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PT/BORAX COMPOSITE AS A HIGH DIELECTRIC CONSTANT MATERIAL WITH LOWER DIELECTRIC LOSS

Year 2017, Volume: 18 Issue: 5, 1089 - 1097, 31.12.2017

Abstract

In recent years, high dielectric
constant composites have been considered as the key materials for many
cutting-edge applications such as supercapacitors, memory devices, electrical,
mechanical, and biochemical engineering. However, the high dielectric loss at
low frequencies become a crucial problem which makes the composite unsuitable
for these technological applications. In this respect, this work has been
devoted to prepare a new high dielectric constant composite material with low
dielectric loss. From this point of view, Polythiophene /Na₂B₄O₇ (PT/Borax)
composites with different borax contents varying from 10.0 wt.% to 50.0 wt.% have been prepared. The morphology and chemical structure of the composites as
well as pure PT have been determined by Scanning Electron Microscopy (SEM) and
Fourier Transformed Infrared (FTIR) Spectroscopy, respectively. The dielectric
properties of the samples have been measured within 100Hz-16.5MHz frequency
region at room temperature. The polymer composite with high dielectric constant
and low dielectric loss at low frequency for various technological applications
has been achieved for 50.0 wt.% Borax additive. The dielectric relaxation
mechanism of the samples have also been identified as non-Debye type. The
electrical conductivity properties of the samples have also been discussed in
terms of Jonscher’s Universal power law.

References

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  • [2] ZHANG L, Cheng Z-Y. Development of polymer-based 0–3 composites with high dielectric constant. Journal of Advanced Dielectrics 2011;1:389-406.
  • [3] Tsui B-Y, Su T-T, Shew B-Y, Huang Y-T. Effect of surface preparation on the radiation hardness of high-dielectric constant gate dielectric. Solid-State Electronics 2013;81:119-23.
  • [4] Ribes G, Mitard J, Denais M, Bruyere S, Monsieur F, Parthasarathy C, et al. Review on high-k dielectrics reliability issues. IEEE Transactions on Device and materials Reliability 2005;5:5-19.
  • [5] Baldwin AF, Ma R, Mannodi‐Kanakkithodi A, Huan TD, Wang C, Tefferi M, et al. Poly (dimethyltin glutarate) as a prospective material for high dielectric applications. Advanced Materials 2015;27:346-51.
  • [6] Wan Y-J, Zhu P-L, Yu S-H, Yang W-H, Sun R, Wong C-P, et al. Barium titanate coated and thermally reduced graphene oxide towards high dielectric constant and low loss of polymeric composites. Composites Science and Technology 2017;141:48-55.
  • [7] Gumus OY, Unal HI, Erol O, Sari B. Synthesis, characterization, and colloidal properties of polythiophene/borax conducting composite. Polymer Composites 2011;32:418-26.
  • [8] Tarcan E. Structural and Dielectric Properties of Polythiophene/Chrom (III) Acetylacetonate Composites. Journal of Macromolecular Science, Part B 2015;54:897-906.
  • [9] Kim SH, Hyun K, Moon TS, Mitsumata T, Hong JS, Ahn KH, et al. Morphology–rheology relationship in hyaluronate/poly (vinyl alcohol)/borax polymer blends. Polymer 2005;46:7156-63.
  • [10] Seo K, Chung I. Reaction analysis of 3, 4-ethylenedioxythiophene with potassium persulfate in aqueous solution by using a calorimeter. Polymer 2000;41:4491-9.
  • [11] Tran-Van F, Garreau S, Louarn G, Froyer G, Chevrot C. Fully undoped and soluble oligo (3, 4-ethylenedioxythiophene) s: spectroscopic study and electrochemical characterization. Journal of Materials Chemistry 2001;11:1378-82.
  • [12] Vijayan M, Trivedi D. Studies on polyaniline in methane sulphonic acid (MeSA). Synthetic metals 1999;107:57-64.
  • [13] Cole KS, Cole RH. Dispersion and absorption in dielectrics I. Alternating current characteristics. The Journal of chemical physics 1941;9:341-51.
  • [14] Haase W, Wróbel S. Relaxation phenomena: liquid crystals, magnetic systems, polymers, high-Tc superconductors, metallic glasses: Springer Science & Business Media; 2013.
  • [15] Meller A. The System Boron-Nitrogen. B Boron Compounds: Springer; 1991. p. 1-261.
  • [16] Menczel JD, Prime RB. Thermal analysis of polymers: fundamentals and applications: John Wiley & Sons; 2014.
  • [17] Adam N, Uğur AL, Altındal A, Erdoğmuş A. Synthesis, characterization and dielectric properties of novel phthalocyanines bearing an octa-peripherally substituted mercaptoquinoline moiety. Polyhedron 2014;68:32-9.
  • [18] Jonscher AK. Dielectric relaxation in solids. Journal of Physics D: Applied Physics 1999;32:R57.
Year 2017, Volume: 18 Issue: 5, 1089 - 1097, 31.12.2017

