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Production of Pure PVC, Graphene and Carbon Nanotube-Doped PVC Electrospun Nanofiber Membranes: A Highly Effective Method for Removing Acid Blue 74 Dye from Wastewater

Year 2025, Volume: 8 Issue: 2, 517 - 523, 15.03.2025
https://doi.org/10.34248/bsengineering.1634974

Abstract

Dyeing wastewater is produced by various industries, including textiles, cosmetics, tanning, and plastics. Annually, about 1.6 million tons of dyes are manufactured, with 10-15% released into the environment as wastewater. Organic dyes are particularly harmful pollutants, even at low concentrations. The adsorption technique has proven effective for removing these pollutants from water, significantly relying on the properties and efficiency of the adsorbent. Nanofibers are emerging as promising adsorbents for dye removal due to their unique properties and high efficiency. This research focuses on polymeric nanofibers to address global dye pollution, as they effectively eliminate various dyes and contaminants. However, their mechanical properties can be a limitation under harsh conditions. To enhance their strength and hydrophilicity, incorporating nanofillers like carbon nanotubes and graphene oxide has shown significant benefits. This study examines the impact of different nanofibers on the adsorption of Acid Blue 74 (AB74) dye. Pure, carbon nanotube-doped, and graphene-doped PVC nanofibers were produced via electrospinning. Their properties were analyzed using FTIR and SEM, while key parameters such as contact time, adsorbent dosage, dye concentration, and pH were assessed to understand the adsorption behavior. Additionally, dye adsorption isotherms and kinetics were investigated.

