THE PRUİTT-BAGGETT CATALYST IN THE STEREOREGULAR PÖLYMERIZATION OF PROPYLENE OXIDE

Serpil Aksoy

doi:10.1501/Commub_0000000457

EN

THE PRUİTT-BAGGETT CATALYST IN THE STEREOREGULAR PÖLYMERIZATION OF PROPYLENE OXIDE

Abstract

The Pruitt-Baggett adduct (PBA) (MW = 438 gmol~3) which formed from the reacticn of FeCls with propylene oxide (PO) was hydrolysed in diethylether (ether) solution at different r = H2O/Fe mol ratios. The hydrolysates (PBH/r) which were insoluble in ether could be con- verted into catalytically active form (PBC/r) by a thermal treatment (baking). PBC/r (r < 1) was soluble in ether and in PO. PBC /r polymerized PO into a mixture of cyrstalline polymer and non-crystallizable oily polymer. It was found that the catalytic activity of PBC/r coıdd be varied by changing the hydrolysis conditions and the baking time.

Keywords

References

THE PRUİTT-BAGGETT CATALYST IN THE STEREOREGULAR PÖLYMERIZATION OF PROPYLENE OXIDE

Details

Primary Language

English

Subjects

Chemical Engineering

Journal Section

Research Article

Authors

Serpil Aksoy This is me
Türkiye

Publication Date

January 1, 1990

Submission Date

January 1, 1990

Acceptance Date

-

Published in Issue

Year 1990 Volume: 36

DOI

https://doi.org/10.1501/Commub_0000000457

IZ

https://izlik.org/JA65KR72FP

Cite

RIS / Bibtex

APA

Aksoy, S. (1990). THE PRUİTT-BAGGETT CATALYST IN THE STEREOREGULAR PÖLYMERIZATION OF PROPYLENE OXIDE. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering, 36. https://doi.org/10.1501/Commub_0000000457

AMA

1.Aksoy S. THE PRUİTT-BAGGETT CATALYST IN THE STEREOREGULAR PÖLYMERIZATION OF PROPYLENE OXIDE. Commun. Fac. Sci. Univ. Ank. Ser. B. 1990;36. doi:10.1501/Commub_0000000457

Chicago

Aksoy, Serpil. 1990. “THE PRUİTT-BAGGETT CATALYST IN THE STEREOREGULAR PÖLYMERIZATION OF PROPYLENE OXIDE”. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering 36 (January). https://doi.org/10.1501/Commub_0000000457.

EndNote

Aksoy S (January 1, 1990) THE PRUİTT-BAGGETT CATALYST IN THE STEREOREGULAR PÖLYMERIZATION OF PROPYLENE OXIDE. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering 36

IEEE

[1]S. Aksoy, “THE PRUİTT-BAGGETT CATALYST IN THE STEREOREGULAR PÖLYMERIZATION OF PROPYLENE OXIDE”, Commun. Fac. Sci. Univ. Ank. Ser. B, vol. 36, Jan. 1990, doi: 10.1501/Commub_0000000457.

ISNAD

Aksoy, Serpil. “THE PRUİTT-BAGGETT CATALYST IN THE STEREOREGULAR PÖLYMERIZATION OF PROPYLENE OXIDE”. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering 36 (January 1, 1990). https://doi.org/10.1501/Commub_0000000457.

JAMA

1.Aksoy S. THE PRUİTT-BAGGETT CATALYST IN THE STEREOREGULAR PÖLYMERIZATION OF PROPYLENE OXIDE. Commun. Fac. Sci. Univ. Ank. Ser. B. 1990;36. doi:10.1501/Commub_0000000457.

MLA

Aksoy, Serpil. “THE PRUİTT-BAGGETT CATALYST IN THE STEREOREGULAR PÖLYMERIZATION OF PROPYLENE OXIDE”. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering, vol. 36, Jan. 1990, doi:10.1501/Commub_0000000457.

Vancouver

1.Serpil Aksoy. THE PRUİTT-BAGGETT CATALYST IN THE STEREOREGULAR PÖLYMERIZATION OF PROPYLENE OXIDE. Commun. Fac. Sci. Univ. Ank. Ser. B. 1990 Jan. 1;36. doi:10.1501/Commub_0000000457