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The Synthesis of MSU-X Mesoporous Materials from Sodium Silicate

Year 2015, Volume: 11 Issue: 3, 0 - , 23.12.2015
https://izlik.org/JA94LP99WF

Abstract

MSU-x (MSU represents Michigan State University) materials are a family of ordered mesoporous silica obtained by using nonionic poly(ethylene oxide)-based surfactants [1]. MSU materials have many application areas due to their mesoporous structure, high mass oil cracking activity and high thermal stability [2]. In recent years MSU mesoporous materials were used in adsorption, catalytic applications, separation process, and drug delivery system [2-6].

In this study, MSU mesoporous silica materials were synthesized from sodium metasilicate pentahydrate (SMP) which is more cost-effective than the tetraethyl orthosilicate (TEOS) as a silica source and Pluronic 123 as a nonionic structure-directing triblock copolymer surfactant in an acidic medium. The synthesized materials were characterized by X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) analyses. The obtained results showed that the MSU-x was successfully synthesized. 

References

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  • K S. Triantafyllidis, E. F. Iliopoulou, E. V. Antonakou, A. A. Lappas, H. Wang, T. J. Pinnavaia, Microporous and Mesoporous Materials, 2007, 99, 132-139.
  • Y. Jung, S. Kim, S. J. Park, J. M. Kim, Colloids and Surfaces A: Physicochem. Eng. Aspects, 2008, 313-314, 162-166.
  • H. Liu, Z. Wang, H. Hu, Y. Liang, M. Wang, Journal of Solid State Chemistry, 2009, 182, 1726-1732.
  • E. Prouzet, C. Boissiere, C. R. Chimie, 2005, 8, 579-596.
  • M. Kruk, M. Jaroniec, J. Phys. Chem. 2001, 105, 7663-7670.
  • P.S. Liu, G.F. Chen, ‘Porous Materials’, Chapter 9, Tsinghua University Press Limited. Published by Elsevier Inc. , 2014.
  • P.S. Liu, G.F. Chen, ‘Porous Materials’, Chapter 3, Tsinghua University Press Limited. Published by Elsevier Inc. , 2014.
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  • B. D. Zdravkov, J.J. Cermak, M. Sefara, J. Jankü, Pore classification in the characterization of porous materials: A perspective, Central European Journal of Chemistry, 2007, 385–395.
  • A. Lu, F. Schüth, Nanocasting: “A Versatile Strategy for Creating Nanostructured Porous Materials”, Advanced Materials, 2006, 18, 1793–1805.
  • T.J. Barton, L.M. Bull, W.G. Klemperer, D.A. Loy, B. McEnaney, M. Misono, P.A.Monson, G. Pez, G.W. Scherer, J. C. Vartuli, O.M. Yaghi, Tailored Porous Materials, 2007, 385–395.
  • G. Haberhauer, M.H. Gerzabek, Australian Research Centers, 28 July 1998.
  • M. S. Yılmaz, S. Pişkin, “Evaluation of novel synthesis of ordered SBA-15 mesoporous silica from gold mine tailings slurry by experimental design”, Journal of the Taiwan Institute of Chemical Engineers 46 ,176–182, 2015.
  • M. S. Yılmaz, Ö. D. Özdemir, S. Pişkin, “Synthesis and characterization of MCM-41 with different methods and adsorption of Sr2+ on MCM-41”, Res Chem Intermed (2015) 41:199–211.
  • C. Boissiere, A. Larbot, A. Lee, P. J. Kooyman, E. Prouzet, “A New Synthesis of Mesoporous MSU-X Silica Controlled by a Two-Step Pathway”, Chem. Mater. 2000, 12, 2902-2913.

