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NOVEL CYCLOMATRIX-TYPE POLYPHOSPHAZENE MICROSPHERES CROSSLINKED WITH OCTACHLOROCYCLOTETRAPHOSPHAZENE: PREPARATION AND CHARACTERIZATION

Year 2017, Volume: 18 Issue: 5, 973 - 987, 31.12.2017
https://doi.org/10.18038/aubtda.312012

Abstract

In this
article, highly cross-linked inorganic and organic hybrid polyphosphazene
microspheres including amino groups on the surface have been successfully
obtained via self-assembly polycondensation approach using 4,4ʹ-diaminodiphenylmethane
and octachlorocyclotetraphosphazene which is a new crosslinker. Experiments
were performed without adding a surfactant or stabilizer, using only an
ultrasonic bath. Otherwise, effect of different molar ratios of the reactants,
reaction time and ultrasonic power were investigated on preparing
morphologically good spheres. The reactivity of octachlorocyclotetraphosphazene
was investigated comparing with hexachlorocyclotriphosphazene which is the most
popular crosslinker cyclic phosphazene molecule. The size of acquired microspheres
were approximately same, and 1.00μm. The novel microspheres were characterized
by SEM, FTIR, ZETA, UV, Fluorescense, XRD and TGA.

References

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  • Reference 2 Wang Y, Mu J, Li L, Shi L, Zhang W, Jiang Z. Preparation and properties of novel fluorinated cross-linked polyphosphazene micro-nano spheres. High Perform Polym 2012, 24(3): 229-236.
  • Reference 3 Mohanty P, Landskron K. Simple systematic synthesis of size-tunable covalent organophosphonitridic framework nano- and microspheres. New J Chem 2010, 34: 215-220.
  • Reference 4 Zhao Z, Ji J. Synthesis and Tribological Behaviors of Epoxy/Phosphazene-Microspheres Coatings under Dry Sliding Condition. Adv Eng Mater 2014, 16(8): 988-995.
  • Reference 5 Ozay H, Ozay O. Synthesis and characterization of drug microspheres containing phosphazene for biomedical applications. Colloids and Surfaces A: Physicochem. Eng. Aspects 2014, 450: 99-105.
  • Reference 6 Wei W, Huang X, Chen K, Tao Y, Tang X. Fluorescent organic–inorganic hybrid polyphosphazene microspheres for the trace detection of nitroaromatic explosives. RSC Adv 2012, 2: 3765-3771.
  • Reference 7 Fu J, Wang M, Zhang C, Zhang P, Xu Q. High hydrogen storage capacity of heteroatom-containing porous carbon nanospheres produced from cross-linked polyphosphazene nanospheres. Mater Lett 2012, 81: 215-218.
  • Reference 8 Wang D, Hu Y, Meng L, Wang X, Lu Q. One-pot synthesis of fluorescent and cross-linked polyphosphazene nanoparticles for highly sensitive and selective detection of dopamine in body fluids. RSC Adv 2015, 5: 92762-92768.
  • Reference 9 Pan T, Huang X, Wei H, Wei W, Tang X. Intrinsically Fluorescent Microspheres with Superior Thermal Stability and Broad Ultraviolet-Visible Absorption Based on Hybrid Polyphosphazene Material Macromol Chem Phys 2012, 213: 1590-1595.
  • Reference 10 Wang M, Fu J, Chen Z, Wang X, Xu Q. In situ growth of gold nanoparticles onto polyphosphazene microspheres with amino-groups for alcohol oxidation in aqueous solutions. Mater Lett 2015, 143: 201-204.
  • Reference 11 Tian Z, Hess A, Fellin CR, Nulwala H, Allcock HR. Phosphazene High Polymers and Models with Cyclic Aliphatic Side Groups: New Structure-Property Relationships. Macromolecules 2015, 48: 4301-4311.
  • Reference 12 Modzelewski T, Wilts E, Allcock HR. Elastomeric Polyphosphazenes with Phenoxy-Cyclotriphosphazene Side Groups. Macromolecules 2015, 48: 7543-7549.
  • Reference 13 Chen K, Huang X, Wan C, Liu H. Heteroatom-doped mesoporous carbon nanofibers based on highly cross-linked hybrid polymeric nanofibers: Facile synthesis and application in an electrochemical supercapacitor. Mater Chem Phys 2015, 164: 85-90.
