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HALLOYSITE INTERCALATION OF NORTHWEST ANATOLIA

Year 2015, Volume: 150 Issue: 150, 121 - 130, 30.06.2015
https://doi.org/10.19111/bmre.44287

Abstract

In this study, the representative samples were taken from the halloysite deposits located in Çanakkale-Balıkesir regions, in NW Anatolia. At first, the dehydration temperatures of the samples were determined after sample preparation and characterization studies. It was found that halloysite samples began to lose their interlayer waters at 50°C and continued up to 70°C. The intercalation studies were carried out on dehydrated samples by using ethylene glycol, potassium acetate, dimethyl sulfoxide and formamide. Although there were negative results by ethylene glycol and potassium acetate, the satisfactory results were obtained by dimethyl sulfoxide and formamide. It was understood that the most effective reagent in terms of intercalation was formamide.

References

  • Akçay, A.E., Dönmez, M., Ilgar, A., Duru, M., Pehlivan, Ş. 2008. 1:100.000 ölçekli Türkiye jeoloji haritaları, Bandırma H 19 paftası No 103, Maden Tetkik ve Arama Genel Müdürlüğü, 26p. Ankara.
  • Anthony, J.W., Bideaux, R.A., Bladh, K.W., Nichols, M.C., 1995. Handbook of Mineralogy, Vol. II. Silica, Silicates, Mineral Data Publishing, Tucson, Arizona. (http://www.handbookofmineralogy.org/ pdfs/halloysite.pdf)
  • Başara, B., Saklar, S., Ağrılı, H., Kibar, U., 2013., Türkiye Halloysit Ve Kaolenlerinin Mineralojik Tanımlanmasında İnterkalasyon Yönteminin Araştırılması proje sonuç raporu, Maden Tetkik Arama Genel Müdürlüğü, Rapor No: 11705. Ankara, (unpublished).
  • Christie, A. B., Douch, C. J., Winfeld, B. J., Thompson, B. N., 2000, New Zealand’s industrial mineral potential, Industrial Minerals, July, 66p.
  • Christie, T., Thompson, B., Brathwaite, B., 2011, Mineral Commodity Report 20- Clays, http://www.nzpam. govt.nz/cms/pdf-library/minerals/publications
  • Churchman, G.J. 1990. Relevance of different intercalation tests for distinguishing halloysite from kaolinite in soils. Clays and Clay Minerals, 38, 591–599.
  • Churchman, G. J., Aldridge, L. P., Carr, R. M. 1972. The relationship between the hydrated and dehydrated states of an halloysite. Clays and Clay Minerals, 20, 241-246.
  • Churchman, G. J., Carr, R. M. 1973. Dehydration of the washed potassium acetate complex of halloysite. Clays and Clay Minerals, 21, 423-424.
  • Churchman, G. J., Theng, B. K. G. 1984. Interactions of halloysites with amides: mineralogical factors affecting complex formation. Clay Minerals, 19, 161-175.
  • Churchman, G. J., Whitton, J. S., Claridge, G. G. C., Theng, B. K. G. 1984. Intercalation method using formamide for differentiating halloysite from kaolinite. Clays and Clay Minerals, 32, 241–248.
  • Dönmez, M., Akçay, A.E., Duru, M., Ilgar, A., Pehlivan, Ş. 2008. 1:100.000 ölçekli Türkiye jeoloji haritaları, Çanakkale H 17 paftası No 101, Maden Tetkik ve Arama Genel Müdürlüğü, 27 p. Ankara.
  • Duru, M., Pehlivan, S., Dönmez, M., Ilgar, A., Akcay, A.E. 2007. 1:100.000 ölçekli Türkiye jeoloji haritaları, Bandırma H 18 paftası No 102, Maden Tetkik ve Arama Genel Müdürlüğü, 50 p. Ankara.
  • Duru, M., Pehlivan, Ş., Okay, A.İ., Şentürk, Y., Kar, H.,2012. Biga Yarımadası’nın Tersiyer Öncesi Jeolojisi, s.7-74, Biga Yarımadası’nın Genel ve Ekonomik Jeolojisi, Editörler: Erdoğan Yüzer, Gürkan Tunay, Maden Tetkik ve Arama Genel Müdürlüğü Özel Yayın Serisi, No: 28, Ankara.
