Influence of Nanofibrillated Cellulose on Mechanical and Thermal Properties of Polyester Composites
Year 2023,
Volume: 19 Issue: 2, 189 - 195, 29.06.2023
Bayram Poyraz
,
Şevki Eren
,
Serkan Subaşı
,
Ayhan Tozluoğlu
Abstract
This study reports the effects of nano-fibrillated cellulose fillers on the chemical, thermal, and mechanical properties of unsaturated polyester (PE) composites. In the study, the PE was mixed with Nanofibrillated Cellulose (CNF) in the ratios of 0.5, 1, and 1.5 % using Methyl Ethyl Ketone Peroxide (MEKP) and Cobalt octoate (CoOc) as initiator and catalyst, respectively. For characterization, chemical and thermal analyses were carried out with FT-IR and thermogravimetric analysis. Mechanical properties were investigated with Universal Testing Machine, and morphological properties were investigated with SEM. At the end of the study, some minor altered vibrations were seen in FT-IR while thermal stability decreased. The compressive strength of filler-based composites was lower than that of the neat PE composite whereas tensile strength increased. Homogenous dispersion was also seen in the composites. This study confirms the applicability of various fillers as a reinforcing agent in PE resin used in the pipeline sector.
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Year 2023,
Volume: 19 Issue: 2, 189 - 195, 29.06.2023
Bayram Poyraz
,
Şevki Eren
,
Serkan Subaşı
,
Ayhan Tozluoğlu
References
- References 1
Kalkan, E, Karakışla, MM, Saçak, M. 2018. Polypyrrole and silver particles coated poly (ethylene terephthalate) nonwoven composite for electromagnetic interference shielding. Journal of Composite Materials, 52(10): 1353-1362.
- References 2
Eichorn, S and Dufresne, A. 2018. Review: current international research into cellulose nanofibers and nanocomposite. Journal of Material Science, 45: 1-33.
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Klemm, D, Kramer, F, Moritz, S, Lindström, T, Ankerfors, M, Gray, D, Dorri, A. 2011. Nanocellulose: a new family of nature-based materials, Angewandte Chemie International Edition, 50: 5438–5466.
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Bismarck, S, Mishra, T, Lampke, M, Misra, LT. 2005. Plant fibers as reinforcement for green composites, in Mohanty AK (Ed.), Natural Fibres, Biopolymers, and Biocomposites, CRS Press.
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SpƗrninš, E. 2006. Mechanical Properties of Flax Fibers and Their Composites, 971, Luleå University, Luleå, Sweden.
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Güven, O, Monteiro, S, Mourac, E, Drelich, J. 2016. Re-Emerging Field of Lignocellulosic Fiber – Polymer Composites and Ionizing Radiation Technology in their Formulation, Polymer Reviews, 56(4): 702-736.
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Lin, N and Dufresne, A. 2014. Nanocellulose in biomedicine: current status and future prospect, European Polymer Journal, 59: 302–325.
- References 8
Kim, DY and Stecki, AJ. 2010. Electrowetting on paper for electronic paper display, ACS Applied Material Interaction, 2(11): 3318–3323.
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Haghdan, S, and Smith, GD. 2016. Natural fiber reinforced polyester composites: A literature review Journal of Reinforced Plastics and Composites, 34(14): 1179-1190.
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Cintil, JC, Jithin, J, Lovely, M, Joachim, K, Sabu, T. 2014. Nanofibril reinforced unsaturated polyester nanocomposites: Morphology, mechanical and barrier properties, viscoelastic behavior and polymer chain confinement, Industrial Crops and Products, 56: 246–254.
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Cintil, JC, Jithin, J, Lovely, M, Hassan, PA, Miran, M, Sabu, T. 2014. Rheological behavior of nanocellulose reinforced unsaturated polyester nanocomposite, International Journal of Biological Macromolecules, 69: 274–281.
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Farhan, A, Mikael, S, Lars, B. 2015. Nanostructured biocomposites based on unsaturated polyester resin and a cellulose nanofiber network, Composites Science and Technology, 117: 298-30.
- References 13
Alessandra, L, Lisete, CS, Ademir, JZ. 2016. Dynamic-mechanical and thermomechanical properties of cellulose nanofiber/polyester resin composites, Carbohydrate Polymers, 136: 955–963.
- References 14
Poyraz, B, Tozluoğlu, A, Candan, Z, Demir, A. 2017. Influence of PVA and silica on chemical, thermo-mechanical and electric properties of Celluclast treated nano fibrillated cellulose composites, International Journal of Biological Macromolecules, 104: 384–392.
- References 15
ASTM (2012) C579-18. Standard test methods for compressive strength of chemical-resistant mortars. grouts. monolithic surfacings and polymer concrete. ASTM International, USA.
- References 16
Carrillo, F, Colom, X, Sunol, J, Saurina, J. 2004. Structural FTIR analysis and thermal characterization of lyocell and viscose-type fibers. European Polymer Journal, 40(9): 2229-2234.
- References 17
Shimazaki, Y, Yasuo, M, Yoshitaka, T, Masaya, N, Kentaro, A, Shinsuku, I, Hiroyuki, Y. 2007. Excellent thermal conductivity of transparent cellulose nanofiber/epoxy resin nanocomposites. Biomacromolecules, 8(9): 2976-2978.
- References 18
Zhua, J, Suying, W, Rahul, P, Ran, D, Ashwini, SK, Andrew, W, Zhang, G. 2011. Ionic liquid assisted electrospinning of quantum dots/elastomer composite nanofibers. Polymer, 52; 1954-1962.