, S. P., Walton, P. H., Joyce M. J., Port S. N., (2000).A selective uranium extraction agent prepared by polymer imprinting. Chemical Communications, 273- 274
  • Say, R., Birlik, E., Ersöz, A., Yilmaz, F., Gedikbey, T., Denizli, A., (2003). Preconcentration of copper on ion-selective imprinted polymer microbeads, Analytica Chimica Acta, 480, 251-258.
  • Vigneau, O., Pinel, C., Lemaire, M., (2002). “Solid- liquid separation of lanthanide/lanthanide and lanthanide/actinide using ionic imprinted polymer derivativeChemistry Letters, 202-203. on a DTPA
  • Wulff, G. (1995). Molecular imprinting in cross- linked materials with the aid of molecular templates - a way towards artificial antibodiesAngewandte Chemie International Edition 34 (17), 1812-1832.
  • Xie, F., Lin, X., Wu, X., Xie, Z. (2008). Solid phase extraction of lead (II), copper (II), cadmium (II) and nickel (II) using gallic acid-modified silica gel prior to determination by flame atomic absorption spectrometry Talanta., 74, 836–843

SENTETİK SUDAN ÇİFT BASKILI POLİMER KULLANILARAK Cd(II)'NİN SEÇİCİ UZAKLAŞTIRILMASI

Year 2015, Volume: 16 Issue: 1, 15 - 22, 11.05.2015
https://doi.org/10.18038/btd-a.59620

Abstract

Bu çalışmanın amacı, sentetik sudan Cd(II)’nin seçici uzaklaştırılması için kullanılabilecek iyon baskılı polimer hazırlamaktır. İyon baskılı polimer partikülleri, dodesilamin ve Cd(II) varlığında, çapraz bağlayıcı olarak teraetoksisilan, monomer olarak 3-merkaptopropil-trimetoksilanın kullanıldığı moleküler baskılama tekniği ile hazırlanmıştır. Daha sonra baskı iyonları 0,1 M HNO3/etanol kullanılarak uzaklaştırılmıştır. Beç işlemi, Cd(II) katı faz özelliklerinin belirlenmesi için kullanılmıştır. Elde edilen sonuçlar, iyon baskılı polimerin büyük adsorpsiyon kapasitesine (98.2 mgg-1) sahip olduğunu göstermiştir. Optimum pH ve adsorpsiyon süresi sırasıyla 5.0 ve 2 saat olarak bulunmuştur. Seçicilik çalışmalarında, baskılama aynı yüklü diğer yarışmacı metal iyonları üzerinden Cd(II) iyonlarına doğru materyalin afinitesinin arttığı bulunmuştur. Cd(II)/Zn(II), Cd(II)/Cu(II) and Cd(II)/Hg(II)’ın seçicilikleri sırasıyla 2,73; 8,83 ve 112 olarak bulunmuştur