  • Ece, Ö. İ., Schroeder, P. A. 2007. Clay mineralogy and chemistry of halloysite and alunite deposits in the Turplu area-Balıkesir-Turkey. Clays and Clay Minerals, 55, 1, 18-35.
  • Erdoğan, M., Gençoğlu, H., Mahmutoğlu, Y., 2012. Biga Yarımadası’nın Endüstriyel Hammadde Olanakları, s.273-289, Biga Yarımadası’nın Genel ve Ekonomik Jeolojisi, Editörler: Erdoğan Yüzer, Gürkan Tunay, Maden Tetkik ve Arama Genel Müdürlüğü Özel Yayın Serisi, No: 28, Ankara
  • Harrison, J.L., Greenberg, S.S., 1962. Dehydration of fully hydrated halloysite from Lawrence County, Indiana., 9th National Conference on Clays and Clay Minerals 374-377.
  • Hillier, S., Ryan, P.C. 2002. Identification of halloysite (7 Å) by ethylene glycol solvation: the ‘MacEwan effect’. Clay Minerals 37, 487–496.
  • Horvath, E., Kristof, J., Kurdi, R., Mako, E., Khunova, V. 2011. Study of urea intercalation into halloysite by thermoanalytical and spectroscopic techniques. Journal of Thermal Analysis and Calorimetry 105, 53–59.
  • Ilgar, A., Demirci, E.S., Demirci, Ö., 2012. Biga Yarımadası Tersiyer İstifinin Stratigrafisi ve Sedimantolojisi, s.75-122, Biga Yarımadası’nın Genel ve Ekonomik Jeolojisi, Editörler: Erdoğan Yüzer, Gürkan Tunay, Maden Tetkik ve Arama Genel Müdürlüğü Özel Yayın Serisi No: 28, Ankara
  • Joussein, E., Petit, S., Churchman, G. J, Theng, B. K. G., Righi, D., Delvaux, B. 2005. Halloysite clay minerals-a review. Clay Minerals, 40, 383–426.
  • Joussein, E., Petit, S., Fialips, C.I., Vieillard, P., Righi, D., 2006. Difference in the dehydration–rehydration behavior of halloysites: new evidence and interpretations. Clays and Clay Minerals 54, 473– 485.
  • Joussein, E., Petit, S., Delvaux, B. 2007. Behavior of halloysite clay under formamide treatment. Applied Clay Science 35, 17–24.
  • Kirkman, J.H.,1981. Morphology and structure of halloysite in New Zeland tephras, Clays and Clay Minerals 29 (1), 1-9.
  • Lacin, D., Yeniyol, M. 2006. An example to the halloysite deposits formed associated with the andesitic pyroclastics: Soğucak halloysite deposit (Yenice- Çanakkale). Istanbul Üniv. Yerbilimleri Dergisi 19, 1, 27-41.
  • Mellouk, S., Cherifi, S., Sassi, M., Marouf-Khelifa, K., Bengueddach, A., Schott, J. and Khelifa, A. 2009. Intercalation of halloysite from Djebel Debagh (Algeria), adsorption of copper ions. Applied Clay Science, 44, 230–236.
  • Murray, H. H. 2007. Applied Clay Mineralogy- Developments in Clay Science 2. Elsevier, 180p.
  • Nicolini, K. P., Fukamachi, C. R. B., Wypych, F., Mangrich, A. S. 2009. Dehydrated halloysite intercalated mechanochemically with urea: Thermal behavior and structural aspects. Journal of Colloid and Interface Science 338, 474–479.
  • Saklar, S., Ağrılı, H., Zimitoğlu, O., Başara, B., Bayrakdar, H., 2011. Türkiye halloysit kaynaklarının değerlendirme olanaklarının araştırılması proje sonuç raporu, Maden Tetkik Arama Genel Müdürlüğü Rapor No: 11467, 122 p. Ankara, (unpublished)
  • Saklar, S., Ağrılı, H., Zimitoğlu, O., Başara, B., Kaan, U. 2012. Kuzeybatı Anadolu halloysit/kaolinitlerinin karakterizasyon çalışmaları, Maden Tetkik Arama Genel Müdürlüğü Dergisi 145, 48-61.
  • Uygun, A. 1999. KB - Anadoluda karbonat kayaları içine yerleşmiş bazı halloysit yataklarının jeolojisi ve oluşumu. Maden Tetkik Arama Genel Müdürlüğü Dergisi 121, 141-151.
  • Wada, K. 1961. Lattice expansion of kaolin minerals by treatment with potassium acetate. American Mineralogist 46, 78-91.
  • Wills, B.A., Napier-Munn, T.J., 2006. Wills Mineral Processing Technology, 7th Edition, Elsevier, Amsterdam.
Year 2015, Volume: 150 Issue: 150, 121 - 130, 30.06.2015
https://doi.org/10.19111/bmre.44287