Year 2015, Volume: 11 Issue: 3, 0 - , 23.12.2015
https://izlik.org/JA94LP99WF

Abstract

References

  • C. Boissie`re, A. Larbot, E. Prouzet, Chemistry of Materials 2000, 12, 1937-1940.
  • K S. Triantafyllidis, E. F. Iliopoulou, E. V. Antonakou, A. A. Lappas, H. Wang, T. J. Pinnavaia, Microporous and Mesoporous Materials, 2007, 99, 132-139.
  • Y. Jung, S. Kim, S. J. Park, J. M. Kim, Colloids and Surfaces A: Physicochem. Eng. Aspects, 2008, 313-314, 162-166.
  • H. Liu, Z. Wang, H. Hu, Y. Liang, M. Wang, Journal of Solid State Chemistry, 2009, 182, 1726-1732.
  • E. Prouzet, C. Boissiere, C. R. Chimie, 2005, 8, 579-596.
  • M. Kruk, M. Jaroniec, J. Phys. Chem. 2001, 105, 7663-7670.
  • P.S. Liu, G.F. Chen, ‘Porous Materials’, Chapter 9, Tsinghua University Press Limited. Published by Elsevier Inc. , 2014.
  • P.S. Liu, G.F. Chen, ‘Porous Materials’, Chapter 3, Tsinghua University Press Limited. Published by Elsevier Inc. , 2014.
  • K. Ishizaki, S. Komarnen, M. Nanko, ‘Porous Materials: Process technology and applications’, Springer Science, 1998.
  • B. D. Zdravkov, J.J. Cermak, M. Sefara, J. Jankü, Pore classification in the characterization of porous materials: A perspective, Central European Journal of Chemistry, 2007, 385–395.
  • A. Lu, F. Schüth, Nanocasting: “A Versatile Strategy for Creating Nanostructured Porous Materials”, Advanced Materials, 2006, 18, 1793–1805.
  • T.J. Barton, L.M. Bull, W.G. Klemperer, D.A. Loy, B. McEnaney, M. Misono, P.A.Monson, G. Pez, G.W. Scherer, J. C. Vartuli, O.M. Yaghi, Tailored Porous Materials, 2007, 385–395.
  • G. Haberhauer, M.H. Gerzabek, Australian Research Centers, 28 July 1998.
  • M. S. Yılmaz, S. Pişkin, “Evaluation of novel synthesis of ordered SBA-15 mesoporous silica from gold mine tailings slurry by experimental design”, Journal of the Taiwan Institute of Chemical Engineers 46 ,176–182, 2015.
  • M. S. Yılmaz, Ö. D. Özdemir, S. Pişkin, “Synthesis and characterization of MCM-41 with different methods and adsorption of Sr2+ on MCM-41”, Res Chem Intermed (2015) 41:199–211.
  • C. Boissiere, A. Larbot, A. Lee, P. J. Kooyman, E. Prouzet, “A New Synthesis of Mesoporous MSU-X Silica Controlled by a Two-Step Pathway”, Chem. Mater. 2000, 12, 2902-2913.
There are 16 citations in total.

Details

Primary Language English
Authors

Nervin Mermer This is me

Sevil Karakaş This is me

Müge Yılmaz

Publication Date December 23, 2015
DOI https://doi.org/10.18466/cbujos.55665
IZ https://izlik.org/JA94LP99WF
Published in Issue Year 2015 Volume: 11 Issue: 3

Cite

APA Mermer, N., Karakaş, S., & Yılmaz, M. (2015). The Synthesis of MSU-X Mesoporous Materials from Sodium Silicate. Celal Bayar University Journal of Science, 11(3). https://doi.org/10.18466/cbujos.55665
AMA 1.Mermer N, Karakaş S, Yılmaz M. The Synthesis of MSU-X Mesoporous Materials from Sodium Silicate. CBUJOS. 2015;11(3). doi:10.18466/cbujos.55665
Chicago Mermer, Nervin, Sevil Karakaş, and Müge Yılmaz. 2015. “The Synthesis of MSU-X Mesoporous Materials from Sodium Silicate”. Celal Bayar University Journal of Science 11 (3). https://doi.org/10.18466/cbujos.55665.
EndNote Mermer N, Karakaş S, Yılmaz M (December 1, 2015) The Synthesis of MSU-X Mesoporous Materials from Sodium Silicate. Celal Bayar University Journal of Science 11 3
IEEE [1]N. Mermer, S. Karakaş, and M. Yılmaz, “The Synthesis of MSU-X Mesoporous Materials from Sodium Silicate”, CBUJOS, vol. 11, no. 3, Dec. 2015, doi: 10.18466/cbujos.55665.
ISNAD Mermer, Nervin - Karakaş, Sevil - Yılmaz, Müge. “The Synthesis of MSU-X Mesoporous Materials from Sodium Silicate”. Celal Bayar University Journal of Science 11/3 (December 1, 2015). https://doi.org/10.18466/cbujos.55665.
JAMA 1.Mermer N, Karakaş S, Yılmaz M. The Synthesis of MSU-X Mesoporous Materials from Sodium Silicate. CBUJOS. 2015;11. doi:10.18466/cbujos.55665.
MLA Mermer, Nervin, et al. “The Synthesis of MSU-X Mesoporous Materials from Sodium Silicate”. Celal Bayar University Journal of Science, vol. 11, no. 3, Dec. 2015, doi:10.18466/cbujos.55665.
Vancouver 1.Nervin Mermer, Sevil Karakaş, Müge Yılmaz. The Synthesis of MSU-X Mesoporous Materials from Sodium Silicate. CBUJOS. 2015 Dec. 1;11(3). doi:10.18466/cbujos.55665