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Surface modification of anhydrous borax powders with stearic acid via mechanical dry powder coating

Year 2019, Volume 4, Issue 1, 7 - 15, 16.03.2019
https://doi.org/10.30728/boron.414410

Abstract

Surface modification of anhydrous borax powders with stearic acid in the laboratory-scale planetary ball mill via mechanical dry powder coating approach was investigated. The alteration of hydrophilic surface properties of anhydrous borax with stearic acid was optimized by modifier amount and activation time. The cohesion mechanisms of powders, which processed at conditions of 0.5, 1 and 2 wt. % stearic acid amount with the function of 30, 60 and 120 minute activation time, were evaluated in terms of the solubility test, contact angle measurements, particle size distributions, and scanning electron microscopy (SEM) analysis. Results indicate that anhydrous borax surface could be switched from hydrophilic to hydrophobic with changing contact angle from wetting (17o) to non-wetting (99o). Water-insoluble amount of anhydrous borax powders, as a coating efficiency indicator, was increased from 73 % to 91 % by coating with 1 wt. % stearic acid for 60 min. Furthermore, SEM analysis results demonstrate that stearic acid was discretely coated over the anhydrous borax surface. As a conclusion, an effective mechanical dry coating processing by a one-step coating approach could be applied to obtain a modified anhydrous borax surface, which offers controlled solubility behaviour in water-based suspensions. 

References

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  • [21] Jeong S. B., Yang, Y. C., Chae Y.B., Kim B. G., Characteristics of the treated ground calcium carbonate powder with stearic acid using the dry process coating system, Mater. Trans., 50 (2), 409–414, 2009.
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  • [28] Kanimozhi D., Ratha Bai V., Analysis of bioactive components of ethanolic extract of coriandrum sativum L., IJRPS 2012, 2 (3),97-110, 2012.
  • [29] Jeong S. B., Yang Y. C., Chae Y. B., Kim B. G., Characteristics of the treated ground calcium carbonate powder with stearic acid using the dry process coating system, Mater. Trans., (50–2), 409 - 414, 2009.
  • [30] Liao J., Du G., Qiao X., Hao D., Surface modification of diatomite by stearic acid and its effects on reinforcing for natural rubber/styrene-butadiene rubber blend. J. Chin. Ceram Soc., (39), 641-645, 2011 . [31] Wang Y., Lee W. C., Characterization and treatment of calcium carbonate: A comparative study, Polym. Compos., (24), 119–131, 2003.
  • [32] Wang B. B., Feng J. T., Zhao Y. P., Yu T. X., Fabrication of novel superhydrophobic surfaces and water droplet bouncing behavior, J. Adhes. Sci. Technol., 24, 2693-2705, 2010.

Year 2019, Volume 4, Issue 1, 7 - 15, 16.03.2019
https://doi.org/10.30728/boron.414410

