A New Method For Estimating the Relative pK Values of Amines and Alcohols

Celâl Tüzün

A New Method For Estimating the Relative pK Values of Amines and Alcohols

Abstract

Linear free energy relationships were established between reaction rate constants of alcohols and amines with ethyi magnesium bromide in diethyl ether at 25 °, and their pK values in terms of Bronsted equation, which are: for alcohols, log k = — 0,09 pK + 0,93 (at 25 °C) and for amines, log k = — 0,07 pK -J- 0,78 (at 25 °C) From these equations, the relative pK values of amines and alcohols can be predic-’ ted by measuring their reaction rate constants with ethyi magnesium bromide in diethyl ether, at 25°C.

Keywords

Method, Estimating, Alcohols

References

Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering

Details

Primary Language

English

Subjects

Chemical Engineering

Journal Section

Research Article

Authors

Celâl Tüzün This is me
Türkiye

Publication Date

January 1, 1972

Submission Date

January 1, 1972

Acceptance Date

-

Published in Issue

Year 1972 Volume: 19

IZ

https://izlik.org/JA86XJ99DF

APA

Tüzün, C. (1972). A New Method For Estimating the Relative pK Values of Amines and Alcohols. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering, 19. https://izlik.org/JA86XJ99DF

AMA

1.Tüzün C. A New Method For Estimating the Relative pK Values of Amines and Alcohols. Commun. Fac. Sci. Univ. Ank. Ser. B. 1972;19. https://izlik.org/JA86XJ99DF

Chicago

Tüzün, Celâl. 1972. “A New Method For Estimating the Relative PK Values of Amines and Alcohols”. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering 19 (January). https://izlik.org/JA86XJ99DF.

EndNote

Tüzün C (January 1, 1972) A New Method For Estimating the Relative pK Values of Amines and Alcohols. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering 19

IEEE

[1]C. Tüzün, “A New Method For Estimating the Relative pK Values of Amines and Alcohols”, Commun. Fac. Sci. Univ. Ank. Ser. B, vol. 19, Jan. 1972, [Online]. Available: https://izlik.org/JA86XJ99DF

ISNAD

Tüzün, Celâl. “A New Method For Estimating the Relative PK Values of Amines and Alcohols”. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering 19 (January 1, 1972). https://izlik.org/JA86XJ99DF.

JAMA

1.Tüzün C. A New Method For Estimating the Relative pK Values of Amines and Alcohols. Commun. Fac. Sci. Univ. Ank. Ser. B. 1972;19. Available at https://izlik.org/JA86XJ99DF.

MLA

Tüzün, Celâl. “A New Method For Estimating the Relative PK Values of Amines and Alcohols”. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering, vol. 19, Jan. 1972, https://izlik.org/JA86XJ99DF.

Vancouver

1.Celâl Tüzün. A New Method For Estimating the Relative pK Values of Amines and Alcohols. Commun. Fac. Sci. Univ. Ank. Ser. B [Internet]. 1972 Jan. 1;19. Available from: https://izlik.org/JA86XJ99DF

Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering

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