Yeni okzadiazol ve triazol bazlı kaliksaren türevlerinin sentezi ve ekstraksiyon özellikleri

Abstract

Bu çalışmada, okzadiazol ve triazol türevi taşıyan iki yeni kaliksaren türevi bileşik sentezlendi. Elde edilen nihai ürünlerin yapıları 1H-NMR, 13C-NMR, FT-IR ve HR-MS analizleri ile aydınlatıldı. Bu bileşikler ile sıvı-sıvı ekstraksiyonu yapılarak sulu çözeltideki metil oranjın uzaklaştırılmasında etkinlikleri değerlendirildi. Ayrıca ekstraksiyon yüzdesi üzerine H+ iyonu konsantrasyonu ve NaCl konsantrasyonunun etkisi incelendi. Elde edilen sonuçlar ekstraksiyon yüzdesinin H+ iyonu konsantrasyonuna bağlı olduğunu gösterdi. Triazol türevi 5 için sulu ortamdan metil oranjın uzaklaştırılma yüzdesi % 53.3 olarak bulundu.

Keywords

• Kaliksaren
• okzadiazol
• triazol
• ekstraksiyon.

Novel oxadiazole- and triazole-based calixarene derivatives: synthesis and extraction properties

Abstract

Two new calixarene derivative compounds bearing oxadiazole and triazole groups were synthesized. The final products were illuminated by using 1H-NMR, 13C-NMR, FT-IR and HR-MS. The extraction efficiency of these compounds was investigated in the removal of methyl orange. In addition, the effect of H+ ion concentration in extraction studies conducted in different pH ranges and the effect of NaCl concentration on the percentage of extraction was examined. The results obtained showed that the percentage of extraction was highly dependent on the H+ ion concentration. It was found that the percentage of methyl orange removal was 53.3% for triazole derivatives 5.

Keywords

• calixarene
• oxadiazole
• triazole
• extraction

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