Abstract

References

  • [1] Zhang L, Liu Z, Lu X, Yang G, Zhang X, Cheng Z-Y. Nano-clip based composites with a low percolation threshold and high dielectric constant. Nano Energy 2016;26:550-7.
  • [2] ZHANG L, Cheng Z-Y. Development of polymer-based 0–3 composites with high dielectric constant. Journal of Advanced Dielectrics 2011;1:389-406.
  • [3] Tsui B-Y, Su T-T, Shew B-Y, Huang Y-T. Effect of surface preparation on the radiation hardness of high-dielectric constant gate dielectric. Solid-State Electronics 2013;81:119-23.
  • [4] Ribes G, Mitard J, Denais M, Bruyere S, Monsieur F, Parthasarathy C, et al. Review on high-k dielectrics reliability issues. IEEE Transactions on Device and materials Reliability 2005;5:5-19.
  • [5] Baldwin AF, Ma R, Mannodi‐Kanakkithodi A, Huan TD, Wang C, Tefferi M, et al. Poly (dimethyltin glutarate) as a prospective material for high dielectric applications. Advanced Materials 2015;27:346-51.
  • [6] Wan Y-J, Zhu P-L, Yu S-H, Yang W-H, Sun R, Wong C-P, et al. Barium titanate coated and thermally reduced graphene oxide towards high dielectric constant and low loss of polymeric composites. Composites Science and Technology 2017;141:48-55.
  • [7] Gumus OY, Unal HI, Erol O, Sari B. Synthesis, characterization, and colloidal properties of polythiophene/borax conducting composite. Polymer Composites 2011;32:418-26.
  • [8] Tarcan E. Structural and Dielectric Properties of Polythiophene/Chrom (III) Acetylacetonate Composites. Journal of Macromolecular Science, Part B 2015;54:897-906.
  • [9] Kim SH, Hyun K, Moon TS, Mitsumata T, Hong JS, Ahn KH, et al. Morphology–rheology relationship in hyaluronate/poly (vinyl alcohol)/borax polymer blends. Polymer 2005;46:7156-63.
  • [10] Seo K, Chung I. Reaction analysis of 3, 4-ethylenedioxythiophene with potassium persulfate in aqueous solution by using a calorimeter. Polymer 2000;41:4491-9.
  • [11] Tran-Van F, Garreau S, Louarn G, Froyer G, Chevrot C. Fully undoped and soluble oligo (3, 4-ethylenedioxythiophene) s: spectroscopic study and electrochemical characterization. Journal of Materials Chemistry 2001;11:1378-82.
  • [12] Vijayan M, Trivedi D. Studies on polyaniline in methane sulphonic acid (MeSA). Synthetic metals 1999;107:57-64.
  • [13] Cole KS, Cole RH. Dispersion and absorption in dielectrics I. Alternating current characteristics. The Journal of chemical physics 1941;9:341-51.
  • [14] Haase W, Wróbel S. Relaxation phenomena: liquid crystals, magnetic systems, polymers, high-Tc superconductors, metallic glasses: Springer Science & Business Media; 2013.
  • [15] Meller A. The System Boron-Nitrogen. B Boron Compounds: Springer; 1991. p. 1-261.
  • [16] Menczel JD, Prime RB. Thermal analysis of polymers: fundamentals and applications: John Wiley & Sons; 2014.
  • [17] Adam N, Uğur AL, Altındal A, Erdoğmuş A. Synthesis, characterization and dielectric properties of novel phthalocyanines bearing an octa-peripherally substituted mercaptoquinoline moiety. Polyhedron 2014;68:32-9.
  • [18] Jonscher AK. Dielectric relaxation in solids. Journal of Physics D: Applied Physics 1999;32:R57.
There are 18 citations in total.

