Synthesis, Radical Copolymerization of (p-vinylphenyl)cyclopropyl chlorocinnamate with Styrene and Photosensitivity of the Prepared Copolymer

Abstract

The radical copolymerization of of (p-vinylphenyl)cyclopropyl chlorocinnamate with styrene has been studied. The new cyclopropane-containing photosensitive copolymer has been prepared. The composition and structure of the synthesized copolymer have been established, the constant values of relative activity of monomers have been determined and the parameters Q-e have been calculated. The dependence of photosensitivity on composition of copolymer has been revealed.

Keywords

• microstructure, monomers, copolymerization, (p-vinylphenyl)cyclopropyl chlorocinnamate, photosensitivity

References

1. Bokov Yu.S. «Photo-, Electrono- and X-ray resists». Publ.house «Radio and communications» 1982, 135.
2. Ohe Y, Ito H, Watanabe N, Ichimura K. J Appl Polym Sci 2000;77: 2189.
3. Yanovskaya L.A., Dombrovskiy V.A., Khusid A.Kh. Cyclopropanes with functional groups. Publ.house „Nauka ”. Moscow 1980.P-197.
4. Guliyev K.G., Ponomaryova G.Z., Guliyev A.M. Synthesis and properties of epoxy-containing polycyclopropyl styrene.// High-molecular compounds (Russian). Series B. Vol 49, N−8, p. 1577-1581. 2007.
5. K.G.Guliyev, A.M.Aliyeva, G.Z.Ponomaryova, D.R.Nurullayeva, A.M.Guliyev, American Journal of Applied Chemistry, 2015, Vol. 3, № 1, P.21-24.
6. Guliyev K.G., Aliyeva A.M., Guliyev A.M. Synthesis and polymerization of (p-vinylphenyl)cyclopropyl chlorocinnamate. // J.Applied Chemistry (Russian). 2013. V. 86. N 1. P. 101-104.
7. Kolesnikov G.S. Synthesis of vinyl derivatives of aromatic and heterocyclic compounds.- M.: IAN USSR, 1960, p. 21-22.
8. Kuznetsov E.V., Divgun S.M. et al. Practical work on chemistry and physics of polymers. M.: Chemistry, 1977. P 256.

9. Zilberman E.N. // High-molecular compounds (Russian). B. 1979. V.21, № 1. p.33-36
10. Guliyev K.G., Ponomaryova G.Z., Mamedli S.B., Guliyev A.M. // Journal of Structural Chemistry (Russian). 2009. V. 50. № 4. P. 720-722.
11. Rehab A, Salahuddin N. Polymer 1999;40:2197.