AND CHARACTERIZATION OF METAL COMPLEXES OF (1Z,2E)-N'-HYDROXY-2-(HYDROXYIMINO)-N-(p-TOLYL)ACETIMIDAMIDE LIGAND

Abstract

In this study, (1Z,2E)-N'-hydroxy-2-(hydroxyimino)-N-(p-tolyl)acetimidamide (H₂L) ligand was synthesized, which is reported in literature, and ligand constituted anti-chloroglyoxime (gly) and p-toluidin (ptol) was synthesized and its metal complexes with Fe(II) and Zn(II) were obtained. The structure of ligand has been proposed by using elemantal analysis, ¹H-NMR, ¹³C‑NMR, FT-IR, UV-Vis techniques. The structure of amorphous Fe(II) and Zn(II)complexes have been proposed by using elemantal analysis, ICP-OES, FT-IR, UV-Vis, magnetic susceptibility and molar conductivity techniques.

Keywords

• Glyoxime,Metal Complexes,p-Toluidine,Vic-Dioxime

(1Z, 2E)-N’-HİDROKSİL-2-HİDROKSİİMİNO-N-p-TOLİL-ASETAMİDİN LİGANDININ Fe(II) VE Zn(II) KOMPLEKSLERININ SENTEZI VE YAPILARININ AYDINLATILMASI

Abstract

Bu çalışmada anti-kloroglioksim (gly) ile p-toluidin (ptol) reaksiyonundan (1Z, 2E)-N’-hidroksil-2-hidroksiimino-N-p-tolil-asetamidin (H₂L) ligandı literatürde belirtildiği şekilde sentezlenmiştir. Daha sonra bu ligandının Fe(II) ve Zn(II) metal kompleksleri sentezlenmiştir. Ligandın yapısı elementel analiz, ¹H-NMR, ¹³C-NMR, FT-IR, UV-Vis metotları ile aydınlatılmıştır. Amorf halde elde edilen Fe(II) ve Zn(II) komplekslerinin yapıları ise elementel analiz, ICP-OES, FT-IR, UV-Vis, manyetik duyarlılık ve molar iletkenlik sonuçları dikkate alınarak önerilmiştir.

Keywords

• Glioksim,Metal Kompleksleri,p-Toluidin,Vic-Dioksim

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