Reaction Of Unsaturated ^-Bromo Phosphonite And a-Chloro Phosphonate With DiazoMethane And Its Derivatives

William I. Awad

doi:10.1501/Commub_0000000517

EN

Reaction Of Unsaturated ^-Bromo Phosphonite And a-Chloro Phosphonate With DiazoMethane And Its Derivatives

Abstract

Diethyl (2-bromo-l- phenyl, vinyl) phosphonite and diethyl (1-chloro-l-phenyl, vinyl) phosphonate react with diazomethane, diphenyldiazomethane, and phenylbenzoyldiazomet- hane. The reaction with diazomethane goes by 3 ' 2 “ 5 scheme of dipolar cycloaddition. The reaction of the phosphonite with diphenyldiazomethane goes by the 3-3-6 scheme, while in the case of phosphonate cleavage of C-P bond took place. However, the reaction of phospho-nate with pheriylbenzoyldiazomethane goes by 3 -- 2 — 5 scheme of 1, 3-dipolar cycloaddition with. the cleavage of C-P bond. .

Keywords

References

Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering

Details

Primary Language

English

Subjects

Chemical Engineering

Journal Section

Research Article

Authors

William I. Awad This is me
Türkiye

Publication Date

January 1, 1983

Submission Date

January 1, 1983

Acceptance Date

-

Published in Issue

Year 1983 Volume: 29

DOI

https://doi.org/10.1501/Commub_0000000517

IZ

https://izlik.org/JA49TA89PY

Cite

RIS / Bibtex

APA

Awad, W. I. (1983). Reaction Of Unsaturated ^-Bromo Phosphonite And a-Chloro Phosphonate With DiazoMethane And Its Derivatives. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering, 29. https://doi.org/10.1501/Commub_0000000517

AMA

1.Awad WI. Reaction Of Unsaturated ^-Bromo Phosphonite And a-Chloro Phosphonate With DiazoMethane And Its Derivatives. Commun. Fac. Sci. Univ. Ank. Ser. B. 1983;29. doi:10.1501/Commub_0000000517

Chicago

Awad, William I. 1983. “Reaction Of Unsaturated ^-Bromo Phosphonite And A-Chloro Phosphonate With DiazoMethane And Its Derivatives”. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering 29 (January). https://doi.org/10.1501/Commub_0000000517.

EndNote

Awad WI (January 1, 1983) Reaction Of Unsaturated ^-Bromo Phosphonite And a-Chloro Phosphonate With DiazoMethane And Its Derivatives. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering 29

IEEE

[1]W. I. Awad, “Reaction Of Unsaturated ^-Bromo Phosphonite And a-Chloro Phosphonate With DiazoMethane And Its Derivatives”, Commun. Fac. Sci. Univ. Ank. Ser. B, vol. 29, Jan. 1983, doi: 10.1501/Commub_0000000517.

ISNAD

Awad, William I. “Reaction Of Unsaturated ^-Bromo Phosphonite And A-Chloro Phosphonate With DiazoMethane And Its Derivatives”. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering 29 (January 1, 1983). https://doi.org/10.1501/Commub_0000000517.

JAMA

1.Awad WI. Reaction Of Unsaturated ^-Bromo Phosphonite And a-Chloro Phosphonate With DiazoMethane And Its Derivatives. Commun. Fac. Sci. Univ. Ank. Ser. B. 1983;29. doi:10.1501/Commub_0000000517.

MLA

Awad, William I. “Reaction Of Unsaturated ^-Bromo Phosphonite And A-Chloro Phosphonate With DiazoMethane And Its Derivatives”. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering, vol. 29, Jan. 1983, doi:10.1501/Commub_0000000517.

Vancouver

1.William I. Awad. Reaction Of Unsaturated ^-Bromo Phosphonite And a-Chloro Phosphonate With DiazoMethane And Its Derivatives. Commun. Fac. Sci. Univ. Ank. Ser. B. 1983 Jan. 1;29. doi:10.1501/Commub_0000000517