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Synthesis and Cationic polymerization of Some Substituted of Vinylcyclopropyl Ethers

Year 2015, Volume: 11 Issue: 3, 0 - , 23.12.2015

R Shahnazarli Sh Aliyeva Abasgulu Guliyev

Abstract

By cationic polymerization of substituted vinylcyclopropyl ethers a series of polyvinylcyclopropyl ethers has been prepared. By data of spectral analysis the structure of the prepared polymers has been established and it has been shown that the polymerization proceeds only with opening of double bond and conservation of cyclopropane ring. The influence of substituent of three-membered cycle on reactivity of the synthesized monomers has been estimated.

Keywords

synthesis; cyclopropane-containing vinyl ethers; reactivity of monomers; cationic polymerization; model reactions

References

  • M. F. Shostakovskiy, “Vinyl ethers”. M.: AS USSR, 1962, 167 p.
  • M. V. Markova, D. I. Mognolov, L. V. Morozova and et al, “Composition proton conducting membranes on the basis of polyvinylglycidyl ether of ethylene glycol”. High-molecular compounds (in Russian). 2004, 56 B, № 2, p. 216-225
  • B. A. Zhubanov, E. M. Shaykhutdinov, E. F. Osadchaya, “Vinyl ethers in the radical polymerization”. Alam-Ata: Nauka, 1985. 160 p.
  • A. Matsumoto, T. Nakana, M. Oiwa, “Radical polymerization of Butyl Vinyl Ether”. Macromol.Chem., Rapid Commun., 1983, 4, p.277-279
  • K. Zh. Abdiyev, “Synthesis of (so)polymers on the basis of vinyl ethers” (Review). Izv.AS Repub.Kaz. 2008, Ser.chem. № 3, p.33-41
  • R. Z. Shahnazarli, Sh. H. Aliyeva, A. M. Guliyev, “Cationic polymerization of cyclopropane-containing vinyl ethers”. Georgia, Batumi, 2015, p.110. [Digests 4th International Caucasian Symposium on Polymers and Advanced Materials “ICSP&AM4”].
  • S. M. Shostakovskiy, V. N. Mochalov, G. M. Larionov, “Synthesis and biological activity of gem-dichlorocyclopropyl ethers”. Chem.Pharm.J., (in Russian), 1985. № 11, p.1330-1335
  • K. A. Makarov, A. F. Nikolaev, A. I.Andreev et al., “Estimation of copolymerization ability of monomers on results of chromatographic study of copolymerization”. High-molecular compounds (in Russian), 1967, v.115, № 12, p.867-868
  • T. V. Arbuzova, “Synthesis of substituted gem-dichlorocyclopropanes and reactions on their basisе”.– Dissert.cand.chem.sci., Ufa, 2006, 111 p.
  • M. S. Zefirov, I. V. Kazimirchik, K. A. Lukin. “Cycloaddition of dichlorocarbene to olefins”. M.: Nauka, 1985, p.144-150
  • F. Sanda, T. Takata, T. Endo, “Vinylcyclopropanone Cyclic Acetale – Synthesis, Polymerization, Structure of the Polymer and Mechanism of the Polymerization”. Macromolecules. 1994, v.27, p.1099-1111
  • R. Z. Shahnazarli, A. A. Aliyeva, A. M. .Guliyev, “Chemical; reagent and processes of multitonnage chemistry” (REACTANT-2007): Coll.scient.works XX Intern.scien.-techn.conf. Minsk, 2007. P. 89-95

Year 2015, Volume: 11 Issue: 3, 0 - , 23.12.2015

R Shahnazarli Sh Aliyeva Abasgulu Guliyev

Abstract

References

  • M. F. Shostakovskiy, “Vinyl ethers”. M.: AS USSR, 1962, 167 p.
  • M. V. Markova, D. I. Mognolov, L. V. Morozova and et al, “Composition proton conducting membranes on the basis of polyvinylglycidyl ether of ethylene glycol”. High-molecular compounds (in Russian). 2004, 56 B, № 2, p. 216-225
  • B. A. Zhubanov, E. M. Shaykhutdinov, E. F. Osadchaya, “Vinyl ethers in the radical polymerization”. Alam-Ata: Nauka, 1985. 160 p.
  • A. Matsumoto, T. Nakana, M. Oiwa, “Radical polymerization of Butyl Vinyl Ether”. Macromol.Chem., Rapid Commun., 1983, 4, p.277-279
  • K. Zh. Abdiyev, “Synthesis of (so)polymers on the basis of vinyl ethers” (Review). Izv.AS Repub.Kaz. 2008, Ser.chem. № 3, p.33-41
  • R. Z. Shahnazarli, Sh. H. Aliyeva, A. M. Guliyev, “Cationic polymerization of cyclopropane-containing vinyl ethers”. Georgia, Batumi, 2015, p.110. [Digests 4th International Caucasian Symposium on Polymers and Advanced Materials “ICSP&AM4”].
  • S. M. Shostakovskiy, V. N. Mochalov, G. M. Larionov, “Synthesis and biological activity of gem-dichlorocyclopropyl ethers”. Chem.Pharm.J., (in Russian), 1985. № 11, p.1330-1335
  • K. A. Makarov, A. F. Nikolaev, A. I.Andreev et al., “Estimation of copolymerization ability of monomers on results of chromatographic study of copolymerization”. High-molecular compounds (in Russian), 1967, v.115, № 12, p.867-868
  • T. V. Arbuzova, “Synthesis of substituted gem-dichlorocyclopropanes and reactions on their basisе”.– Dissert.cand.chem.sci., Ufa, 2006, 111 p.
  • M. S. Zefirov, I. V. Kazimirchik, K. A. Lukin. “Cycloaddition of dichlorocarbene to olefins”. M.: Nauka, 1985, p.144-150
  • F. Sanda, T. Takata, T. Endo, “Vinylcyclopropanone Cyclic Acetale – Synthesis, Polymerization, Structure of the Polymer and Mechanism of the Polymerization”. Macromolecules. 1994, v.27, p.1099-1111
  • R. Z. Shahnazarli, A. A. Aliyeva, A. M. .Guliyev, “Chemical; reagent and processes of multitonnage chemistry” (REACTANT-2007): Coll.scient.works XX Intern.scien.-techn.conf. Minsk, 2007. P. 89-95
There are 12 citations in total.

Details

Primary Language English
Journal Section Articles
Authors

R Shahnazarli This is me

Sh Aliyeva This is me

Abasgulu Guliyev This is me

Publication Date December 23, 2015
Published in Issue Year 2015 Volume: 11 Issue: 3

Cite

APA Shahnazarli, R., Aliyeva, S., & Guliyev, A. (2015). Synthesis and Cationic polymerization of Some Substituted of Vinylcyclopropyl Ethers. Celal Bayar Üniversitesi Fen Bilimleri Dergisi, 11(3). https://doi.org/10.18466/cbujos.59141
AMA Shahnazarli R, Aliyeva S, Guliyev A. Synthesis and Cationic polymerization of Some Substituted of Vinylcyclopropyl Ethers. CBUJOS. December 2015;11(3). doi:10.18466/cbujos.59141
Chicago Shahnazarli, R, Sh Aliyeva, and Abasgulu Guliyev. “Synthesis and Cationic Polymerization of Some Substituted of Vinylcyclopropyl Ethers”. Celal Bayar Üniversitesi Fen Bilimleri Dergisi 11, no. 3 (December 2015). https://doi.org/10.18466/cbujos.59141.
EndNote Shahnazarli R, Aliyeva S, Guliyev A (December 1, 2015) Synthesis and Cationic polymerization of Some Substituted of Vinylcyclopropyl Ethers. Celal Bayar Üniversitesi Fen Bilimleri Dergisi 11 3
IEEE R. Shahnazarli, S. Aliyeva, and A. Guliyev, “Synthesis and Cationic polymerization of Some Substituted of Vinylcyclopropyl Ethers”, CBUJOS, vol. 11, no. 3, 2015, doi: 10.18466/cbujos.59141.
ISNAD Shahnazarli, R et al. “Synthesis and Cationic Polymerization of Some Substituted of Vinylcyclopropyl Ethers”. Celal Bayar Üniversitesi Fen Bilimleri Dergisi 11/3 (December 2015). https://doi.org/10.18466/cbujos.59141.
JAMA Shahnazarli R, Aliyeva S, Guliyev A. Synthesis and Cationic polymerization of Some Substituted of Vinylcyclopropyl Ethers. CBUJOS. 2015;11. doi:10.18466/cbujos.59141.
MLA Shahnazarli, R et al. “Synthesis and Cationic Polymerization of Some Substituted of Vinylcyclopropyl Ethers”. Celal Bayar Üniversitesi Fen Bilimleri Dergisi, vol. 11, no. 3, 2015, doi:10.18466/cbujos.59141.
Vancouver Shahnazarli R, Aliyeva S, Guliyev A. Synthesis and Cationic polymerization of Some Substituted of Vinylcyclopropyl Ethers. CBUJOS. 2015;11(3).