Borofenin Si/SiO2 Substratına Kimyasal Buhar Biriktirme Yöntemiyle Direkt Olarak Sentezlenmesi ve Analizi

Year 2024, Volume: 7 Issue: 6, 1280 - 1286, 15.11.2024

Mehmet Bay

https://doi.org/10.34248/bsengineering.1548625

Abstract

Bu çalışmada, borofenin doğrudan Si/SiO2 alt taşı üzerine kimyasal buhar biriktirme metodu (KBB) ile sentezlenmesi ve analizine, ayrıca potansiyel uygulamalarına yer verilmiştir. Borofenin kalınlık kontrollü olarak homojen büyütülmesi, 2 boyutlu malzeme tabanlı yüksek performanslı cihaz üretiminde kritik öneme sahiptir. Borofen, Grafene benzer özelliklere sahip olup kristal yapısı, yüksek çekme gücü ve elektrik iletkenliği gibi özellikleri nedeniyle, sensör uygulamaları, foto detektörler, gaz sensörleri, 2 boyutlu enerji depolama uygulamaları gibi birçok alanda cazip bir malzeme haline gelmiştir. Sonuçlar, borofen tabanlı cihazların potansiyelinin yüksek olduğunu göstermektedir. Bu potansiyel, yüksek kristalli ve katmanlı iki boyutlu düzenleme gibi benzersiz yapısal özellikler nedeniyle elde edilmiştir. Metal alt taşlarında borofenin büyütülmesi, kolay bir şekilde sentezlenirken, yüksek kaliteli analiz imkânı ve performanslı cihazlar için kritik olan Si/SiO2 alt taşlarında büyütülmesi, katalizör etkisi azaldığı için daha zor olur. Bu zorluk, KBB parametreleri olan basınç, reaksiyon sıcaklığı, gaz akış oranı, kimyasal toz miktarları gibi birçok KBB parametresi optimize edilerek borofenin Si/SiO2 alt taşı üzerine başarılı şekilde büyütülmesiyle aşılmıştır.

Keywords

Borofen, KBB, Si/SiO2

Project Number

TÜBİTAK 20AG025, TÜBİTAK 20AG001, TÜBİTAK 124E061, ESTÜ 21GAP078

Analysis and Direct Synthesis of Borophene on Sİ/SiO2 Substrate Using CVD Method

Abstract

This study presents the synthesis and analysis of borophene by chemical vapor deposition (CVD) on Si/SiO2 substrate, as well as its potential applications. The controlled growth of borophene with homogeneous thickness is crucial for the production of high-performance devices based on two-dimensional materials. Borophene, with its graphene-like properties, including crystalline structure, high tensile strength, and electrical conductivity, is a promising material for various applications, such as sensors, photodetectors, gas sensors, and 2D energy storage devices. The results demonstrate the potential of borophene for the development of essential devices. This potential is attributed to its unique structural features, including high crystallinity and layered two-dimensional arrangement. While borophene can be easily synthesized on metal substrates, its growth on Si/SiO2 substrate is more challenging due to the reduced catalyst effect. However, this challenge was overcome by optimizing the CVD parameters, including pressure, reaction temperature, gas flow rate, and chemical powder concentration, resulting in successful growth of borophene on Si/SiO2 substrate.

