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Regioselectivity Of The Reactions Of Aryl Carbamoyl -N- Aryl Nitrile (mines With Some Dipolarophiles.

Year 1983, Volume: 29 , 0 - 0, 01.01.1983
https://doi.org/10.1501/Commub_0000000224

Abstract

The regioselectivity of the cyloadditions of nitrile imines 1, derived from Aryl Carbamoyl hyd- razidoyl chlorides 2, to the C=C and C=S double bonds of the enol tautomer of benzoyl aceta- nilide, ethyl benzoylacetate, p-acetoacetotoluidide and the resonance stabilized thiocyanate anion respectively was investigated. The results indicate that the reactions studied are dipole- LUMO controlled and that the larger orbital coefficient in the LUMO of 1 is on the carbon atom.

References

  • Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering
Year 1983, Volume: 29 , 0 - 0, 01.01.1983
https://doi.org/10.1501/Commub_0000000224

Abstract

References

  • Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering
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Details

Primary Language English
Subjects Chemical Engineering
Journal Section Research Article
Authors

Mohamed Kamal Ahmad İbrahim This is me

Publication Date January 1, 1983
Published in Issue Year 1983 Volume: 29

Cite

Vancouver İbrahim MKA. Regioselectivity Of The Reactions Of Aryl Carbamoyl -N- Aryl Nitrile (mines With Some Dipolarophiles. Commun. Fac. Sci. Univ. Ank. Ser. B. 1983;29.

Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering

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