Details

Subjects Engineering
Journal Section Articles
Authors

Mehmet Kılıç

Yaşar Karabul This is me

Zeynep Güven Özdemir

Orhan İçelli

Publication Date December 31, 2017
Published in Issue Year 2017 Volume: 18 Issue: 5

Cite

APA Kılıç, M., Karabul, Y., Güven Özdemir, Z., İçelli, O. (2017). PT/BORAX COMPOSITE AS A HIGH DIELECTRIC CONSTANT MATERIAL WITH LOWER DIELECTRIC LOSS. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, 18(5), 1089-1097. https://doi.org/10.18038/aubtda.291255
AMA Kılıç M, Karabul Y, Güven Özdemir Z, İçelli O. PT/BORAX COMPOSITE AS A HIGH DIELECTRIC CONSTANT MATERIAL WITH LOWER DIELECTRIC LOSS. AUJST-A. December 2017;18(5):1089-1097. doi:10.18038/aubtda.291255
Chicago Kılıç, Mehmet, Yaşar Karabul, Zeynep Güven Özdemir, and Orhan İçelli. “PT/BORAX COMPOSITE AS A HIGH DIELECTRIC CONSTANT MATERIAL WITH LOWER DIELECTRIC LOSS”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 18, no. 5 (December 2017): 1089-97. https://doi.org/10.18038/aubtda.291255.
EndNote Kılıç M, Karabul Y, Güven Özdemir Z, İçelli O (December 1, 2017) PT/BORAX COMPOSITE AS A HIGH DIELECTRIC CONSTANT MATERIAL WITH LOWER DIELECTRIC LOSS. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 18 5 1089–1097.
IEEE M. Kılıç, Y. Karabul, Z. Güven Özdemir, and O. İçelli, “PT/BORAX COMPOSITE AS A HIGH DIELECTRIC CONSTANT MATERIAL WITH LOWER DIELECTRIC LOSS”, AUJST-A, vol. 18, no. 5, pp. 1089–1097, 2017, doi: 10.18038/aubtda.291255.
ISNAD Kılıç, Mehmet et al. “PT/BORAX COMPOSITE AS A HIGH DIELECTRIC CONSTANT MATERIAL WITH LOWER DIELECTRIC LOSS”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 18/5 (December 2017), 1089-1097. https://doi.org/10.18038/aubtda.291255.
JAMA Kılıç M, Karabul Y, Güven Özdemir Z, İçelli O. PT/BORAX COMPOSITE AS A HIGH DIELECTRIC CONSTANT MATERIAL WITH LOWER DIELECTRIC LOSS. AUJST-A. 2017;18:1089–1097.
MLA Kılıç, Mehmet et al. “PT/BORAX COMPOSITE AS A HIGH DIELECTRIC CONSTANT MATERIAL WITH LOWER DIELECTRIC LOSS”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, vol. 18, no. 5, 2017, pp. 1089-97, doi:10.18038/aubtda.291255.
Vancouver Kılıç M, Karabul Y, Güven Özdemir Z, İçelli O. PT/BORAX COMPOSITE AS A HIGH DIELECTRIC CONSTANT MATERIAL WITH LOWER DIELECTRIC LOSS. AUJST-A. 2017;18(5):1089-97.