Abstract


References

  • Akçay, A.E., Dönmez, M., Ilgar, A., Duru, M., Pehlivan, Ş. 2008. 1:100.000 ölçekli Türkiye jeoloji haritaları, Bandırma H 19 paftası No 103, Maden Tetkik ve Arama Genel Müdürlüğü, 26p. Ankara.
  • Anthony, J.W., Bideaux, R.A., Bladh, K.W., Nichols, M.C., 1995. Handbook of Mineralogy, Vol. II. Silica, Silicates, Mineral Data Publishing, Tucson, Arizona. (http://www.handbookofmineralogy.org/ pdfs/halloysite.pdf)
  • Başara, B., Saklar, S., Ağrılı, H., Kibar, U., 2013., Türkiye Halloysit Ve Kaolenlerinin Mineralojik Tanımlanmasında İnterkalasyon Yönteminin Araştırılması proje sonuç raporu, Maden Tetkik Arama Genel Müdürlüğü, Rapor No: 11705. Ankara, (unpublished).
  • Christie, A. B., Douch, C. J., Winfeld, B. J., Thompson, B. N., 2000, New Zealand’s industrial mineral potential, Industrial Minerals, July, 66p.
  • Christie, T., Thompson, B., Brathwaite, B., 2011, Mineral Commodity Report 20- Clays, http://www.nzpam. govt.nz/cms/pdf-library/minerals/publications
  • Churchman, G.J. 1990. Relevance of different intercalation tests for distinguishing halloysite from kaolinite in soils. Clays and Clay Minerals, 38, 591–599.
  • Churchman, G. J., Aldridge, L. P., Carr, R. M. 1972. The relationship between the hydrated and dehydrated states of an halloysite. Clays and Clay Minerals, 20, 241-246.
  • Churchman, G. J., Carr, R. M. 1973. Dehydration of the washed potassium acetate complex of halloysite. Clays and Clay Minerals, 21, 423-424.
  • Churchman, G. J., Theng, B. K. G. 1984. Interactions of halloysites with amides: mineralogical factors affecting complex formation. Clay Minerals, 19, 161-175.
  • Churchman, G. J., Whitton, J. S., Claridge, G. G. C., Theng, B. K. G. 1984. Intercalation method using formamide for differentiating halloysite from kaolinite. Clays and Clay Minerals, 32, 241–248.
  • Dönmez, M., Akçay, A.E., Duru, M., Ilgar, A., Pehlivan, Ş. 2008. 1:100.000 ölçekli Türkiye jeoloji haritaları, Çanakkale H 17 paftası No 101, Maden Tetkik ve Arama Genel Müdürlüğü, 27 p. Ankara.
  • Duru, M., Pehlivan, S., Dönmez, M., Ilgar, A., Akcay, A.E. 2007. 1:100.000 ölçekli Türkiye jeoloji haritaları, Bandırma H 18 paftası No 102, Maden Tetkik ve Arama Genel Müdürlüğü, 50 p. Ankara.
  • Duru, M., Pehlivan, Ş., Okay, A.İ., Şentürk, Y., Kar, H.,2012. Biga Yarımadası’nın Tersiyer Öncesi Jeolojisi, s.7-74, Biga Yarımadası’nın Genel ve Ekonomik Jeolojisi, Editörler: Erdoğan Yüzer, Gürkan Tunay, Maden Tetkik ve Arama Genel Müdürlüğü Özel Yayın Serisi, No: 28, Ankara.
  • Ece, Ö. İ., Schroeder, P. A. 2007. Clay mineralogy and chemistry of halloysite and alunite deposits in the Turplu area-Balıkesir-Turkey. Clays and Clay Minerals, 55, 1, 18-35.
  • Erdoğan, M., Gençoğlu, H., Mahmutoğlu, Y., 2012. Biga Yarımadası’nın Endüstriyel Hammadde Olanakları, s.273-289, Biga Yarımadası’nın Genel ve Ekonomik Jeolojisi, Editörler: Erdoğan Yüzer, Gürkan Tunay, Maden Tetkik ve Arama Genel Müdürlüğü Özel Yayın Serisi, No: 28, Ankara
  • Harrison, J.L., Greenberg, S.S., 1962. Dehydration of fully hydrated halloysite from Lawrence County, Indiana., 9th National Conference on Clays and Clay Minerals 374-377.
