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EMET - ESPEY BÖLGESİNDEKİ BORLU KİLLERDE ESER ELEMENT TAYİNİ

Year 2014, Issue: 033, 25 - 32, 15.04.2014

Abstract

Emet-Espey bölgesinde çeşitli zonlardan alınan Eti Maden işletmesinin atığı olan numunelerde eser elementlerin tayini yapılmıştır. Özellikle borlu kil numunelerinde bazı değerli eser elementlerin önemli miktarda olduğu gözlenmiştir. Teknolojideki hızlı değişim ve araştırma geliştirme çalışmalarının artması sonucunda lityum, rubidyum, sezyum ve titanyum vb. eser elementlerin önemi yıldan yıla artmaktadır. Bu elementlerden lityum, rubidyum ve sezyumun üretimine ya da kazanımına yönelik ülkemizde herhangi bir faaliyet yoktur. Titanyum mineralleri içeren yataklardan sistematik bir üretim yapılmadığı, ihtiyacın ithalatla karşılandığı bilinmektedir.

References

  • [1] Eti Maden İşletmeleri Genel Müdürlüğü, Bor Sektör Raporu, Mayıs (2012).
  • [2] M. Savaş, Emet Bor İşletme Müdürlüğü, teknik genel müdür yardımcısı, yazılı görüşme(2011).
  • [3] Desormeaux, Daniela, Economic activity and lithium demand: Lithium Supply & Markets 2013, 5th, Las Vegas, NV, January 29–30, presentation, 24 p(2013).
  • [4] FMC Corp., FMC lithium announces grand opening of new battery R&D facility: Philadelphia, PA, FMC Corp. press release, September 10. (Accessed October 5, 2008, via http://www.fmclithium.com/LinkClick.aspx link=ContentDocsNewsReleasesPressReleaseNewDryRoomSept2008FINAL.pdf&tabid=2699&mid=7500)(2008).
  • [5] Rockwood Holdings, Inc., Rockwood lithium announces global price increases for lithium salts: Princeton, NJ, Rockwood Holdings, Inc. press release, May 14. (Accessed June 11, 2012, at http:// www.rockwoodspecialties.com/rock_english/news/pr_2012_05a.asp.)(2012b).
  • [6] Rockwood Holdings, Inc., Rockwood lithium increases butyllithium prices: Princeton, NJ, Rockwood Holdings, Inc. press release, October 15. (Accessed October 19, 2012, at http://www.rockwoodspecialties.com/ rock_english/news/pr_2012_10b.asp.)(2012c).
  • [7] F.S. Wagner, Rubidium and rubidium compounds, in Kirk-Othmer encyclopedia of chemical technology (4th ed.): New York, Wiley&Sons, v.21, p. 591-600(1997).
  • [8] J.J. Norton, Lithium, cesium and rubidium-The rare alkali metals, in Brobst, D.A., and Pratt, W.P., eds., United States mineral resources: U.S. Geological Survey Professional Paper 820, p. 365-378(1973).
  • [9] Houston Lake Mining, Rare metals and their applications, accessed October 7, 2003, at URL://www.houston lakemining.com/properties/rare.html(2003).
  • [10] U.S. Geological Survey, Mineral Commodity Summaries, January (2005).
  • [11] U.S. Geological Survey, Mineral Commodity Summaries, January (2012).
  • [12] U.S. Geological Survey, Mineral Commodity Summaries, January (2013).
  • [13] S.İ Lefond., 'Titanium Minerals Industrial Minerals and Rocks' Vol.2, (1983).
  • [14] M Akser., B. İpekoğlu, 'Concentration and Characterization of Rutile From a Feldspar (Albite) Flotation Reject Stream a Laboratory Study' For presentation at the SME Annual Meeting Denver, Colarado, March 1-3, (1999).
  • [15] Industrial Minerals Dergisi, Ocak 1971- Mart 1995 Sayıları.
  • [16] P. Dorman, 'Titanium Minerals-Market Research and Profitability of Norvegian Deposits' Erzmetall 47, (1994).
  • [17] M. Sailer, “Lithium takes charge”, Industrial Minerals, s.37(2000).
  • [18] Y.Erdoğan, M. Aksu, A. Demirbaş, Y. Abalı, “Analyses of boronic ores and sludges and solubilities of boron minerals in CO2 saturated water resources, conservation and recycling”, 24,275-283(1998).
  • [19] C. Helvacı, H. Mordoğan, M. Çolak, I. Gündoğan, “Presence and distribution of lithium in borate deposits and some recent lake waters of West-central Turkey” International Geology Review, 46(2), 177-190(2004).
  • [20] J.J. Kennedy, The alkali metal cesium and some of its salts, Chem. Rev. 23, 157-163(1938).
  • [21] V. Anan’ev, M. Miklin, N. Nelyubina, M. Poroshina, Optical spectra of uv-irradiated rubidium and cesium nitrate ccrystals, J. Photochem. Photobiol. A 162, 67-72(2004).
  • [22] B. Jia, S. Harris, L.L. Lewis, J.P. Zhan, P.R. Brooks, Threshold behavior in electron-transfer collisions between rubidium atoms and CFCl or CFI molecules, J. Phys. Chem. A 109, 9213-9219(2005).
  • [23] K. Dash, S. Trangavel, S.C. Chaurasia J. Arunachalam, Determination of traces of rubidium in high purity cesium chloride by electrothermal atomic absorbtion spectrometry (ETAAS) using boric acid as a modifier, Anal. Chem. Acta 584, 210-214(2007).
  • [24] R.F. Cui, M.C. Hu, L.H. Jin, S.N. Li, Y.C. Jiang, S.P. Xia, Activity coefficient of rubidium cloride and cesium cloride in methanol-water mixtures and a comparative study of Pitzer and Pitzer-Simonson-Clegg models (298,15 K), Fluid Phase Equilib.251, 137-144(2007).
  • [25] "Türkiye Ağır Mineral Araştırması Projesi" MTA Müdürlüğü (devam ediyor).
  • [26] "Manisa-Gördes Bölgesi'nde Titanyum Minerallerinin Araştırılması Ön Etüdleri" İpekoğlu, B., Du Pont (ABD) Ortaklığı

