H2SO4 initiated cationic polymerization of a - methylstyrene was carried out in chloro- jorm. The effect of temperature and monomer concentration on rate of polymerization and on the molecular weight of poly a-methylstyrene were studied. The total activation energy of the reaction was found to be - 32.6 kj mol-1,
Also assuming that the transfer reactions were negligeble, it was obtained that kp/ kt was equal to 2.64xl02.
Primary Language | English |
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Subjects | Chemical Engineering |
Journal Section | Research Article |
Authors | |
Publication Date | January 1, 1986 |
Published in Issue | Year 1986 Volume: 32 Issue: 01.02 |
Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering
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