EN
REACTİON OF ARYL CARBAMOYL ARYL HYDRAZİDOYL CHLO- RIDES WITH ACTIVATED NITRILE
Abstract
The carbanions of ethyl cyanoacetate, cyanoacetanilide, malononitrile and cyanoacetami- de react with aryl carbamoyl aryl hydrazidoyl chlorides (1 a-f) in ethanol at room temperature to give the corresponding substituted pyrazoles (3 a-f, 6 a-c, 7 a-e and 8 a). The structural as- signments have been made on the basis of elemental analysis, spectral data and the Chemical evidence for the resulting pyrazoles. On the other hand, aminoacetonitriie was reacted with (1 b) and 9 to give the corresponding substituted triazines (13 b) and quinolino 1, 2-f triazine derivative (12). The mechanism of the different reactions were discussed.
Keywords
References
- Reaction of aryl carbamoyl aryl hydrazidoyl chlorides with activated nitrile
Details
Primary Language
English
Subjects
Chemical Engineering
Journal Section
Research Article
Authors
M. K. A. Ibrahım
This is me
Türkiye
Publication Date
January 1, 1990
Submission Date
January 1, 1990
Acceptance Date
-
Published in Issue
Year 1970 Volume: 36