Keywords

Borophene, CVD, Si/SiO2

Project Number

TÜBİTAK 20AG025, TÜBİTAK 20AG001, TÜBİTAK 124E061, ESTÜ 21GAP078

References

• Alemán-Vázquez L, Torres-García E, Villagómez R, Cano J-L. 2005. Effect of the particle size on the activity of MoO x C y catalysts for the isomerization of heptane. Catalysıs Lett, 100: 219-226.
• Bay M, Özden A, Ay F, Perkgöz NK. 2019. Bandgap tuning of Monolayer MoS 2(1-x) Se 2x alloys by optimizing parameters. Mater Sci Semicond Process, 99: 134 – 139.
• Chen J, Zhao X, Tan SJR, Xu H, Wu B, Liu B, Fu D, Fu W, Geng D, Liu Y, Liu W, Tang W, Li L, Zhou W, Sum TC, Loh KP 2017. Chemical vapor deposition of large-size monolayer MoSe2 crystals on molten glass. J American Chem Soc, 139: 1073-1076.
• Childres I, Jauregui L, Park W, Caoa H, Chena YP. 2013. Raman spectroscopy of graphene and related materials. New Develop Photon Mater Res, 2013: 403-418.
• Chinnalagu DK, Murugesan B, Arumugam M, Chinniah K, Ganesan S, Cai Y, Mahalingam S. 2023. Fabrication of 2D-Borophene nanosheets anchored S, N-mesoporous carbon nanocomposite (SNC-Bp//SNC-Bp) symmetric device for high-performance supercapacitor application. J Energy Stor, 74: 109328-109336.
• Geim A, Novoselov KS. 2007. The rise of graphene. Nature Mat, 6: 183-191.
• Hou C, Tai G, Wu Z, Hao J. 2020. Borophene: current status, challenges and opportunities. Chem Plus Chem, 85: 2186-2196.
• Hubenthal F. 2011. Noble Metal Nanoparticles: Synthesis and Optical Properties. In: Andrews DL, Scholes GD, Wiederrecht GP, eds. Comprehensive Nanoscience and Technology. Academic Press, Amsterdam, Nederland, pp: 375-435.
• Kobayashi T, Hirajima T, Hiroi Y, Svojtka M. 2008. Determination of SiO2 Raman spectrum indicating the transformation from coesite to quartz in Gföhl migmatitic gneisses in the Moldanubian Zone, Czech Republic. J Miner Petrol SCI, 103: 105-111.
• Novoselov KS, Geim AK, Morozov SV, Jiang D, Katsnelson MI, Grigorieva IV, Dubonos SV, Firsov AA. 2005a. Two-dimensional gas of massless Dirac fermions in graphene. Nature, 438: 197-200.
• Novoselov KS, Jiang D, Schedin F, Booth TJ, Khotkevich VV, Morozov SV, Geim AK. 2005b. Two-dimensional atomic crystals. Proc Natl Acad Sci, 102: 10451 -10453.
• Rahman A, Rahman MT, Chowdhury MA, Bin Ekram S, Uddin MMK, Islam MR, Dong L. 2023. Emerging 2D borophene: Synthesis, characterization, and sensing applications. Sens Actuators A Phys, 359: 114468-114475.
• Sahoo BB, Pandey VS, Dogonchi AS, Thatoi DN, Nayak N, Nayak MK. 2023. Exploring the potential of borophene-based materials for improving energy storage in supercapacitors. Inorg Chem Commun, 154: 110919-110925.
• Somesh TE, Tran DT, Jena S, Bai Y, Prabhakaran S, Kim DH, Kim NH, Lee JH. 2024. Flexible 2D borophene-stacked MXene heterostructure for high-performance supercapacitors. J Chem Eng, 481: 148266-148273.
• Tian Y, Yang H, Li J, Hu S, Cao S, Ren W, Wang Y. 2021. A comprehensive first-principle study of borophene-based nano gas sensor with gold electrodes. Front Phys, 17: 13501-13509.
• Xie Z, Meng X, Li X, Liang W, Huang W, Chen K, Chen J, Xing C, Qiu M, Zhang B, Nie G, Xie N, Yan X. 2020. Two-dimensional borophene: properties, fabrication, and promising applications. Research, 2020: 1-23.
• Yu J, Zhou M, Yang M, Zhang Y, Xu B, Li X, Tao H. 2022. Pristine and defective 2D borophene/graphene heterostructure as the potential anode of lithium‐ion batteries. Adv Mater Interfaces, 9: 2102088-2102095.
• Zha X, Xu P, Huang Q, Du S, Zhang R. 2019. Mo 2 B, a MBene member with high electrical and thermal conductivities, and satisfactory performances in lithium ion batteries. Nanoscale Adv, 2:347-355.