COORDINATION POLYMERS BASED ON MIXED CARBOXYLATE LIGANDS: SYNTHESIS AND THERMAL STUDIES

Abstract

The synthesis of Co II , Cu II , Fe II and Zn II based coordination compounds using terephthalic acid BDC , tartaric acid DHB , and 4- hydroxybenzoic acid 4-HBA as ligands by a solvent-based and solvent-free methods were reported. Thermal studies of the complexes performed in the temperature range of 30 ºC-950 °C showed a 9.406% weight loss observed between 200 ºC-517 ºC for [Co DHB 4-HBA ] complex, and a 1.883 % weight loss observed between 80 ºC352.68 ºC for [Cu DHB 4-HBA ] complex.

Keywords

• Metal complexes,Solvent-based method,Terephthalic acid,Thermal studies

COORDINATION POLYMERS BASED ON MIXED CARBOXYLATE LIGANDS: SYNTHESIS AND THERMAL STUDIES

Abstract

Co II , Cu II , Fe II ve Zn II iyonlarına dayalı koordinasyon bileşiklerinin çözücü içeren ve çözücü içermeyen yöntemler ile ligand olarak tereftalik asit BDC , tartarik asit DHB ve 4-hidroksibenzoik asit 4-HBA kullanılarak sentezi rapor edilmiştir. Komplekslerin 30 ºC-950 °C sıcaklık aralığında gerçekleştirilen termal çalışmaları, [Co DHB 4-HBA ] kompleksi için 200 ºC-517 ºC arasında gözlenen % 9.406 kütle kaybını ve [Cu DHB 4- HBA ] kompleksi için 80 ºC-352.68 ºC arasında gözlenen % 1.883 kütle kaybını göstermiştir.

References

1. R.J. Kuppler, D.J. Timmons, Q.R. Fang, J.R. Li, T.A. Makal, M.D. Young, D. Yuan, D. Zhao, W. Zhuang, and H.C. Zhou, Potential applications of metal-organic frameworks. Coordination Chemistry Reviews, 253 (2009) 3066.
2. Z. Wang, G. Chen, and K. Ding, Self-supported catalysts. Chemical Reviews, (2009) 322-359.
3. J.R. Li, R.J. Kuppler, and H.C. Zhou, Selective gas adsorption and separation in metal–organic frameworks, Chemical Society Reviews, 38 (2009) 1477-1504.
4. P. Horcajada, C. Serre, G. Maurin, N.A. Ramsahye, F. Balas, M. Vallet- Regi, M. Sebban, F. Taulelle, and G.J. Ferey, Flexible porous metal-organic frameworks for a controlled drug delivery. American Chemical Society, 130 (2008) 6774-6780.
5. Y.K. Park, S.B. Choi, H. Kim, K. Kim, B.H. Won, K. Choi, J.S. Choi, W.S. Ahn, N. Won, S. Kim, D.H. Jung, S.H. Choi, G.H. Kim, S.S. Cha, Y.H. Jhon, J.K. Yang, and J. Kim, Crystal structure and guest uptake of a mesoporous metal-organic framework containing cages of 3.9 and 4.7 nm in diameter. Angewandte Chemie International Edition in English, 46 (2007) 8233.
6. J.L.C. Rowsell, and O.M. Yaghi, Review Metal–organic frameworks: a new class of porous materials. Microporous and Mesoporous Materials, 73 (2004) 14.
7. B. Moulton, and M.J. Zaworotko, Coordination polymers: toward functional transition metal sustained materials and supermolecules. Current Opinion In Solid State and Materials Science, 6 (2002) 117-123.
8. S.L. James, Metal-organic frameworks. Chemical Society Reviews, 32 (2003) 288.

