Kolemanit, tinkal, üleksit ve bor atığında atomik absorpsiyon spektroskopi yöntemi ile Fe, Ni, Co ve Zn eser elementlerinin tayini

Year 2020, Volume 5, Issue 4, 176 - 182, 29.12.2020

Argun TÜRKER Orhan ACAR

https://doi.org/10.30728/boron.756254

Abstract

Bu çalışmada, Türkiye’de en bol bulunan bazı bor minerallerinde (kolemanit, tinkal ve üleksit) ve bor atığında Cu, Fe, Ni, Co ve Zn eser elementleri alevli atomik absorpsiyon spektrometresi kullanılarak tayin edilmiştir. Bor minerallerinin çözülmesi için uygun çözücü belirlendikten sonra numuneler çözülmüş ve numune çözeltilerinde elementler tayin edilmiştir. Yöntemin geçerli kılınması amacıyla yöntemin doğruluğu ve kesinliği standart referans maddeler (NIST Montana soil 2711 ve NIST Estuarine sediment 1646a) analiz edilerek kontrol edilmiştir. Ayrıca yöntem için çalışılan her elemente ait doğrusal çalışma aralığı, gözlenebilme sınırı (LOD) ve tayin sınırı (LOQ) değerleri de belirlenmiştir.

Keywords

Kolemanit, Tinkal, Üleksit, Bor atığı, Eser elementler

Determination of Fe, Ni, Co and Zn trace elements in colemanite, tinkal, ulexite and boron waste by atomic absorption spectroscopy method

Abstract

In this study, Cu, Fe, Ni, Co and flame Zn trace elements were determined in boron minerals most abundant in Turkey (colemanite, tinkal and ulexite) and boron waste using atomic absorption spectrometry. After determining the suitable solvent for the dissolution of boron minerals, the samples were dissolved and the elements were determined in the sample solutions. In order to validate the method, the accuracy and precision of the method was checked by analyzing standard reference materials (NIST Montana soil 2711 and NIST Estuarine sediment 1646a). In addition,linear working range, limit of detection (LOD) and limit of quantification (LOQ) values for each element studied were determined for the method. The concentration ranges of the elements determined in boron minerals and boron waste are 111 μg/g and 

Keywords

Atomic absorption spectroscopy, Boron waste, Colemanite, Tinkal, Ulexite

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