References

  • Amorim, F. A. C., Ferreira, S. L. C., (2005) Determination of cadmium and lead in table salt by sequential multi-element flame atomic absorption spectrometry. Talanta, 65, 960- 964
  • Andac, M., Say, R., A. Denizli, (2004). Molecular recognition based cadmium removal from human plasma Journal of Chromatography B., 811, 119-126.
  • Andac, M., Ozyapi, E., Senel, S., Say, R., A.Denizli, (2006). Ion-Selective Imprinted Beads for Aluminum Removal from Aqueous Solutions Industrial Research., 45(5), 1780-1786. Chemistry
  • Araki, K., Maruyama, T., Kamiya, N., Goto M., (2005) prepared by surface molecular imprinting.J. Chromatography B., 818, 141-145.
  • Bae, S. Y., Southard G. L., Murray, G. M., (1999).
  • Molecularly imprinted ion exchange resin for
  • purification preconcentration and determination
  • of UO22+ by spectrophotometry and plasma
  • spectrometry Analytica Chimica Acta 397 (1-3), 173-181.
  • Biju, V. M., Gladis, J. M., Rao T. P., (2003) Ion imprinted polymer particles: synthesis, characterization and dysprosium ion uptake properties suitable for analytical applications Analytica Chimica Acta 478, 43-51.
  • Birlik, E., Ersöz A., Denizli A., Say, R., (2006). Preconcentration of Copper usind Double- Imprinted Polymer via Solid Phase Extraction Analytica Chimica Acta 565, 145-151.
  • Büyüktiryaki, S., Say, R., Ersöz, A., Birlik, E., Denizli, preconcentration of thorium in the presence of UO22+, Ce3+ and La3+ using Th(IV)-imprinted polymer ,Talanta., 67 640-645. Selective
  • Daniel, S., Babu, P. E. J., Rao, T. P., (2005) Preconcentrative Separation of Palladium(II) Using ... of Binding Parameters Based on Adsorption Isotherm Models, Talanta, 65(2): 441-452 .
  • Davis, A. C., Wu, P., Zhang, X. F., Hou, X. D., Jones B. T., (2006). Determination of cadmium in biological samples, Applied Spectroscopy Reviews 41, 35-75.
  • Ersöz, A., Say, R., Denizli A., (2004). Nickel(II) Ion- Imprinted Solid Phase Extraction and Preconcentration In Aqueous Solutions in Packed-Bed Columns, Analytica Chimica Acta, 502, 91-97
  • Fang, G. Z., Tan, J., Yan X. P., (2005). An ion- imprinted functionalized silica gel sorbent prepared techniquecombined with a sol–gel process for selective cadmium(II). Analytical Chemistry 77:1734– 1739 surface imprinting
  • solid-phaseextraction of
  • Gladis, J. M., Rao, T. P., (2003) Synthesis and analytical applications of uranyl ion imprinted polymer particles, Analytical Letters, 36, 2107-2121 .
  • Kala, R., Gladis, J. M., Rao, T. P., (2004). Preconcentrative separation of erbium from Y, Dy, Ho, Tb and Tm by using ion imprinted polymer particles viasolid phase extraction . Analytica Chimica Acta, 518: 143-150.
  • Karabork, M., Ersoz, A., Denizli, A., Say, R., (2008). Polymer-Clay Nanocomposite Iron Traps Based Industrial Research, 47, 2258-2264 .
  • Ion-Imprinting & Engineering Chemistry
  • Hg(II)-imprinted Chimica Acta, 538
  • Lu, Y. K., Yan, X. P., (2004). An imprinted organic- inorganic hybrid sorbent for selective separation of cadmium from aqueous solution Analytical Chemistry,76, 453-457.
  • Makote, R. D., Dai, S., (2001). Matrix-induced modification of imprinting effect for Cu2+ adsorption in hybrid silica matrices Analytica Chimica Acta, 435, 169-176.
  • Prasad, K., Kala, R., Rao, T. P., Naidu, G. R. K., (2006). Ion imprinted polymer based ion- selective electrode for the trace determination of dysprosium(III) ions Analytica Chimica Acta, 566, 69-74
  • Prasad, K., Gopikrishna, P., Kala, R., Rao, T. P., Naidu, G. R. K., (2006). Solid phase extraction preconcentration of cadmium and lead from soils embedded benzophenone and determination by FAAS, Talanta., 69, 938-945.
  • Ramstrom, O., Ye, L., Mosbach, K., (1996). Artificial prepared by molecular imprinting, Chemistry and Biology, 3, 471-477. to corticosteroids
  • Rosatzin, T., Andersson, L. I., Simon, W., Mosbach K., (1991). Preparation of Ca2+ selective sorbents by molecular imprinting using polymerizable ionophores, Journal of the Chemical Society, Perkin Transactions 2, 1261-1265 .
  • Saunders, G. D., Foxon, S. P., Walton, P. H., Joyce M. J., Port S. N., (2000).A selective uranium extraction agent prepared by polymer imprinting. Chemical Communications, 273- 274
  • Say, R., Birlik, E., Ersöz, A., Yilmaz, F., Gedikbey, T., Denizli, A., (2003). Preconcentration of copper on ion-selective imprinted polymer microbeads, Analytica Chimica Acta, 480, 251-258.
  • Vigneau, O., Pinel, C., Lemaire, M., (2002). “Solid- liquid separation of lanthanide/lanthanide and lanthanide/actinide using ionic imprinted polymer derivativeChemistry Letters, 202-203. on a DTPA
  • Wulff, G. (1995). Molecular imprinting in cross- linked materials with the aid of molecular templates - a way towards artificial antibodiesAngewandte Chemie International Edition 34 (17), 1812-1832.
  • Xie, F., Lin, X., Wu, X., Xie, Z. (2008). Solid phase extraction of lead (II), copper (II), cadmium (II) and nickel (II) using gallic acid-modified silica gel prior to determination by flame atomic absorption spectrometry Talanta., 74, 836–843
There are 33 citations in total.

Details

Primary Language English
Journal Section Articles
Authors

Ebru Ozkutuk

Publication Date May 11, 2015
Published in Issue Year 2015 Volume: 16 Issue: 1

Cite

APA Ozkutuk, E. (2015). SELECTIVE REMOVAL OF Cd(II) USING DOUBLE IMPRINTED POLYMER FROM SYNTHETIC WATER. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, 16(1), 15-22. https://doi.org/10.18038/btd-a.59620
AMA Ozkutuk E. SELECTIVE REMOVAL OF Cd(II) USING DOUBLE IMPRINTED POLYMER FROM SYNTHETIC WATER. AUJST-A. August 2015;16(1):15-22. doi:10.18038/btd-a.59620
Chicago Ozkutuk, Ebru. “SELECTIVE REMOVAL OF Cd(II) USING DOUBLE IMPRINTED POLYMER FROM SYNTHETIC WATER”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 16, no. 1 (August 2015): 15-22. https://doi.org/10.18038/btd-a.59620.
EndNote Ozkutuk E (August 1, 2015) SELECTIVE REMOVAL OF Cd(II) USING DOUBLE IMPRINTED POLYMER FROM SYNTHETIC WATER. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 16 1 15–22.
IEEE E. Ozkutuk, “SELECTIVE REMOVAL OF Cd(II) USING DOUBLE IMPRINTED POLYMER FROM SYNTHETIC WATER”, AUJST-A, vol. 16, no. 1, pp. 15–22, 2015, doi: 10.18038/btd-a.59620.
ISNAD Ozkutuk, Ebru. “SELECTIVE REMOVAL OF Cd(II) USING DOUBLE IMPRINTED POLYMER FROM SYNTHETIC WATER”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 16/1 (August 2015), 15-22. https://doi.org/10.18038/btd-a.59620.
JAMA Ozkutuk E. SELECTIVE REMOVAL OF Cd(II) USING DOUBLE IMPRINTED POLYMER FROM SYNTHETIC WATER. AUJST-A. 2015;16:15–22.
MLA Ozkutuk, Ebru. “SELECTIVE REMOVAL OF Cd(II) USING DOUBLE IMPRINTED POLYMER FROM SYNTHETIC WATER”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, vol. 16, no. 1, 2015, pp. 15-22, doi:10.18038/btd-a.59620.
Vancouver Ozkutuk E. SELECTIVE REMOVAL OF Cd(II) USING DOUBLE IMPRINTED POLYMER FROM SYNTHETIC WATER. AUJST-A. 2015;16(1):15-22.