References

  • Ahmed FE, Lalia BS. 2015. A review on electrospinning for membrane fabrication: Challenges and applications. Desalination, 356: 15-30.
  • Ahmed MA, Brick AA, Mohamed AA. 2017. An efficient adsorption of indigo carmine dye from aqueous solution on mesoporous Mg/Fe layered double hydroxide nanoparticles prepared by controlled sol-gel route. Chemosphere, 174: 280-288.
  • Altıntaş F, Delimanlar M, Kolcu E, Olgaç BM. 2023. Filtration with Nanofibers. Res J Biomedic Biotechnol, 4(1): 1-11.
  • Attia AA, Rashwan WE, Khedr SA. 2006. Capacity of activated carbon in the removal of acid dyes subsequent to its thermal treatment. Dyes Pigment, 69: 128-136.
  • Ayodhya D, Veerabhadram G. 2018. A review on recent advances in photodegradation of dyes using doped and heterojunction-based semiconductor metal sulfide nanostructures for environmental protection. Mater Today Ener, 9: 83-113.
  • Bozbeyoglu P, Gündoğdu A. 2023. Adsorption of hexavalent chromium from aqueous solution onto corn cobs – activated carbon. Turkish J Analyt Chem, 5(2): 107-117.
  • Briesemeister M, Gómez-Sánchez JA, Bertemes-Filho P, Pezzin SH. 2024. PVC/CNT electrospun composites: morphology, thermal and impedance spectra. Polymers, 16(20): 2867. Fadlalla MI, Kumar PS, Selvam V, Babu SG. 2020. Emerging energy and environmental application of graphene and their composites: a review. J Mater Sci, 55: 7156-7183.
  • Ghanavati L, Hekmati AH, Rashidi A, Shafiekhani A. 2021. Application of electrospun polyamide-6/modified zeolite nanofibrous composite to remove Acid Blue 74 from textile dyeing wastewater. J Textil Inst, 112: 1730-1742.
  • Gundogdu A, Bozbeyoglu, P, Imamoglu M, Baltaci C, Duran C, Bulut VN. 2022. Characterization of the adsorption mechanism of cadmium(II) and methylene blue upon corncobs activated carbon. Analyt Lett, 56(3): 433-448.
  • Kaczyk A, Mitrowska K, Posyniak A. 2020. Synthetic organic dyes as pollutants of the aquatic environment and their effects for ecosystems: A review. Sci Total Environ, 717: 137222.
  • Kurniawan TA, Chan GYS, Lo WH, Babel S. 2006. Physico-chemical treatment techniques for wastewater laden with heavy metals. Chem Eng J, 118: 83-98.
  • Li M, Wang H, Wu S, li F, Zhi P. 2012. Adsorption of hazardous dyes indigo carmine and acid red on nanofiber membranes. RSC Adv, 2: 900-907.
  • Mo JH, Lee YH, Kim J, Jeong JY, Jegal J. 2008. Treatment of dye aqueous solutions using nanofiltration polyamide composite membranes for reuse of dye wastewater. Paint Pigment, 76: 429-434.
  • Ozkan V, Yapici A, Karaaslan M, Akgol O. 2019. Investigation of electromagnetic properties of glass-fiber reinforced epoxy composites containing PAN nanofibers with MWCNT/Graphene additive. Fresenius Environ Bull, 28(3): 2238-2246.
  • Ozkan V. 2019. Production and characterization of nanocomposite materials by adding nanoparticles to petroleum-derived polymers. PhD Thesis, Iskenderun Technical University, Institute of Engineering and Science, Hatay, Turkiye, pp: 200.
  • Ray SS, Chen SS, Li CW, Nguyen NC, Nguyen, HT. 2016. A comprehensive review: Electrospinning technique for fabrication and surface modification of membranes for water purification applications. RSC Adv, 6: 85495-85514.
  • Rehorek A, Tauber M, Gübitz G. 2004. Application of power ultrasound for azo dye degradation. Ultrason Sonochem, 11: 177-182.
  • Wang W, Fan Z, Zhu Q, Li M, Liu K, Yan K, Wang D. 2019a. Efficient adsorption properties of dyes from aqueous solution by poly(vinyl alcohol-co-ethylene) nanofiber membranes modified with β-cyclodextrin. Color Technol, 135: 244-249.
  • Wang Q, Ju J, Tan Y, Hao L, Ma Y, Wu Y, Zhang H, Xia Y, Sui K. 2019b. Controlled synthesis of sodium alginate electrospun nanofiber membranes for multioccasion adsorption and separation of methylene blue. Carbohydr Polym, 205: 125-134.
  • Wang SX, Yap CC, He J, Chen C, Wong SY, Li X. 2016. Electrospinning: A facile technique to produce functional nanofibers for environmental applications. Nanotechnol Rev, 5: 51-73.
  • Wang X, Dong J, Gong C, Zhang S, Yang J, Zhang A, Feng Z. 2022. Bendable poly(vinylidene fluoride)/ polydopamine/β-cyclodextrin composite electrospun membranes for highly efficient and bidirectional adsorption of cation and anion dyes from aqueous media. Compos Sci Technol, 219: 109256.
  • Wang X, Fu Q, Wang X, Si Y, Yu J, Wang X, Ding B. 2015. In situ cross-linked and highly carboxylated poly(vinyl alcohol) nanofibrous membranes for efficient adsorption of proteins. J Mater Chem B, 3: 7281-7290.
  • Wang Y, Zhu J, Dong G, Zhang Y, Guo N, Liu J. 2015. Ulfonated halloysite nanotubes/polyethersulfone nanocomposite membrane for efficient dye purification. Sep Purif Technol, 150: 243-251.
  • Xue J, Wu T, Dai Y, Xia Y. 2019. Electrospinning and electrospinning nanofibers: Methods, materials and applications. Chem Rev, 119: 5298-5415.
  • Yagub MT, Sen TK, Afroze S. 2014. Ang, HM Dye and its removal from aqueous solution by adsorption: A review. Adv Colloid Interf Sci, 209: 172-184.
  • Zakaria AF, Kamaruzaman S, Abdul Rahman N. 2021. Electrospun polyacrylonitrile/lignin/poly(ethylene glycol)-based porous activated carbon nanofiber for removal of nickel(II) ion from aqueous solution. Polymers, 13: 3590.

