SOLVENT EFFECTS ON THE KINETICS OF THE ALKALINE CATALYSED HYDROLYSIS OF CYANOACETAMIDE

H. M. El-nader

doi:10.1501/Commub_0000000405

EN

SOLVENT EFFECTS ON THE KINETICS OF THE ALKALINE CATALYSED HYDROLYSIS OF CYANOACETAMIDE

Abstract

The rate of the alkaline catalysed hydrolysis of cyanoacetamide was investigated in the presence of ethanol and ethylene glycol up to 60 wt % in the temperature range 25 to 45+0.1°C The reaction rate decreased with the progressive addition of ethanol, while in case of ethylene glycol decreased up to 40 wt % then increased. The isocomposition and isodielectric energies of activation and the thermodynamic parameters of activation were calculated and discussed in terms of solvent effects. The influence of the dielectric constant of the solvent mixture on the reaction rate was discussed. A mechanism was proposed to account for the effect of the solvent on the reaction rate.

Keywords

References

SOLVENT EFFECTS ON THE KINETICS OF THE ALKALINE CATALYSED HYDROLYSIS OF CYANOACETAMIDE

Details

Primary Language

English

Subjects

Chemical Engineering

Journal Section

Research Article

Authors

H. M. El-nader This is me
Türkiye

Publication Date

January 1, 1995

Submission Date

January 1, 1995

Acceptance Date

-

Published in Issue

Year 1995 Volume: 41

DOI

https://doi.org/10.1501/Commub_0000000405

IZ

https://izlik.org/JA63UW62RE

Cite

RIS / Bibtex

APA

El-nader, H. M. (1995). SOLVENT EFFECTS ON THE KINETICS OF THE ALKALINE CATALYSED HYDROLYSIS OF CYANOACETAMIDE. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering, 41. https://doi.org/10.1501/Commub_0000000405

AMA

1.El-nader HM. SOLVENT EFFECTS ON THE KINETICS OF THE ALKALINE CATALYSED HYDROLYSIS OF CYANOACETAMIDE. Commun. Fac. Sci. Univ. Ank. Ser. B. 1995;41. doi:10.1501/Commub_0000000405

Chicago

El-nader, H. M. 1995. “SOLVENT EFFECTS ON THE KINETICS OF THE ALKALINE CATALYSED HYDROLYSIS OF CYANOACETAMIDE”. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering 41 (January). https://doi.org/10.1501/Commub_0000000405.

EndNote

El-nader HM (January 1, 1995) SOLVENT EFFECTS ON THE KINETICS OF THE ALKALINE CATALYSED HYDROLYSIS OF CYANOACETAMIDE. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering 41

IEEE

[1]H. M. El-nader, “SOLVENT EFFECTS ON THE KINETICS OF THE ALKALINE CATALYSED HYDROLYSIS OF CYANOACETAMIDE”, Commun. Fac. Sci. Univ. Ank. Ser. B, vol. 41, Jan. 1995, doi: 10.1501/Commub_0000000405.

ISNAD

El-nader, H. M. “SOLVENT EFFECTS ON THE KINETICS OF THE ALKALINE CATALYSED HYDROLYSIS OF CYANOACETAMIDE”. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering 41 (January 1, 1995). https://doi.org/10.1501/Commub_0000000405.

JAMA

1.El-nader HM. SOLVENT EFFECTS ON THE KINETICS OF THE ALKALINE CATALYSED HYDROLYSIS OF CYANOACETAMIDE. Commun. Fac. Sci. Univ. Ank. Ser. B. 1995;41. doi:10.1501/Commub_0000000405.

MLA

El-nader, H. M. “SOLVENT EFFECTS ON THE KINETICS OF THE ALKALINE CATALYSED HYDROLYSIS OF CYANOACETAMIDE”. Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering, vol. 41, Jan. 1995, doi:10.1501/Commub_0000000405.

Vancouver

1.H. M. El-nader. SOLVENT EFFECTS ON THE KINETICS OF THE ALKALINE CATALYSED HYDROLYSIS OF CYANOACETAMIDE. Commun. Fac. Sci. Univ. Ank. Ser. B. 1995 Jan. 1;41. doi:10.1501/Commub_0000000405