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The Synthesis of MSU-X Mesoporous Materials from Sodium Silicate

Year 2015, Volume: 11 Issue: 3, 0 - , 23.12.2015

Nervin Mermer Sevil Karakaş Müge Yılmaz

Abstract

MSU-x (MSU represents Michigan State University) materials are a family of ordered mesoporous silica obtained by using nonionic poly(ethylene oxide)-based surfactants [1]. MSU materials have many application areas due to their mesoporous structure, high mass oil cracking activity and high thermal stability [2]. In recent years MSU mesoporous materials were used in adsorption, catalytic applications, separation process, and drug delivery system [2-6].

In this study, MSU mesoporous silica materials were synthesized from sodium metasilicate pentahydrate (SMP) which is more cost-effective than the tetraethyl orthosilicate (TEOS) as a silica source and Pluronic 123 as a nonionic structure-directing triblock copolymer surfactant in an acidic medium. The synthesized materials were characterized by X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) analyses. The obtained results showed that the MSU-x was successfully synthesized. 

Keywords

component; Mesoporous MSU-x silicate XRD FT-IR

References

  • C. Boissie`re, A. Larbot, E. Prouzet, Chemistry of Materials 2000, 12, 1937-1940.
  • K S. Triantafyllidis, E. F. Iliopoulou, E. V. Antonakou, A. A. Lappas, H. Wang, T. J. Pinnavaia, Microporous and Mesoporous Materials, 2007, 99, 132-139.
  • Y. Jung, S. Kim, S. J. Park, J. M. Kim, Colloids and Surfaces A: Physicochem. Eng. Aspects, 2008, 313-314, 162-166.
  • H. Liu, Z. Wang, H. Hu, Y. Liang, M. Wang, Journal of Solid State Chemistry, 2009, 182, 1726-1732.
  • E. Prouzet, C. Boissiere, C. R. Chimie, 2005, 8, 579-596.
  • M. Kruk, M. Jaroniec, J. Phys. Chem. 2001, 105, 7663-7670.
  • P.S. Liu, G.F. Chen, ‘Porous Materials’, Chapter 9, Tsinghua University Press Limited. Published by Elsevier Inc. , 2014.
  • P.S. Liu, G.F. Chen, ‘Porous Materials’, Chapter 3, Tsinghua University Press Limited. Published by Elsevier Inc. , 2014.
  • K. Ishizaki, S. Komarnen, M. Nanko, ‘Porous Materials: Process technology and applications’, Springer Science, 1998.
  • B. D. Zdravkov, J.J. Cermak, M. Sefara, J. Jankü, Pore classification in the characterization of porous materials: A perspective, Central European Journal of Chemistry, 2007, 385–395.
  • A. Lu, F. Schüth, Nanocasting: “A Versatile Strategy for Creating Nanostructured Porous Materials”, Advanced Materials, 2006, 18, 1793–1805.
  • T.J. Barton, L.M. Bull, W.G. Klemperer, D.A. Loy, B. McEnaney, M. Misono, P.A.Monson, G. Pez, G.W. Scherer, J. C. Vartuli, O.M. Yaghi, Tailored Porous Materials, 2007, 385–395.
  • G. Haberhauer, M.H. Gerzabek, Australian Research Centers, 28 July 1998.
  • M. S. Yılmaz, S. Pişkin, “Evaluation of novel synthesis of ordered SBA-15 mesoporous silica from gold mine tailings slurry by experimental design”, Journal of the Taiwan Institute of Chemical Engineers 46 ,176–182, 2015.
  • M. S. Yılmaz, Ö. D. Özdemir, S. Pişkin, “Synthesis and characterization of MCM-41 with different methods and adsorption of Sr2+ on MCM-41”, Res Chem Intermed (2015) 41:199–211.
  • C. Boissiere, A. Larbot, A. Lee, P. J. Kooyman, E. Prouzet, “A New Synthesis of Mesoporous MSU-X Silica Controlled by a Two-Step Pathway”, Chem. Mater. 2000, 12, 2902-2913.

Year 2015, Volume: 11 Issue: 3, 0 - , 23.12.2015

Nervin Mermer Sevil Karakaş Müge Yılmaz

Abstract

References

  • C. Boissie`re, A. Larbot, E. Prouzet, Chemistry of Materials 2000, 12, 1937-1940.
  • K S. Triantafyllidis, E. F. Iliopoulou, E. V. Antonakou, A. A. Lappas, H. Wang, T. J. Pinnavaia, Microporous and Mesoporous Materials, 2007, 99, 132-139.
  • Y. Jung, S. Kim, S. J. Park, J. M. Kim, Colloids and Surfaces A: Physicochem. Eng. Aspects, 2008, 313-314, 162-166.
  • H. Liu, Z. Wang, H. Hu, Y. Liang, M. Wang, Journal of Solid State Chemistry, 2009, 182, 1726-1732.
  • E. Prouzet, C. Boissiere, C. R. Chimie, 2005, 8, 579-596.
  • M. Kruk, M. Jaroniec, J. Phys. Chem. 2001, 105, 7663-7670.
  • P.S. Liu, G.F. Chen, ‘Porous Materials’, Chapter 9, Tsinghua University Press Limited. Published by Elsevier Inc. , 2014.
  • P.S. Liu, G.F. Chen, ‘Porous Materials’, Chapter 3, Tsinghua University Press Limited. Published by Elsevier Inc. , 2014.
  • K. Ishizaki, S. Komarnen, M. Nanko, ‘Porous Materials: Process technology and applications’, Springer Science, 1998.
  • B. D. Zdravkov, J.J. Cermak, M. Sefara, J. Jankü, Pore classification in the characterization of porous materials: A perspective, Central European Journal of Chemistry, 2007, 385–395.
  • A. Lu, F. Schüth, Nanocasting: “A Versatile Strategy for Creating Nanostructured Porous Materials”, Advanced Materials, 2006, 18, 1793–1805.
  • T.J. Barton, L.M. Bull, W.G. Klemperer, D.A. Loy, B. McEnaney, M. Misono, P.A.Monson, G. Pez, G.W. Scherer, J. C. Vartuli, O.M. Yaghi, Tailored Porous Materials, 2007, 385–395.
  • G. Haberhauer, M.H. Gerzabek, Australian Research Centers, 28 July 1998.
  • M. S. Yılmaz, S. Pişkin, “Evaluation of novel synthesis of ordered SBA-15 mesoporous silica from gold mine tailings slurry by experimental design”, Journal of the Taiwan Institute of Chemical Engineers 46 ,176–182, 2015.
  • M. S. Yılmaz, Ö. D. Özdemir, S. Pişkin, “Synthesis and characterization of MCM-41 with different methods and adsorption of Sr2+ on MCM-41”, Res Chem Intermed (2015) 41:199–211.
  • C. Boissiere, A. Larbot, A. Lee, P. J. Kooyman, E. Prouzet, “A New Synthesis of Mesoporous MSU-X Silica Controlled by a Two-Step Pathway”, Chem. Mater. 2000, 12, 2902-2913.
There are 16 citations in total.

Details

Primary Language English
Journal Section Articles
Authors

Nervin Mermer This is me

Sevil Karakaş This is me

Müge Yılmaz

Publication Date December 23, 2015
Published in Issue Year 2015 Volume: 11 Issue: 3

Cite

APA Mermer, N., Karakaş, S., & Yılmaz, M. (2015). The Synthesis of MSU-X Mesoporous Materials from Sodium Silicate. Celal Bayar Üniversitesi Fen Bilimleri Dergisi, 11(3). https://doi.org/10.18466/cbujos.55665
AMA Mermer N, Karakaş S, Yılmaz M. The Synthesis of MSU-X Mesoporous Materials from Sodium Silicate. CBUJOS. December 2015;11(3). doi:10.18466/cbujos.55665
Chicago Mermer, Nervin, Sevil Karakaş, and Müge Yılmaz. “The Synthesis of MSU-X Mesoporous Materials from Sodium Silicate”. Celal Bayar Üniversitesi Fen Bilimleri Dergisi 11, no. 3 (December 2015). https://doi.org/10.18466/cbujos.55665.
EndNote Mermer N, Karakaş S, Yılmaz M (December 1, 2015) The Synthesis of MSU-X Mesoporous Materials from Sodium Silicate. Celal Bayar Üniversitesi Fen Bilimleri Dergisi 11 3
IEEE N. Mermer, S. Karakaş, and M. Yılmaz, “The Synthesis of MSU-X Mesoporous Materials from Sodium Silicate”, CBUJOS, vol. 11, no. 3, 2015, doi: 10.18466/cbujos.55665.
ISNAD Mermer, Nervin et al. “The Synthesis of MSU-X Mesoporous Materials from Sodium Silicate”. Celal Bayar Üniversitesi Fen Bilimleri Dergisi 11/3 (December 2015). https://doi.org/10.18466/cbujos.55665.
JAMA Mermer N, Karakaş S, Yılmaz M. The Synthesis of MSU-X Mesoporous Materials from Sodium Silicate. CBUJOS. 2015;11. doi:10.18466/cbujos.55665.
MLA Mermer, Nervin et al. “The Synthesis of MSU-X Mesoporous Materials from Sodium Silicate”. Celal Bayar Üniversitesi Fen Bilimleri Dergisi, vol. 11, no. 3, 2015, doi:10.18466/cbujos.55665.
Vancouver Mermer N, Karakaş S, Yılmaz M. The Synthesis of MSU-X Mesoporous Materials from Sodium Silicate. CBUJOS. 2015;11(3).