The regioselectivity of the cyloadditions of nitrile imines 1, derived from Aryl Carbamoyl hyd- razidoyl chlorides 2, to the C=C and C=S double bonds of the enol tautomer of benzoyl aceta- nilide, ethyl benzoylacetate, p-acetoacetotoluidide and the resonance stabilized thiocyanate anion respectively was investigated. The results indicate that the reactions studied are dipole- LUMO controlled and that the larger orbital coefficient in the LUMO of 1 is on the carbon atom.
Primary Language | English |
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Subjects | Chemical Engineering |
Journal Section | Research Article |
Authors | |
Publication Date | January 1, 1983 |
Published in Issue | Year 1983 Volume: 29 |
Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering
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