A New Method For Estimating the Relative pK Values of Amines and Alcohols
Abstract
Linear free energy relationships were established between reaction rate constants of alcohols and amines with ethyi magnesium bromide in diethyl ether at 25 °, and their pK values in terms of Bronsted equation, which are:
for alcohols, log k = — 0,09 pK + 0,93 (at 25 °C)
and for amines, log k = — 0,07 pK -J- 0,78 (at 25 °C)
From these equations, the relative pK values of amines and alcohols can be predic-’ ted by measuring their reaction rate constants with ethyi magnesium bromide in diethyl ether, at 25°C.
Keywords
References
- Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering
Details
Primary Language
English
Subjects
Chemical Engineering
Journal Section
Research Article
Authors
Celâl Tüzün
This is me
Türkiye
Publication Date
January 1, 1972
Submission Date
January 1, 1972
Acceptance Date
-
Published in Issue
Year 1970 Volume: 19
