Karbon Çeliğinin Hidroklorik Asit Çözeltisindeki Korozyonuna Allantoin İçeren Schiff Bazınınİnhibitör Etkisi

Abstract

1,0 M HCl çözeltisi içerisinde 293 K’de yumuşak çeliğin korozyon davranışı üzerine (E)-1-(2-hidroksi-5-metoksibenziliden)-3-(2,5-diokzoimidazolin-4-il) molekülünün inhibitör etkisi araştırılmıştır. ALMS molekülünün korozyon inhibisyon etkinliği lineer polarizasyon direnci, potansiyodinamik polarizasyon eğrileri ve ACimpedans yöntemleri kullanılarak değerlendirilmiştir. Schiff bazının yumuşak çelik yüzeyine adsorpsiyonun Langmuir adsorpsiyon izotermine uyduğu görülmüştür. Adsorpsiyon izoterminden yararlanarak termodinamik adsorpsiyon parametreleri olan adsorpsiyon denge sabiti ve adsorpsiyon serbest enerjisi değeri hesaplanmıştır

Keywords

• Yumuşak çelik, schiff bazı, korozyon inhibitörü, SEM, AFM

The Inhibition Effect of Schiff Base Compound Containing Allantoin on Carbon Steel Corrosion in Hydrochloric Acid Solution

Abstract

The effect of (E)-1-(2-hydroxy-5-methoxybenzylidene)-3-(2,5-dioxoimidazolidin-4-yl) urea (ALMS) on corrosion behaviour of mild steel in 1.0 M HCl has been investigated at 293 K. The corrosion inhibition efficiency of ALMS has been evaluated by using potentiodynamic polarization curves, linear polarization resistance and electrochemical impedance spectroscopy techniques. ALMS molecule appears to function through the Langmuir adsorption isotherm. Thermodynamic parameters of adsorption of studied molecule were calculated using adsorption isotherm

Keywords

• Mild steel, schiff base, corrosion inhibitor, SEM, AFM

References

1. [1] Moretti, G., Guidi, F., Grion, G., Tryptamine as a green iron corrosion inhibitor in 0.5 M deaerated sulphuric acid, Corrosion Science, 46, 387–403, (2004).
2. [2] Ferreira, E.S., Giacomelli, C., Giacomellia, F.C., Spinelli, Evaluation of the inhibitor Effect of L-ascorbic acid on the corrosion of mild steel, Material Chemistry and Physics, 83, 129–134, (2004).
3. [3] Goncalves, R.S., Mello, L.D., Electrochemical investigation of ascorbic acid adsorption on low-carbon steel in 0.50 M Na2SO4 solutions, Corrosion Science, 43, 457–470, (2001).
4. [4] Giacomelli, F.C., Giacomelli, C., Amadori, M.F., Schmidt, V., Spinelli, A., Inhibitor effect of succinic acid on the corrosion resistance of mild steel: electrochemical, gravimetric and optical microscopic studies, Material Chemistry and Physics, 83, 124–128, (2004).
5. [5] Amin, M.A., El-Rehim, S.S.A., El-Sherbini, E.E.F., Bayoumy, R.S., The inhibition of low carbon steel corrosion in hydrochloric acid solutions by succinic acid: Part I. Weight loss, polarization, EIS, PZC, EDX and SEM studies, Electrochimica Acta, 52, 3588–3600, (2007).
6. [6] Fallavena, T., Antonow, M., Gonçalves, R.S., Caffeine as non-toxic corrosion inhibitor for copper in aqueous solutions of potassium nitrate, Applied Surface Science, 253, 566–571, (2006).
7. [7] Bouyanzer, A., Hammouti, B., Majidi, L., Pennyroyal oil from Mentha pulegium as corrosion inhibitor for steel in 1 M HCl, Materials Letters, 60, 2840–2843, (2006).
8. [8] Rahim, A.A., Rocca, E., Steinmetz, J., Kassim, M.J., Inhibitive action of mangrove tannins and phosphoric acid on pre-rusted steel via electrochemical methods Corrosion Science, 50, 1546–1550, (2008).