Abstract

References

  • [1] McMillian P. W., Glass-Ceramics, 2nd Edition, Academic Press, New York, 1979.
  • [2] Kingery W. D., Bowen H. K., Uhlmann, D. R., Introduction to Ceramics, John Wiley and Sons, New York, 1976.
  • [3] Hawthorne F. C., Burns P. C., Grice J. D., The crystal chemistry of boron. In Boron Mineralogy, Petrology and Geology (E. S. Grew and L. M. Anevitz, Eds.), Mineral Society American, MSA Reviews in Mineralogy, 33 (2), 41-116, 1996.
  • [4] Helvaci C. Borates, in Encyclopedia of Geology, (Selley R.C., Cocks, L.R.M and Plimer, I.R., eds.), Elsevier, (3), 510-522, 2005.
  • [5] Kirk-Othmer, Encyclopedia of Chemical Technology, Ch.4, 5th Edition, 241-294, 2004.
  • [6] Akpinar S., Yazici Z.O., Can M.F., Investigation of surface-modified anhydrous borax utilisation in raw glazes, Ceram. Int 44, 18344–18351, 2018.
  • [7] ECETOC Technical Report No. 63, Reproductive and General Toxicology of Some Inorganic Borates and Risks Assessment for Human Beings, European Centre for Ecotoxicology and Toxicology of Chemicals (ECETOC), Brussels, Belgium, 3, 1995.
  • [8] Kaplan J., Zamek J., A substitute for gerstley borate, Ceramics Technical, 32, 24-29, 2011.
  • [9] Otles M. S., Modification of surface properties of biopowders by dry particle coating, Ph.D. Thesis, Université de Toulouse, National Institute of Posts and Telecommunications, Rabat, 2008.
  • [10] Pfeffer R., Dave R. N., Dongguang W., Ramlakhan M., Synthesis of engineered particulates with tailored properties using dry particle coating, Powder Technol., 117, pp.40-67, 2001.
  • [11] Yoshihara I., Pieper W., Hybridization–technology for surface modification of powders without binders, Swiss Pharma 6, 21, 1999.
  • [12] Ouabbas Y., Chamayou A., Galet L., Baron M., Thomas G., Grosseau P., Guilhot B., Surface modification of silica particles by dry coating: Characterization and powder ageing, Powder Technol., 190a, 200-209, 2009.
  • [13] Lefebvre G., Galet L., Chamayou A., Dry coating of talc particles: Effect of material and process modifications on their wettability and dispersibility, AIChE Journal, 57 (1), 79-86, 2011.
  • [14] Sonoda R., Horibe M., Oshima T., Iwasaki T., Watano S., Improvement of dissolution property of poorly water-soluble drug by novel dry coating method using planetary ball mill, Chem. Pharm. Bull. 56 (9),1243-7, 2008.
  • [15] Tsai W. T., Microstructural characterization of calcite-based powder materials prepared by planetary ball milling, Materials, 6, 3361-3372, 2013.
  • [16] Suryanarayana C., Mechanical alloying and milling, Prog. Mater Sci., 46, 1–184, 2001.
  • [17] Baláž P., Mechanochemistry in Nanoscience and Minerals Engineering, Chapter 2, High Energy Milling, Springer, Hardcover, Netherland, 2008.
  • [18] Hersey J. A., Ordered mixing: A new concept in powder mixing practice, Powder Technology, 11 (1) 41-44, 1975.
  • [19] Dahmash J., Dry particle coating-a unique solution for pharmaceutical formulation, Pharmaceutical Technology, 42 (3) 26-30, 2018.
  • [20] Gilbert M., Petiraksakul P., Mathieson I., Characterization of stearate-stearic acid coated fillers, Mater. Sci. Technol., (17), 1472–1478, 2001.
  • [21] Jeong S. B., Yang, Y. C., Chae Y.B., Kim B. G., Characteristics of the treated ground calcium carbonate powder with stearic acid using the dry process coating system, Mater. Trans., 50 (2), 409–414, 2009.
  • [22] Mihajlovic S. R., Vucinic D. R., Sekulic Z. T., Milicevic S. Z., Kolonja B. M., Mechanism of stearic acid adsorption to calcite, Powder Technol., 245, 208–216, 2013.
  • [23] Gilbert M., Sutherland I., Guest A., Characterization of coated particulate fillers, J. Mater. Sci., 35, 391–397, 2000.
  • [24] Griffin M., The Structure and Biological Functions of Lipids, Bio Factsheets, 3, 2000.
  • [25] Markley K. S., Fatly Acids: Their chemistry and physical properties, Part 1, 2nd ed., Interscience Publishers Inc., New York. 1960. [26] Agernäs O., Tengberg T., Development of two methods to evaluate lubricating greases using a rheometer, B.Sc. Thesis in Chemical Engineering, Chalmers University of Technology, Göteborg, Sweden, 2011.
  • [27] Hashmi S., Effect of surface roughness on wetting properties, in Comprehensive Materials Finishing, 285, 2017.
  • [28] Kanimozhi D., Ratha Bai V., Analysis of bioactive components of ethanolic extract of coriandrum sativum L., IJRPS 2012, 2 (3),97-110, 2012.
  • [29] Jeong S. B., Yang Y. C., Chae Y. B., Kim B. G., Characteristics of the treated ground calcium carbonate powder with stearic acid using the dry process coating system, Mater. Trans., (50–2), 409 - 414, 2009.
  • [30] Liao J., Du G., Qiao X., Hao D., Surface modification of diatomite by stearic acid and its effects on reinforcing for natural rubber/styrene-butadiene rubber blend. J. Chin. Ceram Soc., (39), 641-645, 2011 . [31] Wang Y., Lee W. C., Characterization and treatment of calcium carbonate: A comparative study, Polym. Compos., (24), 119–131, 2003.
  • [32] Wang B. B., Feng J. T., Zhao Y. P., Yu T. X., Fabrication of novel superhydrophobic surfaces and water droplet bouncing behavior, J. Adhes. Sci. Technol., 24, 2693-2705, 2010.