  • Hillier, S., Ryan, P.C. 2002. Identification of halloysite (7 Å) by ethylene glycol solvation: the ‘MacEwan effect’. Clay Minerals 37, 487–496.
  • Horvath, E., Kristof, J., Kurdi, R., Mako, E., Khunova, V. 2011. Study of urea intercalation into halloysite by thermoanalytical and spectroscopic techniques. Journal of Thermal Analysis and Calorimetry 105, 53–59.
  • Ilgar, A., Demirci, E.S., Demirci, Ö., 2012. Biga Yarımadası Tersiyer İstifinin Stratigrafisi ve Sedimantolojisi, s.75-122, Biga Yarımadası’nın Genel ve Ekonomik Jeolojisi, Editörler: Erdoğan Yüzer, Gürkan Tunay, Maden Tetkik ve Arama Genel Müdürlüğü Özel Yayın Serisi No: 28, Ankara
  • Joussein, E., Petit, S., Churchman, G. J, Theng, B. K. G., Righi, D., Delvaux, B. 2005. Halloysite clay minerals-a review. Clay Minerals, 40, 383–426.
  • Joussein, E., Petit, S., Fialips, C.I., Vieillard, P., Righi, D., 2006. Difference in the dehydration–rehydration behavior of halloysites: new evidence and interpretations. Clays and Clay Minerals 54, 473– 485.
  • Joussein, E., Petit, S., Delvaux, B. 2007. Behavior of halloysite clay under formamide treatment. Applied Clay Science 35, 17–24.
  • Kirkman, J.H.,1981. Morphology and structure of halloysite in New Zeland tephras, Clays and Clay Minerals 29 (1), 1-9.
  • Lacin, D., Yeniyol, M. 2006. An example to the halloysite deposits formed associated with the andesitic pyroclastics: Soğucak halloysite deposit (Yenice- Çanakkale). Istanbul Üniv. Yerbilimleri Dergisi 19, 1, 27-41.
  • Mellouk, S., Cherifi, S., Sassi, M., Marouf-Khelifa, K., Bengueddach, A., Schott, J. and Khelifa, A. 2009. Intercalation of halloysite from Djebel Debagh (Algeria), adsorption of copper ions. Applied Clay Science, 44, 230–236.
  • Murray, H. H. 2007. Applied Clay Mineralogy- Developments in Clay Science 2. Elsevier, 180p.
  • Nicolini, K. P., Fukamachi, C. R. B., Wypych, F., Mangrich, A. S. 2009. Dehydrated halloysite intercalated mechanochemically with urea: Thermal behavior and structural aspects. Journal of Colloid and Interface Science 338, 474–479.
  • Saklar, S., Ağrılı, H., Zimitoğlu, O., Başara, B., Bayrakdar, H., 2011. Türkiye halloysit kaynaklarının değerlendirme olanaklarının araştırılması proje sonuç raporu, Maden Tetkik Arama Genel Müdürlüğü Rapor No: 11467, 122 p. Ankara, (unpublished)
  • Saklar, S., Ağrılı, H., Zimitoğlu, O., Başara, B., Kaan, U. 2012. Kuzeybatı Anadolu halloysit/kaolinitlerinin karakterizasyon çalışmaları, Maden Tetkik Arama Genel Müdürlüğü Dergisi 145, 48-61.
  • Uygun, A. 1999. KB - Anadoluda karbonat kayaları içine yerleşmiş bazı halloysit yataklarının jeolojisi ve oluşumu. Maden Tetkik Arama Genel Müdürlüğü Dergisi 121, 141-151.
  • Wada, K. 1961. Lattice expansion of kaolin minerals by treatment with potassium acetate. American Mineralogist 46, 78-91.
  • Wills, B.A., Napier-Munn, T.J., 2006. Wills Mineral Processing Technology, 7th Edition, Elsevier, Amsterdam.
There are 32 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Articles
Authors