Production of Pure PVC, Graphene and Carbon Nanotube-Doped PVC Electrospun Nanofiber Membranes: A Highly Effective Method for Removing Acid Blue 74 Dye from Wastewater

Year 2025, Volume: 8 Issue: 2, 517 - 523, 15.03.2025
https://doi.org/10.34248/bsengineering.1634974

Abstract

Dyeing wastewater is produced by various industries, including textiles, cosmetics, tanning, and plastics. Annually, about 1.6 million tons of dyes are manufactured, with 10-15% released into the environment as wastewater. Organic dyes are particularly harmful pollutants, even at low concentrations. The adsorption technique has proven effective for removing these pollutants from water, significantly relying on the properties and efficiency of the adsorbent. Nanofibers are emerging as promising adsorbents for dye removal due to their unique properties and high efficiency. This research focuses on polymeric nanofibers to address global dye pollution, as they effectively eliminate various dyes and contaminants. However, their mechanical properties can be a limitation under harsh conditions. To enhance their strength and hydrophilicity, incorporating nanofillers like carbon nanotubes and graphene oxide has shown significant benefits. This study examines the impact of different nanofibers on the adsorption of Acid Blue 74 (AB74) dye. Pure, carbon nanotube-doped, and graphene-doped PVC nanofibers were produced via electrospinning. Their properties were analyzed using FTIR and SEM, while key parameters such as contact time, adsorbent dosage, dye concentration, and pH were assessed to understand the adsorption behavior. Additionally, dye adsorption isotherms and kinetics were investigated.