  • Reference 14 Jin W, Yuan L, Liang G, Gu A, Multifunctional Cyclotriphosphazene/Hexagonal Boron Nitride Hybrids and Their Flame Retarding Bismaleimide Resins with High Thermal Conductivity and Thermal Stability. Appl Mater Interfaces 2014, 6: 14931-14944.
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  • Reference 17 Liu X, Breon JP,Chen C,Allcock HR. Substituent exchange reactions of trimeric and tetrameric aryloxycyclophosphazenes with sodium 2,2,2-trifluoroethoxide. Dalton. Trans 2012, 41: 2100-2109.
  • Reference 18 Zhu X, Liang Y, Zhang D, Wang L,Ye Y, Zhao Y. Synthesis and Characterization of Side Group–Modified Cyclotetraphosphazene Derivatives. Phosphorus Sulfur Silicon Relat Elem 2011,186: 281-286.
  • Reference 19 Krause WE, Parvez M, Visscher KB, Allcock HR. Synthesis and Structure of Adamantane-Containing Phosphazenes. Inorg Chem 1996, 35: 6337-6338.
  • Reference 20 Paasch S, Krüger K, Thomas B. Solid-state nuclear magnetic resonance investigations on chlorocyclophosphazenes. Solid State Nucl Mag 1995, 4: 267 280.
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  • Reference 22 Huang Z, Chen S, Lu X, Lu Q. Water-triggered self-assembly polycondensation for the one-pot synthesis of cyclomatrix polyphosphazene nanoparticles from amino acid ester. Chem Commun 2015, 51: 8373-8376.
  • Reference 23 Zhang JX, Qiu LY, Wu XL, Jin Y, Zhu KJ. Temperature-Triggered Nanosphere Formation Through Self-Assembly of Amphiphilic Polyphosphazene. Macromol Chem Phys 2006, 207(14): 1289-1296.
  • Reference 24 Zhang P, Huang X, Fu J, Huang Y, Zhu Y, Tang X. A One-Pot Approach to Novel Cross-Linked Polyphosphazene Microspheres with Active Amino Groups. Macromol Chem and Phys 2009,210: 792-798.
  • Reference 25 Wei W, Lu R, Ye W, Sun J, Zhu Y, Luo J, Liu X. Liquid Marbles Stabilized by Fluorine-Bearing Cyclomatrix Polyphosphazene Particles and Their Application as High-Efficiency Miniature Reactors. Langmuir 2016, 32(7): 1707 1715.
  • Reference 26 Chen C, Zhu X, Gao Q, Fang F, Wang L, Huang X. Immobilization of lipase onto functional cyclomatrix polyphosphazene microspheres. J Mol Catal B-Enzym 2016, 132: 67-74.
  • Reference 27 Fu J, Chen Z, Wu X, Wang M, Wang X, Zhang J, Zhang J, Xu Q. Hollow poly(cyclo triphosphazene-co-phloroglucinol) microspheres: An effective and selective adsorbent for the removal of cationic dyes from aqueous solution. Chem Eng J 2015, 281: 42-52.
  • Reference 28 Liu W, Huang X, Wei H, Chen K, Gao J, Tang X. Facile preparation of hollow crosslinked polyphosphazene submicrospheres with mesoporous shells. J Mater Chem 2011, 21(34): 12964-12968.
  • Reference 29 Zhu Y, Fu J, Zhu L, Tang X, Huang X. Preparation of novel hybrid inorganic–organic hollow microspheres via a self-template approach. Polym Int 2008, 57(3): 449 453.
  • Reference 30 Chang F, Huang X, Wei H, Chen K, Shan C, Tang X. Intrinsically fluorescent hollow spheres based on organic–inorganic hybrid polyphosphazene material: Synthesis and application in drug release. Mater Lett 2014, 125: 128 131.
  • Reference 31 Fu J, Wang M, Zhang C, Wang X, Wang H, Xu Q. Template-induced covalent assembly of hybrid particles for the facile fabrication of magnetic Fe3O4–polymer hybrid hollow microspheres. J Mater Sci 2013, 48(9): 3557-3565.
  • Reference 32 Hu Y, Meng L, Niu L, Lu Q. Highly Cross-Linked and Biocompatible Polyphosphazene-Coated Superparamagnetic Fe3O4 Nanoparticles for Magnetic Resonance Imaging. Langmuir 2013, 29(29): 9156-9163.
  • Reference 33 Tang X, Huang X. Modern Inorganic Synthetic Chemistry, Elsevier, AMSTERDAM, 2011.
Year 2017, Volume: 18 Issue: 5, 973 - 987, 31.12.2017
https://doi.org/10.18038/aubtda.312012

