The Solution Polymerization of Methyl Acrylate and Determination of The Chain Transfer Constant for Acetone

E. Pulat

The Solution Polymerization of Methyl Acrylate and Determination of The Chain Transfer Constant for Acetone

Abstract

The initiated polymerization of methyl acrylate is studied in the presence of carbon tetrachloride, chloroform, acetone and petroleum ether at 60 °C. Benzoyl peroxide was used as the initiator. The transfer constant for acetone has been found to be 2.3 X 10-5 at 60 ° C. Using the transfer constant value found by Gadkary and Kapur [3] at 80°C for the same solvent, we have also calculated the value of Etr-S - Ep and log (Atr-S /Ap ). By measurîng the rate of polymerization of methyl acrylate in bulk, at three diffe- rent temperatures^ the apparent activation energy of polymerization has been determined. From this we have calculated the activation energy of the termination reaction, since the activation energy Ed , for the decomposition of the initiator, and Ep , for the pro- pagation reaction are konown.

Keywords

References

Ankara Üniversitesi Communications, Series B: Chemistry and Chemical Engineering

Details

Primary Language

English

Subjects

Chemical Engineering

Journal Section

Research Article

Authors

E. Pulat This is me
Türkiye

Publication Date

January 1, 1968

Submission Date

January 1, 1968

Acceptance Date

-

Published in Issue

Year 1968 Volume: 15

IZ

https://izlik.org/JA62CC26UA

Cite

RIS / Bibtex

APA

Pulat, E. (1968). The Solution Polymerization of Methyl Acrylate and Determination of The Chain Transfer Constant for Acetone. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering, 15. https://izlik.org/JA62CC26UA

AMA

1.Pulat E. The Solution Polymerization of Methyl Acrylate and Determination of The Chain Transfer Constant for Acetone. Commun. Fac. Sci. Univ. Ank. Ser. B. 1968;15. https://izlik.org/JA62CC26UA

Chicago

Pulat, E. 1968. “The Solution Polymerization of Methyl Acrylate and Determination of The Chain Transfer Constant for Acetone”. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering 15 (January). https://izlik.org/JA62CC26UA.

EndNote

Pulat E (January 1, 1968) The Solution Polymerization of Methyl Acrylate and Determination of The Chain Transfer Constant for Acetone. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering 15

IEEE

[1]E. Pulat, “The Solution Polymerization of Methyl Acrylate and Determination of The Chain Transfer Constant for Acetone”, Commun. Fac. Sci. Univ. Ank. Ser. B, vol. 15, Jan. 1968, [Online]. Available: https://izlik.org/JA62CC26UA

ISNAD

Pulat, E. “The Solution Polymerization of Methyl Acrylate and Determination of The Chain Transfer Constant for Acetone”. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering 15 (January 1, 1968). https://izlik.org/JA62CC26UA.

JAMA

1.Pulat E. The Solution Polymerization of Methyl Acrylate and Determination of The Chain Transfer Constant for Acetone. Commun. Fac. Sci. Univ. Ank. Ser. B. 1968;15. Available at https://izlik.org/JA62CC26UA.

MLA

Pulat, E. “The Solution Polymerization of Methyl Acrylate and Determination of The Chain Transfer Constant for Acetone”. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering, vol. 15, Jan. 1968, https://izlik.org/JA62CC26UA.

Vancouver

1.E. Pulat. The Solution Polymerization of Methyl Acrylate and Determination of The Chain Transfer Constant for Acetone. Commun. Fac. Sci. Univ. Ank. Ser. B [Internet]. 1968 Jan. 1;15. Available from: https://izlik.org/JA62CC26UA