A new boronic acid and boronate esters containing polymer groups: synthesis and investigation of their spectroscopic properties

Abstract

With the increasing importance of chemical compounds containing the boron element day by day, original studies have been included. For this aim, a new boronic acid and boronate esters containing polymer groups were synthesized by the reaction methoxypolyethylene glycol amine and 4-formylphenylboronic acid for the firstly. Then, as a result of the dehydration reaction of the new boronic acid containing polymer groups with various diols, the boronate esters containing polymer groups were obtained. The structure of the resulting new boron-doped polymers was successfully synthesized. The structures of these polymers were elucidated by NMR (1H, 13C and 11B), LC-MS/MS spectrometer, IR, UV-Vis absorbance spectroscopy and fluorescence spectroscopy.

Keywords

• Boronate ester
• Boron polymer
• Synthesis
• Spectroscopy

Polimer grupları içeren yeni bir boronik asit ve boronat esterleri: spektroskopik özelliklerinin sentezi ve araştırılması

Abstract

Bor elementini içeren kimyasal bileşiklerin gün geçtikçe artan önemi ile özgün çalışmalara yer verilmiştir. Bu amaçla ilk olarak metoksipolietilen glikol amin ve 4-formilfenilboronik asit reaksiyonu ile polimer grupları içeren yeni bir boronik asit ve boronat esterleri sentezlendi. Daha sonra yeni boronik asit içeren polimer grubunun çeşitli diollerle dehidrasyon reaksiyonu sonucunda polimer grupları içeren boronat esterleri elde edilmiştir. Ortaya çıkan yeni bor katkılı polimerlerin yapısı başarıyla sentezlendi. Bu polimerlerin yapıları NMR (1H, 13C ve 11B), LC-MS/MS spektrometresi, IR, UV-Vis absorbans spektroskopisi ve floresan spektroskopisi ile aydınlatıldı.

Keywords

• Boronat ester
• Boron polimer
• Sentez
• Spektroskopi

Supporting Institution

Harran Üniversitesi

Thanks

Bu çalışması Harran Üniversitesi Bilimsel Araştırma Proje (HUBAP) birimi tarafından desteklenmiştir.

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