References

  • Ahmed FE, Lalia BS. 2015. A review on electrospinning for membrane fabrication: Challenges and applications. Desalination, 356: 15-30.
  • Ahmed MA, Brick AA, Mohamed AA. 2017. An efficient adsorption of indigo carmine dye from aqueous solution on mesoporous Mg/Fe layered double hydroxide nanoparticles prepared by controlled sol-gel route. Chemosphere, 174: 280-288.
  • Altıntaş F, Delimanlar M, Kolcu E, Olgaç BM. 2023. Filtration with Nanofibers. Res J Biomedic Biotechnol, 4(1): 1-11.
  • Attia AA, Rashwan WE, Khedr SA. 2006. Capacity of activated carbon in the removal of acid dyes subsequent to its thermal treatment. Dyes Pigment, 69: 128-136.
  • Ayodhya D, Veerabhadram G. 2018. A review on recent advances in photodegradation of dyes using doped and heterojunction-based semiconductor metal sulfide nanostructures for environmental protection. Mater Today Ener, 9: 83-113.
  • Bozbeyoglu P, Gündoğdu A. 2023. Adsorption of hexavalent chromium from aqueous solution onto corn cobs – activated carbon. Turkish J Analyt Chem, 5(2): 107-117.
  • Briesemeister M, Gómez-Sánchez JA, Bertemes-Filho P, Pezzin SH. 2024. PVC/CNT electrospun composites: morphology, thermal and impedance spectra. Polymers, 16(20): 2867. Fadlalla MI, Kumar PS, Selvam V, Babu SG. 2020. Emerging energy and environmental application of graphene and their composites: a review. J Mater Sci, 55: 7156-7183.
  • Ghanavati L, Hekmati AH, Rashidi A, Shafiekhani A. 2021. Application of electrospun polyamide-6/modified zeolite nanofibrous composite to remove Acid Blue 74 from textile dyeing wastewater. J Textil Inst, 112: 1730-1742.
  • Gundogdu A, Bozbeyoglu, P, Imamoglu M, Baltaci C, Duran C, Bulut VN. 2022. Characterization of the adsorption mechanism of cadmium(II) and methylene blue upon corncobs activated carbon. Analyt Lett, 56(3): 433-448.
  • Kaczyk A, Mitrowska K, Posyniak A. 2020. Synthetic organic dyes as pollutants of the aquatic environment and their effects for ecosystems: A review. Sci Total Environ, 717: 137222.
  • Kurniawan TA, Chan GYS, Lo WH, Babel S. 2006. Physico-chemical treatment techniques for wastewater laden with heavy metals. Chem Eng J, 118: 83-98.
  • Li M, Wang H, Wu S, li F, Zhi P. 2012. Adsorption of hazardous dyes indigo carmine and acid red on nanofiber membranes. RSC Adv, 2: 900-907.
  • Mo JH, Lee YH, Kim J, Jeong JY, Jegal J. 2008. Treatment of dye aqueous solutions using nanofiltration polyamide composite membranes for reuse of dye wastewater. Paint Pigment, 76: 429-434.
  • Ozkan V, Yapici A, Karaaslan M, Akgol O. 2019. Investigation of electromagnetic properties of glass-fiber reinforced epoxy composites containing PAN nanofibers with MWCNT/Graphene additive. Fresenius Environ Bull, 28(3): 2238-2246.
  • Ozkan V. 2019. Production and characterization of nanocomposite materials by adding nanoparticles to petroleum-derived polymers. PhD Thesis, Iskenderun Technical University, Institute of Engineering and Science, Hatay, Turkiye, pp: 200.
  • Ray SS, Chen SS, Li CW, Nguyen NC, Nguyen, HT. 2016. A comprehensive review: Electrospinning technique for fabrication and surface modification of membranes for water purification applications. RSC Adv, 6: 85495-85514.
  • Rehorek A, Tauber M, Gübitz G. 2004. Application of power ultrasound for azo dye degradation. Ultrason Sonochem, 11: 177-182.
  • Wang W, Fan Z, Zhu Q, Li M, Liu K, Yan K, Wang D. 2019a. Efficient adsorption properties of dyes from aqueous solution by poly(vinyl alcohol-co-ethylene) nanofiber membranes modified with β-cyclodextrin. Color Technol, 135: 244-249.
  • Wang Q, Ju J, Tan Y, Hao L, Ma Y, Wu Y, Zhang H, Xia Y, Sui K. 2019b. Controlled synthesis of sodium alginate electrospun nanofiber membranes for multioccasion adsorption and separation of methylene blue. Carbohydr Polym, 205: 125-134.
  • Wang SX, Yap CC, He J, Chen C, Wong SY, Li X. 2016. Electrospinning: A facile technique to produce functional nanofibers for environmental applications. Nanotechnol Rev, 5: 51-73.
  • Wang X, Dong J, Gong C, Zhang S, Yang J, Zhang A, Feng Z. 2022. Bendable poly(vinylidene fluoride)/ polydopamine/β-cyclodextrin composite electrospun membranes for highly efficient and bidirectional adsorption of cation and anion dyes from aqueous media. Compos Sci Technol, 219: 109256.
  • Wang X, Fu Q, Wang X, Si Y, Yu J, Wang X, Ding B. 2015. In situ cross-linked and highly carboxylated poly(vinyl alcohol) nanofibrous membranes for efficient adsorption of proteins. J Mater Chem B, 3: 7281-7290.
  • Wang Y, Zhu J, Dong G, Zhang Y, Guo N, Liu J. 2015. Ulfonated halloysite nanotubes/polyethersulfone nanocomposite membrane for efficient dye purification. Sep Purif Technol, 150: 243-251.
  • Xue J, Wu T, Dai Y, Xia Y. 2019. Electrospinning and electrospinning nanofibers: Methods, materials and applications. Chem Rev, 119: 5298-5415.
  • Yagub MT, Sen TK, Afroze S. 2014. Ang, HM Dye and its removal from aqueous solution by adsorption: A review. Adv Colloid Interf Sci, 209: 172-184.
  • Zakaria AF, Kamaruzaman S, Abdul Rahman N. 2021. Electrospun polyacrylonitrile/lignin/poly(ethylene glycol)-based porous activated carbon nanofiber for removal of nickel(II) ion from aqueous solution. Polymers, 13: 3590.
There are 26 citations in total.