Abstract

References

  • Reference 1 Köhler J, Kühl S, Keul H, Möller M, Pich A. Synthesis and Characterization of Polyamine-Based Cyclophosphazene Hybrid Microspheres. J Polym Sci Pol Chem 2014, 52: 527-536.
  • Reference 2 Wang Y, Mu J, Li L, Shi L, Zhang W, Jiang Z. Preparation and properties of novel fluorinated cross-linked polyphosphazene micro-nano spheres. High Perform Polym 2012, 24(3): 229-236.
  • Reference 3 Mohanty P, Landskron K. Simple systematic synthesis of size-tunable covalent organophosphonitridic framework nano- and microspheres. New J Chem 2010, 34: 215-220.
  • Reference 4 Zhao Z, Ji J. Synthesis and Tribological Behaviors of Epoxy/Phosphazene-Microspheres Coatings under Dry Sliding Condition. Adv Eng Mater 2014, 16(8): 988-995.
  • Reference 5 Ozay H, Ozay O. Synthesis and characterization of drug microspheres containing phosphazene for biomedical applications. Colloids and Surfaces A: Physicochem. Eng. Aspects 2014, 450: 99-105.
  • Reference 6 Wei W, Huang X, Chen K, Tao Y, Tang X. Fluorescent organic–inorganic hybrid polyphosphazene microspheres for the trace detection of nitroaromatic explosives. RSC Adv 2012, 2: 3765-3771.
  • Reference 7 Fu J, Wang M, Zhang C, Zhang P, Xu Q. High hydrogen storage capacity of heteroatom-containing porous carbon nanospheres produced from cross-linked polyphosphazene nanospheres. Mater Lett 2012, 81: 215-218.
  • Reference 8 Wang D, Hu Y, Meng L, Wang X, Lu Q. One-pot synthesis of fluorescent and cross-linked polyphosphazene nanoparticles for highly sensitive and selective detection of dopamine in body fluids. RSC Adv 2015, 5: 92762-92768.
  • Reference 9 Pan T, Huang X, Wei H, Wei W, Tang X. Intrinsically Fluorescent Microspheres with Superior Thermal Stability and Broad Ultraviolet-Visible Absorption Based on Hybrid Polyphosphazene Material Macromol Chem Phys 2012, 213: 1590-1595.
  • Reference 10 Wang M, Fu J, Chen Z, Wang X, Xu Q. In situ growth of gold nanoparticles onto polyphosphazene microspheres with amino-groups for alcohol oxidation in aqueous solutions. Mater Lett 2015, 143: 201-204.
  • Reference 11 Tian Z, Hess A, Fellin CR, Nulwala H, Allcock HR. Phosphazene High Polymers and Models with Cyclic Aliphatic Side Groups: New Structure-Property Relationships. Macromolecules 2015, 48: 4301-4311.
  • Reference 12 Modzelewski T, Wilts E, Allcock HR. Elastomeric Polyphosphazenes with Phenoxy-Cyclotriphosphazene Side Groups. Macromolecules 2015, 48: 7543-7549.
  • Reference 13 Chen K, Huang X, Wan C, Liu H. Heteroatom-doped mesoporous carbon nanofibers based on highly cross-linked hybrid polymeric nanofibers: Facile synthesis and application in an electrochemical supercapacitor. Mater Chem Phys 2015, 164: 85-90.
  • Reference 14 Jin W, Yuan L, Liang G, Gu A, Multifunctional Cyclotriphosphazene/Hexagonal Boron Nitride Hybrids and Their Flame Retarding Bismaleimide Resins with High Thermal Conductivity and Thermal Stability. Appl Mater Interfaces 2014, 6: 14931-14944.
  • Reference 15 Süzen Y, Metinoğlu S. Synthesis and characterization of novel inorganic and organic hybrid poly[cyclotriphosphazene-co-(4,4'-diaminodiphenylmethane)] microspheres via one-pot self-assembly polycondensation approach. J Turkish Chem Soc Sect Chem (JOTCSA) 2016, 3 (2): 167-182.
  • Reference 16 Beşli S, Mutlu C, İbişoğlu H, Yüksel F, Allen CW. Synthesis of a New Class of Fused Cyclotetraphosphazene Ring Systems. Inorg Chem 2015, 54: 334-341.