9. [9] Chauhan, L.R., Gunasekaran, G., Corrosion inhibition of mild steel by plant extract in dilute HCl medium, Corrosion Science, 49, 1143–1161, (2007).
10. [10] İspir, E., The synthesis, characterization, electrochemical character, catalytic and antimicrobial activity of novel, azo-containing Schiff bases and their metal complexes, Dyes and Pigments, 82,13–19, (2009).
11. [11] Liang, Z., Liu, Z., Gao, Y., Synthesis, characterization and photochromic studies of three novel calix[4]arene–Schiff bases, Spectrochimica Acta Part A, 68, 1231-1235, 2007.
12. [12] R.C., Felicio, E.T.G., Canalheiro, E.R., Dockal, Preparation, characterization and thermogravimetric studies of[N,N%-cis-1,2-cyclohexylene bis(salicylideneaminato)] cobalt(II) and [N,N%-(9)-trans-1,2-cyclohexylene bis(salicylideneaminato)]cobalt(II), Polyhedron, 20, 261–268, (2001).
13. [13] Tahaa, Z. A., Ajlounia, A. M., Al-Hassan, K.A., Hijazi, A. K., Faiq, A. B., Syntheses, characterization, biological activity and fluorescence properties of bis- (salicylaldehyde)-1,3-propylenediimine Schiff base ligand and its lanthanide complexes, Spectrochimica Acta Part A, 81, 317– 323, (2011).
14. [14] Saheb, V., Sheikhshoaie, I., A new Schiff base compound N,N_-(2,2- dimetylpropane)-bis(dihydroxylacetophenone): Synthesis, experimental and theoretical studieson its crystal structure, FTIR, UV–visible, 1H NMR and 13C NMR spectra, Spectrochimica Acta Part A, 81, 144-150, (2011).
15. [15] Kristina, M.H., Starcevi, S.K., Lucin, P.P., Paveli, K., Zamola, G.K., Synthesis, spectroscopic characterization and antiproliferative evaluation in vitro of novel
16. Schiff bases related to benzimidazoles, European Journal Medicina Chememistry, 46, 2274-2279, (2011).
17. [16] Yurt, A., Duran, B., Dal, H., An experimental and theroretical investigaton on adsorption properties of some diphenolic Schiff bases as corrosion inhibitors at acidic solution/ mild steel interface, Arabian Journal of Chemistry (2010), doi:10.1016/j.arabjc.2010.12.010 (Article in press).
18. [17] Bentiss, F., Traisnel, M., Vezin, H., Hildebrand, H.F., Lagrenée, M., 2,5-Bis(4- dimethylaminophenyl)-1,3,4-oxadiazole and 2,5-bis(4-dimethylaminophenyl)- 1,3,4-thiadiazole as corrosion inhibitors for mild steel in acidic media, Corrosion Science, 46, 2781–2792, (2004).
19. [18] Erbil, M., The determination of corrosion rates by analysis of AC impedance diagrams, Chimica Acta Turcica, 1, 59–70, (1988).
20. [19] Bayol, E., Gurten, T., Gurten, A. A.,Erbil, M, Interactions of some Schiff base compounds with mild steel surface in hydrochloric acid solution, Materials Chemistry and Physics, 112, 624–630, (2008).
21. [20] Solmaz, R., Altunbas, E., Kardas, G., Adsorption and corrosion inhibition effect of 2-((5-mercapto-1,3,4-thiadiazol-2-ylimino)methyl)phenol Schiff base on mild steel, Materials Chemistry and Physics, 125, 796–801, (2011).
22. [21] Sürme, Y., Gürten, A.A., Bayol, E., Corrosion behavior of mild steel in the presence of scale inhibitor in sulfuric acid solution, Protection of Metals and Physical Chemistry of Surfaces, 47, 117–120, (2011).
23. [22] Behpour, M., Ghoreishi, S.M., Soltani, N., Salavati-Niasari, M., The inhibitive effect of some bis-N,S-bidentate Schiff bases on corrosion behaviour of 304 stainless steel in hydrochloric acid solution, Corrosion Science, 51, 1073–1082, (2009).
24. [23] Branzoi, A., Branzoi, F., Baibarac, M., The Inhibition of the Corrosion of Armco Iron in HCl Solutions in the Presence of Surfactants of the Type of N-Alkyl Quaternary Ammonium Salts, Materials Chemistry and Physics, 65, 288-297, (2000).
25. [24] Chang, R., Chemistry, Fifth Edition, McGraw-Hill, USA, 736-758, (1994).
26. [25] Hilal, N. Bowen, W.R. Alkhatib L., Ogunbiyi, O., A review of atomic force microscopy applied to cell interactions with membranes, Chemical Engineering Research and Design, 84, 282–292, (2006).
27. [26] Döner, A., Solmaz, R., Kardaş, G., Experimental and theoretical studies of thiazoles as corrosion inhibitors for mild steel in sulphuric acid solution, Corrosion Science, 53, 2902–2913, (2011).
28. [27] Mu, G., Li, X., Inhibition of cold rolled steel corrosion by Tween-20 in sulfuric acid: Weight loss, electrochemical and AFM approaches, Journal of Colloid and Interface Science, 289, 184–192, (2005).
29. [28] Kumar, Y.D., Maiti, B., Quraishi, M.A., Electrochemical and quantum chemical studies of 3,4-dihydropyrimidin-2(1H)-ones as corrosion inhibitors for mild steel in hydrochloric acid solution, Corrosion Science, 52, 3586–3598, (2010).
30. [29] Shokry H., Yuasa M., Sekine I., Issa R.M., El-Baradie H.Y., Gomma G. K., Corrosion Inhibition of Mild Steel by Schiff Base Compounds in Various Aqueous Solutions, Corrosion Science, 40, 2173-2186, (1998).
31. [30] Sorkhabi A.H., Shaabani B., Seifzadeh D., Corrosion Inhibition of Mild Steel by Some Schiff Base Compounds in Hydrochloric Acid, Applied Surface Science, 239, 154-64, (2005).
32. [31] Arslan, T., Kandemirli, F., Ebenso, E. E., Love, I., Alemu, H., Quantum chemical studies on the corrosion inhibition of some sulphonamides on mild steel in acidic medium, Corrosion Science, 51, 35–47, (2009).
33. [32] Yüce, A.O., Kardas, G., Adsorption and inhibition effect of 2-thiohydantoin on mild steel corrosionin 0.1 M HCl, Corrosion Science, 58, 86–94, (2012).
34. [33] Özkır, D., Kayakırılmaz, K., Bayol, E., Gurten, A.A., Kandemirli, F., The inhibition effect of Azure A on mild steel in 1 M HCl. A complete study: Adsorption, temperature, duration and quantum chemical aspects, Corrosion Science, 56, 143–152, (2012).