Details

Primary Language English
Subjects Engineering
Journal Section Research Article
Authors

Süleyman AKPINAR> (Primary Author)
AFYON KOCATEPE ÜNİVERSİTESİ, MÜHENDİSLİK FAKÜLTESİ
Türkiye


Zeyni ARSOY>
AFYON KOCATEPE ÜNİVERSİTESİ, MÜHENDİSLİK FAKÜLTESİ
0000-0001-5694-6338
Türkiye


R. Sena ŞENOL This is me

Publication Date March 16, 2019
Published in Issue Year 2019, Volume 4, Issue 1

Cite

Bibtex @research article { boron414410, journal = {Journal of Boron}, issn = {2149-9020}, eissn = {2667-8438}, address = {}, publisher = {TENMAK Bor Araştırma Enstitüsü}, year = {2019}, volume = {4}, number = {1}, pages = {7 - 15}, doi = {10.30728/boron.414410}, title = {Surface modification of anhydrous borax powders with stearic acid via mechanical dry powder coating}, key = {cite}, author = {Akpınar, Süleyman and Arsoy, Zeyni and Şenol, R. Sena} }
APA Akpınar, S. , Arsoy, Z. & Şenol, R. S. (2019). Surface modification of anhydrous borax powders with stearic acid via mechanical dry powder coating . Journal of Boron , 4 (1) , 7-15 . DOI: 10.30728/boron.414410
MLA Akpınar, S. , Arsoy, Z. , Şenol, R. S. "Surface modification of anhydrous borax powders with stearic acid via mechanical dry powder coating" . Journal of Boron 4 (2019 ): 7-15 <https://dergipark.org.tr/en/pub/boron/issue/43938/414410>
Chicago Akpınar, S. , Arsoy, Z. , Şenol, R. S. "Surface modification of anhydrous borax powders with stearic acid via mechanical dry powder coating". Journal of Boron 4 (2019 ): 7-15
RIS TY - JOUR T1 - Surface modification of anhydrous borax powders with stearic acid via mechanical dry powder coating AU - SüleymanAkpınar, ZeyniArsoy, R. SenaŞenol Y1 - 2019 PY - 2019 N1 - doi: 10.30728/boron.414410 DO - 10.30728/boron.414410 T2 - Journal of Boron JF - Journal JO - JOR SP - 7 EP - 15 VL - 4 IS - 1 SN - 2149-9020-2667-8438 M3 - doi: 10.30728/boron.414410 UR - https://doi.org/10.30728/boron.414410 Y2 - 2019 ER -
EndNote %0 Journal of Boron Surface modification of anhydrous borax powders with stearic acid via mechanical dry powder coating %A Süleyman Akpınar , Zeyni Arsoy , R. Sena Şenol %T Surface modification of anhydrous borax powders with stearic acid via mechanical dry powder coating %D 2019 %J Journal of Boron %P 2149-9020-2667-8438 %V 4 %N 1 %R doi: 10.30728/boron.414410 %U 10.30728/boron.414410
ISNAD Akpınar, Süleyman , Arsoy, Zeyni , Şenol, R. Sena . "Surface modification of anhydrous borax powders with stearic acid via mechanical dry powder coating". Journal of Boron 4 / 1 (March 2019): 7-15 . https://doi.org/10.30728/boron.414410
AMA Akpınar S. , Arsoy Z. , Şenol R. S. Surface modification of anhydrous borax powders with stearic acid via mechanical dry powder coating. Journal of Boron. 2019; 4(1): 7-15.
Vancouver Akpınar S. , Arsoy Z. , Şenol R. S. Surface modification of anhydrous borax powders with stearic acid via mechanical dry powder coating. Journal of Boron. 2019; 4(1): 7-15.
IEEE S. Akpınar , Z. Arsoy and R. S. Şenol , "Surface modification of anhydrous borax powders with stearic acid via mechanical dry powder coating", Journal of Boron, vol. 4, no. 1, pp. 7-15, Mar. 2019, doi:10.30728/boron.414410

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