Research Article

Effect of CaF2 Additions on the Yield of AZ63 Magnesium Chips during Remelting

Volume: 7 Number: 1 January 15, 2024
EN TR

Effect of CaF2 Additions on the Yield of AZ63 Magnesium Chips during Remelting

Abstract

Magnesium is one of the metals listed in European Union’s critical raw materials list. Primary production of magnesium is a high energy demanding process which raised the necessity of recycling the magnesium alloys in an efficient way. Remelting those scraps under a salt flux consist of chlorides (NaCl, KCl, and MgCl2) and fluorides (CaF2) are a common process however, different alloys might behave differently when it comes to salt-metal-metal oxide interactions. Furthermore, the condition of the salt flux such as dry-mixed or pre-melted (fused) affects the coagulation and metal yield. This work presents results on the effect of CaF2 concentration and pre-melting the salt flux on metal yield during remelting of chips. A yield up to 75% was observed in the case of remelting of chips under a fused salt flux with 5.5% CaF2 concentration.

Keywords

Project Number

118C311

References

  1. Akbari S, Friedrich B. 2010. Salt-Metal interaction in magnesium recycling. In Proceedings of International Workshop on Metal-Slag Interaction, September 14-19, Yalta, Crimea, Ukraine, pp: 71.
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  3. Çağlar Yüksel ÖT, Erzi E, Dışpınar D, Çiğdem M. 2017. Melt quality change with different fluxes in secondary A356 alloy. In Proceedings of European Congress and Exhibition on Advanced Materials and Processes, September 17-22, Athens, Greece, pp: 1-5.
  4. Demirci G. 2006. Electrolytic magnesium production using coaxial electrodes. PhD thesis, Middle East Technical University, The Graduate School of Natural And Applied Sciences, Ankara, Türkiye, pp: 170.
  5. Ding W, Gomez-Vidal J, Bonk A, Bauer T. 2019. Molten chloride salts for next generation CSP plants: Electrolytical salt purification for reducing corrosive impurity level. Solar Energy Mater Solar Cells, 199: 8-15.
  6. Entr D. 2014. Report on critical raw materials for the EU. European Commission, Brussels, Belgium, pp: 124.
  7. Filotás D, Fernández-Pérez B, Nagy L, Nagy G, Souto R. A novel scanning electrochemical microscopy strategy for the investigation of anomalous hydrogen evolution from AZ63 magnesium alloy. Sensors Actuat B: Chem, 308: 127691.
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Details

Primary Language

English

Subjects

Manufacturing Metallurgy

Journal Section

Research Article

Early Pub Date

December 11, 2023

Publication Date

January 15, 2024

Submission Date

September 8, 2023

Acceptance Date

November 7, 2023

Published in Issue

Year 2024 Volume: 7 Number: 1

APA
Yörük, P., & Gökelma, M. (2024). Effect of CaF2 Additions on the Yield of AZ63 Magnesium Chips during Remelting. Black Sea Journal of Engineering and Science, 7(1), 16-20. https://doi.org/10.34248/bsengineering.1356822
AMA
1.Yörük P, Gökelma M. Effect of CaF2 Additions on the Yield of AZ63 Magnesium Chips during Remelting. BSJ Eng. Sci. 2024;7(1):16-20. doi:10.34248/bsengineering.1356822
Chicago
Yörük, Pınar, and Mertol Gökelma. 2024. “Effect of CaF2 Additions on the Yield of AZ63 Magnesium Chips During Remelting”. Black Sea Journal of Engineering and Science 7 (1): 16-20. https://doi.org/10.34248/bsengineering.1356822.
EndNote
Yörük P, Gökelma M (January 1, 2024) Effect of CaF2 Additions on the Yield of AZ63 Magnesium Chips during Remelting. Black Sea Journal of Engineering and Science 7 1 16–20.
IEEE
[1]P. Yörük and M. Gökelma, “Effect of CaF2 Additions on the Yield of AZ63 Magnesium Chips during Remelting”, BSJ Eng. Sci., vol. 7, no. 1, pp. 16–20, Jan. 2024, doi: 10.34248/bsengineering.1356822.
ISNAD
Yörük, Pınar - Gökelma, Mertol. “Effect of CaF2 Additions on the Yield of AZ63 Magnesium Chips During Remelting”. Black Sea Journal of Engineering and Science 7/1 (January 1, 2024): 16-20. https://doi.org/10.34248/bsengineering.1356822.
JAMA
1.Yörük P, Gökelma M. Effect of CaF2 Additions on the Yield of AZ63 Magnesium Chips during Remelting. BSJ Eng. Sci. 2024;7:16–20.
MLA
Yörük, Pınar, and Mertol Gökelma. “Effect of CaF2 Additions on the Yield of AZ63 Magnesium Chips During Remelting”. Black Sea Journal of Engineering and Science, vol. 7, no. 1, Jan. 2024, pp. 16-20, doi:10.34248/bsengineering.1356822.
Vancouver
1.Pınar Yörük, Mertol Gökelma. Effect of CaF2 Additions on the Yield of AZ63 Magnesium Chips during Remelting. BSJ Eng. Sci. 2024 Jan. 1;7(1):16-20. doi:10.34248/bsengineering.1356822

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