Synthesis and characterization of Multi-Functional Material MoBP3O12

Year 2017, Volume: 2 Issue: 2, 71 - 74, 25.09.2017

Gülşah Çelik Gül , Figen Kurtuluş , Halil Güler

Abstract

New
metal borophosphate compound MoBP₃O₁₂, as a potential
candidate of nonlinear optical material, was obtained by hydrothermal method.
The title compound was synthesized from the mixture of MoO₃, B₂O₃,
and (NH₄)₂HPO₄ with the molar ratio 1:0.5:3, by
heating at 200 °C for 3 days. The powder X-ray diffraction data was indexed in
tetragonal system with the refined unit cell parameters, a = b = 5.302 (8), c =
21.538 (4) Å and Z = 1. Stoichiometric chemical analysis of molybdenum was done
by inductively coupled plasma atomic emission spectroscopy (ICP-AES) and boron
content was analysed by spectrophotometric azomethine H method. The indexed powder X-ray diffraction (XRD)
data with POWD program, fourier transform infrared spectroscopy (FTIR) spectrum
and thermal analysis of MoBP₃O₁₂ are also given in the
paper.

Keywords

Borophosphate compounds, Hydrothermal synthesis, X-ray diffraction, Nonlinear optic materials, POWD program

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