COORDINATION POLYMERS BASED ON MIXED CARBOXYLATE LIGANDS: SYNTHESIS AND THERMAL STUDIES

Year 2018, Volume: 60 Issue: 2, 1 - 16, 01.12.2018

O.vincent Adımula C.adedibu Tella C.ıfechukwu Udeaja T.abolaji Durodoye Amudat Lawal

https://doi.org/10.1501/commub_0000000558

Abstract

The synthesis of Co II , Cu II , Fe II and Zn II based coordination compounds using terephthalic acid BDC , tartaric acid DHB , and 4- hydroxybenzoic acid 4-HBA as ligands by a solvent-based and solvent-free methods were reported. Thermal studies of the complexes performed in the temperature range of 30 ºC-950 °C showed a 9.406% weight loss observed between 200 ºC-517 ºC for [Co DHB 4-HBA ] complex, and a 1.883 % weight loss observed between 80 ºC352.68 ºC for [Cu DHB 4-HBA ] complex.

Keywords

Metal complexes, Solvent-based method, Terephthalic acid, Thermal studies

COORDINATION POLYMERS BASED ON MIXED CARBOXYLATE LIGANDS: SYNTHESIS AND THERMAL STUDIES

Abstract

Co II , Cu II , Fe II ve Zn II iyonlarına dayalı koordinasyon bileşiklerinin çözücü içeren ve çözücü içermeyen yöntemler ile ligand olarak tereftalik asit BDC , tartarik asit DHB ve 4-hidroksibenzoik asit 4-HBA kullanılarak sentezi rapor edilmiştir. Komplekslerin 30 ºC-950 °C sıcaklık aralığında gerçekleştirilen termal çalışmaları, [Co DHB 4-HBA ] kompleksi için 200 ºC-517 ºC arasında gözlenen % 9.406 kütle kaybını ve [Cu DHB 4- HBA ] kompleksi için 80 ºC-352.68 ºC arasında gözlenen % 1.883 kütle kaybını göstermiştir.

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