STOBBE CONDENSATION INVOLVING DIETHYL-p,^-DIMETHYL- GLUTARATE II

Year 1989, Volume: 35 , 0 - 0, 01.01.1989

F.a. El-bassıouny

https://doi.org/10.1501/Commub_0000000472

Abstract

Diethy]-Ş,3-dimethylglutarate condenses with furan-2-aldehyde and thiophene-2-aI- dehyde in presence of sodium hydride to give predominantly the (Z)-half ester (la,b) together with small amounts of the (E)-half eseter (2a,b). The structure of the (E)-half esters was based on thier cyclization to cyclopenteno-furan and cyclopenteno-thiophene derivatives (5a,b) res- pectively, as well as, spectroscopic evidence.

Keywords

STOBBE CONDENSATION, INVOLVING, GLUTARATE

References

• Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering