Review

A review on reactor design parameters of sodium borohydride (NaBH4) hydrolysis

Volume: 10 Number: 2 June 30, 2025
EN TR

A review on reactor design parameters of sodium borohydride (NaBH4) hydrolysis

Abstract

Sodium borohydride (NaBH4) is a promising hydrogen storage medium, but its practical implementation remains challenging. The aim of this study is to examine the effect of critical parameters, to investigate the methods and techniques used in the literature, and to provide information about the issues affecting the reactor design of NaBH4 hydrolysis. In this way, it is expected that the study will contribute to the commercialization of sodium borohydride and commercial product development efforts. This study discusses the effects of various parameters, such as NaBH4 ratio, sodium hydroxide (NaOH) ratio, fuel flow rate, temperature, and pressure. The manuscript also introduces reactor designs, materials, separation, and purification methods. Additionally, the study highlights challenges related to catalyst durability and the transient behavior of the reactor.

Keywords

Ethical Statement

There is no need for permission from the ethics committee for the article prepared

References

  1. [1] Yüksel, Y. E., & Öztürk, M. (2020). Thermodynamic analysis of a multigeneration energy system based geothermal energy. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi, 26(1), 113–121. https://doi.org/10.5505/pajes.2019.98411
  2. [2] Nacar, S., Öncü, S., & Kayfeci, M. (2022). Induction heated metal hydride tube for hydrogen storage system. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi, 28(5), 676–680. https://doi.org/10.5505/pajes.2021.97692
  3. [3] Long, B., Chen, J., Sharshir, S. W., Ibrahim, L., Zhou, W., Wang, C., … & Yuan, Z. (2024). The mechanism and challenges of cobalt-boron-based catalysts in the hydrolysis of sodium borohydride. Journal of Materials Chemistry A, 12, 5606–5625. https://doi.org/10.1039/d3ta07308d
  4. [4] Wang, X., Liao, J., Li, H., Wang, H., Wang, R., Pollet, B.G., & Ji, S.(2018). Highly active porous Co–B nanoalloy synthesized on liquid-gas interface for hydrolysis of sodium borohydride. International Journal of Hydrogen Energy, 43(37), 17543–17555. https://doi.org/10.1016/J.IJHYDENE.2018.07.147
  5. [5] Hoşgün, S., & Hoşgün, Z. (2024). Optimization of hydrogen generation rate with Co/MMT catalyst from NaBH4 using Box-Behnken method. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi, 30(1), 87–94. https://doi.org/10.5505/pajes.2023.34919
  6. [6] Liu, B., Rose, A., Zhang, N., Hu, Y. Y., & Ma, M. (2017). Efficient co-nanocrystal-based catalyst for hydrogen generation from borohydride. Journal of Physical Chemistry C, 121(23), 12610–12616. https://doi.org/10.1021/ACS.JPCC.7B03094
  7. [7] Yu, Y., Kang, L., Sun, L., Xu, F., Pan, H., Sang, Z., … & Li, B. (2022). Bimetallic Pt-Ni nanoparticles confined in porous titanium oxide cage for hydrogen generation from NaBH4 hydrolysis. Nanomaterials, 12(2550), 1–12. https://doi.org/10.3390/NANO12152550
  8. [8] Shen, X., Wang, Q., Wu, Q., Guo, S., Zhang, Z., … & Li, B. (2015). CoB supported on Ag-activated TiO2 as a highly active catalyst for hydrolysis of alkaline NaBH4 solution. Energy, 90, 464–474. https://doi.org/10.1016/J.ENERGY.2015.07.075

Details

Primary Language

English

Subjects

Inorganic Chemistry (Other)

Journal Section

Review

Publication Date

June 30, 2025

Submission Date

January 3, 2025

Acceptance Date

June 15, 2025

Published in Issue

Year 2025 Volume: 10 Number: 2

APA
Kaya, C. (2025). A review on reactor design parameters of sodium borohydride (NaBH4) hydrolysis. Journal of Boron, 10(2), 68-84. https://doi.org/10.30728/boron.1612416
AMA
1.Kaya C. A review on reactor design parameters of sodium borohydride (NaBH4) hydrolysis. Journal of Boron. 2025;10(2):68-84. doi:10.30728/boron.1612416
Chicago
Kaya, Cenk. 2025. “A Review on Reactor Design Parameters of Sodium Borohydride (NaBH4) Hydrolysis”. Journal of Boron 10 (2): 68-84. https://doi.org/10.30728/boron.1612416.
EndNote
Kaya C (June 1, 2025) A review on reactor design parameters of sodium borohydride (NaBH4) hydrolysis. Journal of Boron 10 2 68–84.
IEEE
[1]C. Kaya, “A review on reactor design parameters of sodium borohydride (NaBH4) hydrolysis”, Journal of Boron, vol. 10, no. 2, pp. 68–84, June 2025, doi: 10.30728/boron.1612416.
ISNAD
Kaya, Cenk. “A Review on Reactor Design Parameters of Sodium Borohydride (NaBH4) Hydrolysis”. Journal of Boron 10/2 (June 1, 2025): 68-84. https://doi.org/10.30728/boron.1612416.
JAMA
1.Kaya C. A review on reactor design parameters of sodium borohydride (NaBH4) hydrolysis. Journal of Boron. 2025;10:68–84.
MLA
Kaya, Cenk. “A Review on Reactor Design Parameters of Sodium Borohydride (NaBH4) Hydrolysis”. Journal of Boron, vol. 10, no. 2, June 2025, pp. 68-84, doi:10.30728/boron.1612416.
Vancouver
1.Cenk Kaya. A review on reactor design parameters of sodium borohydride (NaBH4) hydrolysis. Journal of Boron. 2025 Jun. 1;10(2):68-84. doi:10.30728/boron.1612416

Cited By