  • Reference 17 Liu X, Breon JP,Chen C,Allcock HR. Substituent exchange reactions of trimeric and tetrameric aryloxycyclophosphazenes with sodium 2,2,2-trifluoroethoxide. Dalton. Trans 2012, 41: 2100-2109.
  • Reference 18 Zhu X, Liang Y, Zhang D, Wang L,Ye Y, Zhao Y. Synthesis and Characterization of Side Group–Modified Cyclotetraphosphazene Derivatives. Phosphorus Sulfur Silicon Relat Elem 2011,186: 281-286.
  • Reference 19 Krause WE, Parvez M, Visscher KB, Allcock HR. Synthesis and Structure of Adamantane-Containing Phosphazenes. Inorg Chem 1996, 35: 6337-6338.
  • Reference 20 Paasch S, Krüger K, Thomas B. Solid-state nuclear magnetic resonance investigations on chlorocyclophosphazenes. Solid State Nucl Mag 1995, 4: 267 280.
  • Reference 21 Beşli S, İbişoğlu H, Kılıç A, Ün İ, Yüksel F. Spiro, ansa-derivatives of cyclotetraphosphazenes with a tetrafluorobutane-1,4-diol. Polyhedron 2010, 29(17): 3220-3228.
  • Reference 22 Huang Z, Chen S, Lu X, Lu Q. Water-triggered self-assembly polycondensation for the one-pot synthesis of cyclomatrix polyphosphazene nanoparticles from amino acid ester. Chem Commun 2015, 51: 8373-8376.
  • Reference 23 Zhang JX, Qiu LY, Wu XL, Jin Y, Zhu KJ. Temperature-Triggered Nanosphere Formation Through Self-Assembly of Amphiphilic Polyphosphazene. Macromol Chem Phys 2006, 207(14): 1289-1296.
  • Reference 24 Zhang P, Huang X, Fu J, Huang Y, Zhu Y, Tang X. A One-Pot Approach to Novel Cross-Linked Polyphosphazene Microspheres with Active Amino Groups. Macromol Chem and Phys 2009,210: 792-798.
  • Reference 25 Wei W, Lu R, Ye W, Sun J, Zhu Y, Luo J, Liu X. Liquid Marbles Stabilized by Fluorine-Bearing Cyclomatrix Polyphosphazene Particles and Their Application as High-Efficiency Miniature Reactors. Langmuir 2016, 32(7): 1707 1715.
  • Reference 26 Chen C, Zhu X, Gao Q, Fang F, Wang L, Huang X. Immobilization of lipase onto functional cyclomatrix polyphosphazene microspheres. J Mol Catal B-Enzym 2016, 132: 67-74.
  • Reference 27 Fu J, Chen Z, Wu X, Wang M, Wang X, Zhang J, Zhang J, Xu Q. Hollow poly(cyclo triphosphazene-co-phloroglucinol) microspheres: An effective and selective adsorbent for the removal of cationic dyes from aqueous solution. Chem Eng J 2015, 281: 42-52.
  • Reference 28 Liu W, Huang X, Wei H, Chen K, Gao J, Tang X. Facile preparation of hollow crosslinked polyphosphazene submicrospheres with mesoporous shells. J Mater Chem 2011, 21(34): 12964-12968.
  • Reference 29 Zhu Y, Fu J, Zhu L, Tang X, Huang X. Preparation of novel hybrid inorganic–organic hollow microspheres via a self-template approach. Polym Int 2008, 57(3): 449 453.
  • Reference 30 Chang F, Huang X, Wei H, Chen K, Shan C, Tang X. Intrinsically fluorescent hollow spheres based on organic–inorganic hybrid polyphosphazene material: Synthesis and application in drug release. Mater Lett 2014, 125: 128 131.
  • Reference 31 Fu J, Wang M, Zhang C, Wang X, Wang H, Xu Q. Template-induced covalent assembly of hybrid particles for the facile fabrication of magnetic Fe3O4–polymer hybrid hollow microspheres. J Mater Sci 2013, 48(9): 3557-3565.
  • Reference 32 Hu Y, Meng L, Niu L, Lu Q. Highly Cross-Linked and Biocompatible Polyphosphazene-Coated Superparamagnetic Fe3O4 Nanoparticles for Magnetic Resonance Imaging. Langmuir 2013, 29(29): 9156-9163.
  • Reference 33 Tang X, Huang X. Modern Inorganic Synthetic Chemistry, Elsevier, AMSTERDAM, 2011.
There are 33 citations in total.