Bülent Başara This is me

Saruhan Saklar This is me

Publication Date June 30, 2015
Published in Issue Year 2015 Volume: 150 Issue: 150

Cite

APA Başara, B., & Saklar, S. (2015). HALLOYSITE INTERCALATION OF NORTHWEST ANATOLIA. Bulletin of the Mineral Research and Exploration, 150(150), 121-130. https://doi.org/10.19111/bmre.44287
AMA Başara B, Saklar S. HALLOYSITE INTERCALATION OF NORTHWEST ANATOLIA. Bull.Min.Res.Exp. June 2015;150(150):121-130. doi:10.19111/bmre.44287
Chicago Başara, Bülent, and Saruhan Saklar. “HALLOYSITE INTERCALATION OF NORTHWEST ANATOLIA”. Bulletin of the Mineral Research and Exploration 150, no. 150 (June 2015): 121-30. https://doi.org/10.19111/bmre.44287.
EndNote Başara B, Saklar S (June 1, 2015) HALLOYSITE INTERCALATION OF NORTHWEST ANATOLIA. Bulletin of the Mineral Research and Exploration 150 150 121–130.
IEEE B. Başara and S. Saklar, “HALLOYSITE INTERCALATION OF NORTHWEST ANATOLIA”, Bull.Min.Res.Exp., vol. 150, no. 150, pp. 121–130, 2015, doi: 10.19111/bmre.44287.
ISNAD Başara, Bülent - Saklar, Saruhan. “HALLOYSITE INTERCALATION OF NORTHWEST ANATOLIA”. Bulletin of the Mineral Research and Exploration 150/150 (June 2015), 121-130. https://doi.org/10.19111/bmre.44287.
JAMA Başara B, Saklar S. HALLOYSITE INTERCALATION OF NORTHWEST ANATOLIA. Bull.Min.Res.Exp. 2015;150:121–130.
MLA Başara, Bülent and Saruhan Saklar. “HALLOYSITE INTERCALATION OF NORTHWEST ANATOLIA”. Bulletin of the Mineral Research and Exploration, vol. 150, no. 150, 2015, pp. 121-30, doi:10.19111/bmre.44287.
Vancouver Başara B, Saklar S. HALLOYSITE INTERCALATION OF NORTHWEST ANATOLIA. Bull.Min.Res.Exp. 2015;150(150):121-30.

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