Details

Primary Language English
Subjects Nanomaterials
Journal Section Research Articles
Authors

Vildan Özkan 0000-0001-8719-9099

Pınar Bozbeyoğlu 0000-0002-3704-2701

Publication Date March 15, 2025
Submission Date February 7, 2025
Acceptance Date March 4, 2025
Published in Issue Year 2025 Volume: 8 Issue: 2

Cite

APA Özkan, V., & Bozbeyoğlu, P. (2025). Production of Pure PVC, Graphene and Carbon Nanotube-Doped PVC Electrospun Nanofiber Membranes: A Highly Effective Method for Removing Acid Blue 74 Dye from Wastewater. Black Sea Journal of Engineering and Science, 8(2), 517-523. https://doi.org/10.34248/bsengineering.1634974
AMA Özkan V, Bozbeyoğlu P. Production of Pure PVC, Graphene and Carbon Nanotube-Doped PVC Electrospun Nanofiber Membranes: A Highly Effective Method for Removing Acid Blue 74 Dye from Wastewater. BSJ Eng. Sci. March 2025;8(2):517-523. doi:10.34248/bsengineering.1634974
Chicago Özkan, Vildan, and Pınar Bozbeyoğlu. “Production of Pure PVC, Graphene and Carbon Nanotube-Doped PVC Electrospun Nanofiber Membranes: A Highly Effective Method for Removing Acid Blue 74 Dye from Wastewater”. Black Sea Journal of Engineering and Science 8, no. 2 (March 2025): 517-23. https://doi.org/10.34248/bsengineering.1634974.
EndNote Özkan V, Bozbeyoğlu P (March 1, 2025) Production of Pure PVC, Graphene and Carbon Nanotube-Doped PVC Electrospun Nanofiber Membranes: A Highly Effective Method for Removing Acid Blue 74 Dye from Wastewater. Black Sea Journal of Engineering and Science 8 2 517–523.
IEEE V. Özkan and P. Bozbeyoğlu, “Production of Pure PVC, Graphene and Carbon Nanotube-Doped PVC Electrospun Nanofiber Membranes: A Highly Effective Method for Removing Acid Blue 74 Dye from Wastewater”, BSJ Eng. Sci., vol. 8, no. 2, pp. 517–523, 2025, doi: 10.34248/bsengineering.1634974.
ISNAD Özkan, Vildan - Bozbeyoğlu, Pınar. “Production of Pure PVC, Graphene and Carbon Nanotube-Doped PVC Electrospun Nanofiber Membranes: A Highly Effective Method for Removing Acid Blue 74 Dye from Wastewater”. Black Sea Journal of Engineering and Science 8/2 (March 2025), 517-523. https://doi.org/10.34248/bsengineering.1634974.
JAMA Özkan V, Bozbeyoğlu P. Production of Pure PVC, Graphene and Carbon Nanotube-Doped PVC Electrospun Nanofiber Membranes: A Highly Effective Method for Removing Acid Blue 74 Dye from Wastewater. BSJ Eng. Sci. 2025;8:517–523.
MLA Özkan, Vildan and Pınar Bozbeyoğlu. “Production of Pure PVC, Graphene and Carbon Nanotube-Doped PVC Electrospun Nanofiber Membranes: A Highly Effective Method for Removing Acid Blue 74 Dye from Wastewater”. Black Sea Journal of Engineering and Science, vol. 8, no. 2, 2025, pp. 517-23, doi:10.34248/bsengineering.1634974.
Vancouver Özkan V, Bozbeyoğlu P. Production of Pure PVC, Graphene and Carbon Nanotube-Doped PVC Electrospun Nanofiber Membranes: A Highly Effective Method for Removing Acid Blue 74 Dye from Wastewater. BSJ Eng. Sci. 2025;8(2):517-23.

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