Details

Subjects Engineering
Journal Section Articles
Authors

Yasemin Süzen

Simge Metinoğlu

Publication Date December 31, 2017
Published in Issue Year 2017 Volume: 18 Issue: 5

Cite

APA Süzen, Y., & Metinoğlu, S. (2017). NOVEL CYCLOMATRIX-TYPE POLYPHOSPHAZENE MICROSPHERES CROSSLINKED WITH OCTACHLOROCYCLOTETRAPHOSPHAZENE: PREPARATION AND CHARACTERIZATION. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, 18(5), 973-987. https://doi.org/10.18038/aubtda.312012
AMA Süzen Y, Metinoğlu S. NOVEL CYCLOMATRIX-TYPE POLYPHOSPHAZENE MICROSPHERES CROSSLINKED WITH OCTACHLOROCYCLOTETRAPHOSPHAZENE: PREPARATION AND CHARACTERIZATION. AUJST-A. December 2017;18(5):973-987. doi:10.18038/aubtda.312012
Chicago Süzen, Yasemin, and Simge Metinoğlu. “NOVEL CYCLOMATRIX-TYPE POLYPHOSPHAZENE MICROSPHERES CROSSLINKED WITH OCTACHLOROCYCLOTETRAPHOSPHAZENE: PREPARATION AND CHARACTERIZATION”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 18, no. 5 (December 2017): 973-87. https://doi.org/10.18038/aubtda.312012.
EndNote Süzen Y, Metinoğlu S (December 1, 2017) NOVEL CYCLOMATRIX-TYPE POLYPHOSPHAZENE MICROSPHERES CROSSLINKED WITH OCTACHLOROCYCLOTETRAPHOSPHAZENE: PREPARATION AND CHARACTERIZATION. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 18 5 973–987.
IEEE Y. Süzen and S. Metinoğlu, “NOVEL CYCLOMATRIX-TYPE POLYPHOSPHAZENE MICROSPHERES CROSSLINKED WITH OCTACHLOROCYCLOTETRAPHOSPHAZENE: PREPARATION AND CHARACTERIZATION”, AUJST-A, vol. 18, no. 5, pp. 973–987, 2017, doi: 10.18038/aubtda.312012.
ISNAD Süzen, Yasemin - Metinoğlu, Simge. “NOVEL CYCLOMATRIX-TYPE POLYPHOSPHAZENE MICROSPHERES CROSSLINKED WITH OCTACHLOROCYCLOTETRAPHOSPHAZENE: PREPARATION AND CHARACTERIZATION”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 18/5 (December 2017), 973-987. https://doi.org/10.18038/aubtda.312012.
JAMA Süzen Y, Metinoğlu S. NOVEL CYCLOMATRIX-TYPE POLYPHOSPHAZENE MICROSPHERES CROSSLINKED WITH OCTACHLOROCYCLOTETRAPHOSPHAZENE: PREPARATION AND CHARACTERIZATION. AUJST-A. 2017;18:973–987.
MLA Süzen, Yasemin and Simge Metinoğlu. “NOVEL CYCLOMATRIX-TYPE POLYPHOSPHAZENE MICROSPHERES CROSSLINKED WITH OCTACHLOROCYCLOTETRAPHOSPHAZENE: PREPARATION AND CHARACTERIZATION”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, vol. 18, no. 5, 2017, pp. 973-87, doi:10.18038/aubtda.312012.
Vancouver Süzen Y, Metinoğlu S. NOVEL CYCLOMATRIX-TYPE POLYPHOSPHAZENE MICROSPHERES CROSSLINKED WITH OCTACHLOROCYCLOTETRAPHOSPHAZENE: PREPARATION AND CHARACTERIZATION. AUJST-A. 2017;18(5):973-87.