9. B. Xiao, P.S. Wheatley, X. Zhao, A.J. Fletcher, S. Fox, A.G. Rossi, and R.E. Morris, High-capacity hydrogen and nitric oxide adsorption and storage in a metal−organic framework. Journal of the American Chemical Society, (2007) 1203-1209.
10. G. Ferey, C. Mellot-Draznieks, C. Serre, and F. Millange, Crystallized frameworks with giant pores: are there limits to the possible?. Accounds Chemical Resarch, 38 (2005) 217-225.
11. A.C. Tella, G. Mehlana, L.O. Alimi, and S.A.Z. Bourne, Solvent-free synthesis, characterization and solvent-vapor interaction of zinc(II) and copper(II) coordination polymers containing nitrogen-donor ligands. Zeitschrift für Anorganische und Allgemeine Chemie, 64 (2017) 523-530.
12. Z. Xu, Mechanics of metal-catecholate complexes: The roles of coordination state and metal types. Coordination Chemistry Reviews, 250 (2006) 2745
13. S. Ma and H.C. Zhou, Gas storage in porous metal–organic frameworks for clean energy applications. Chemical Communications, 46 (2010) 44-53.
14. Y.K. Hwang, D.Y. Hong, J.S. Chang, S.H. Jhung, Y.K. Seo, J. Kim, and G. Férey, Amine grafting on coordinatively unsaturated metal centres of MOFs: consequences for catalysis and metal encapsulation. Angewandte Chemie International Edition, 47 (2008) 4144-4148.
15. A.C. Tella, S.O. Owalude, C.A. Ojekanmi, and O.S. Oluwafemi, Synthesis of copper–isonicotinate metal–organic frameworks simply by mixing solid reactants and investigation of their adsorptive properties for the removal of the fluorescein dye. New Journal of Chemistry, 38 (2014) 4494-4500.
16. S. Kitagawa, R. Kitaura, and Noro, Functional porous coordination polymers. Angewandte Chemie International Edition, 43 (2004) 2334-2375.
17. G. Ferey, J. Cejka, H. van Bekkum, A. Corma, and F. Schuth, Safer nanoformulation for the next generation. Studues In Surface Science Catalysis, 168 (2007) 327-374.
18. R. Liu, T. Yu, Z. Shi, and Z. Wang, The preparation of metal–organic frameworks and their biomedical application. International Journal of Nanomedicine, 11 (2016) 1187-1200.
19. C. Serre, F. Millange, S. Surble, and G.A. Ferey, A route to the synthesis of trivalent transition-metal porous carboxylates with trimeric secondary building units. Angewandte Chemie International Edition, 43 (2004) 6286–
20. N.L. Rosi, J. Eckert, M. Eddaoudi, D.T. Vodak, J. Kim, M. O'Keeffe, and O.M. Yaghi, Hydrogen storage in microporous metal-organic frameworks. Science, 300 (2003) 1127-1129.
21. M.O. Rodrigues, M.V. de Paula, K.A. Wanderley, I.B. Vasconcelos, S. Alves, and T.A. Soares, Metal-organic frameworks for drug delivery and environmental remediation: a molecular docking approach. International Journal of Quantum Chemistry, 112 (2012) 3346-3355.
22. M. Abbasi, F. Saeed, and U. Rafique, Preparation of silver nanoparticles from synthetic and natural sources: remediation model for PAHs. Int. Symp. Adv. Mater. Sci. Eng. 60 (2013) 599.
23. M. Arshadi, S. Foroughifard, J.E. Gholtash, A. Abbaspourrad, Preparation of iron nanoparticles-loaded Spondias purpurea seed waste as an excellent adsorbent for removal of phosphate from synthetic and natural waters. Journal of Colloid and Interface Science 452 (2015) 69-77.
24. Z.Y. Liu, H.W. Bai, and D.D. Sun, Facile fabrication of porous chitosan/TiO2/Fe3O4 microspheres with multifunction for water purifications, New Journal of Chemistry 35 (2011) 137-140.
25. M. Hakimi, Structural and spectral characterization of a chromium(III) picolinate complex: Introducing a new redox reaction. Journal of the Korean Chemical Society 57 (2013) 721-725.
26. A.C. Tella, and J.A. Obaleye, Metal complexes as antibacterial agents: Synthesis, characterization and antibacterial activity of some 3d metal complexes of sulphadimidine. Orbital: The Electronic Journal of Chemistry (2010) 11-26.
27. A.C. Tella, U.B. Eke, A.Y. Isaac, and C.A. Ojekanmi, Mechanically induced solventless synthesis of cobalt and nickel complexes of cimetidine. Orbital: The Electronic Journal of Chemistry 3 (2011) 94-103.
28. A.C. Tella, M.D. Olawale, M. Neuburger, and J.A. Obaleye, Solvent-free synthesis, characterization and solvent-vapor interaction of zinc(II) and copper(II) coordination polymers containing nitrogen-donor ligands. Journal of Solid State Chemistry 255 (2017) 157-166.
29. Y. Rodriguez-Martin, C. Ruiz-Perez, J. Sanchiz, F. Lloret, and M. Julve, Crystal structures and magnetic properties of two- and three-dimensional malonato-bridged manganese(II) complexes. Inorganica Chimica Acta 318 (2001) 159-165.
30. D.C. Onwudiwe and P.A. Ajibade, Synthesis and characterization of metal complexes of N-alkyl-N-phenyl dithiocarbamates. Polyhedron 29 (2010) 1436.
31. D.C. Onwudiwe and P.A. Ajibade, Thermal studies of Zn(II), Cd(II) and Hg(II) complexes of some N-alkyl-N-phenyl-dithiocarbamates. International Journal of Molecular Sciences, 13 (2012) 9502-9513.
32. M. Hakimi, Structural and spectral characterization of a chromium(III) picolinate complex: Introducing a new redox reaction. Journal of the Korean Chemical Society, 57 (2013) 721-725.