DETERMINATION OF THE TRACE ELEMENTS IN BORON CLAYS OF EMET - ESPEY REGION

Year 2014, Issue: 033, 25 - 32, 15.04.2014

Abstract

The trace elements in boron clays which is the waste of Eti – Maden Factory in Espey area is determined. It is observed that particularly boron clay samples were contained significant amount of some valuable trace elements. Importance of lithium, rubidium, cesium, titanium etc.will increase that the result of rapid changing tecnology and increasing research and development activities from year to year. There is no activity that the production of these elements lithium, rubidium and cesium. It is known that there is not a systematical production of titanium bearing minerals and needs met by imports.

References

  • [1] Eti Maden İşletmeleri Genel Müdürlüğü, Bor Sektör Raporu, Mayıs (2012).
  • [2] M. Savaş, Emet Bor İşletme Müdürlüğü, teknik genel müdür yardımcısı, yazılı görüşme(2011).
  • [3] Desormeaux, Daniela, Economic activity and lithium demand: Lithium Supply & Markets 2013, 5th, Las Vegas, NV, January 29–30, presentation, 24 p(2013).
  • [4] FMC Corp., FMC lithium announces grand opening of new battery R&D facility: Philadelphia, PA, FMC Corp. press release, September 10. (Accessed October 5, 2008, via http://www.fmclithium.com/LinkClick.aspx link=ContentDocsNewsReleasesPressReleaseNewDryRoomSept2008FINAL.pdf&tabid=2699&mid=7500)(2008).
  • [5] Rockwood Holdings, Inc., Rockwood lithium announces global price increases for lithium salts: Princeton, NJ, Rockwood Holdings, Inc. press release, May 14. (Accessed June 11, 2012, at http:// www.rockwoodspecialties.com/rock_english/news/pr_2012_05a.asp.)(2012b).
  • [6] Rockwood Holdings, Inc., Rockwood lithium increases butyllithium prices: Princeton, NJ, Rockwood Holdings, Inc. press release, October 15. (Accessed October 19, 2012, at http://www.rockwoodspecialties.com/ rock_english/news/pr_2012_10b.asp.)(2012c).
  • [7] F.S. Wagner, Rubidium and rubidium compounds, in Kirk-Othmer encyclopedia of chemical technology (4th ed.): New York, Wiley&Sons, v.21, p. 591-600(1997).
  • [8] J.J. Norton, Lithium, cesium and rubidium-The rare alkali metals, in Brobst, D.A., and Pratt, W.P., eds., United States mineral resources: U.S. Geological Survey Professional Paper 820, p. 365-378(1973).
  • [9] Houston Lake Mining, Rare metals and their applications, accessed October 7, 2003, at URL://www.houston lakemining.com/properties/rare.html(2003).
  • [10] U.S. Geological Survey, Mineral Commodity Summaries, January (2005).
  • [11] U.S. Geological Survey, Mineral Commodity Summaries, January (2012).
  • [12] U.S. Geological Survey, Mineral Commodity Summaries, January (2013).
  • [13] S.İ Lefond., 'Titanium Minerals Industrial Minerals and Rocks' Vol.2, (1983).
  • [14] M Akser., B. İpekoğlu, 'Concentration and Characterization of Rutile From a Feldspar (Albite) Flotation Reject Stream a Laboratory Study' For presentation at the SME Annual Meeting Denver, Colarado, March 1-3, (1999).
  • [15] Industrial Minerals Dergisi, Ocak 1971- Mart 1995 Sayıları.
  • [16] P. Dorman, 'Titanium Minerals-Market Research and Profitability of Norvegian Deposits' Erzmetall 47, (1994).
  • [17] M. Sailer, “Lithium takes charge”, Industrial Minerals, s.37(2000).
  • [18] Y.Erdoğan, M. Aksu, A. Demirbaş, Y. Abalı, “Analyses of boronic ores and sludges and solubilities of boron minerals in CO2 saturated water resources, conservation and recycling”, 24,275-283(1998).
  • [19] C. Helvacı, H. Mordoğan, M. Çolak, I. Gündoğan, “Presence and distribution of lithium in borate deposits and some recent lake waters of West-central Turkey” International Geology Review, 46(2), 177-190(2004).
  • [20] J.J. Kennedy, The alkali metal cesium and some of its salts, Chem. Rev. 23, 157-163(1938).
  • [21] V. Anan’ev, M. Miklin, N. Nelyubina, M. Poroshina, Optical spectra of uv-irradiated rubidium and cesium nitrate ccrystals, J. Photochem. Photobiol. A 162, 67-72(2004).
  • [22] B. Jia, S. Harris, L.L. Lewis, J.P. Zhan, P.R. Brooks, Threshold behavior in electron-transfer collisions between rubidium atoms and CFCl or CFI molecules, J. Phys. Chem. A 109, 9213-9219(2005).
  • [23] K. Dash, S. Trangavel, S.C. Chaurasia J. Arunachalam, Determination of traces of rubidium in high purity cesium chloride by electrothermal atomic absorbtion spectrometry (ETAAS) using boric acid as a modifier, Anal. Chem. Acta 584, 210-214(2007).
  • [24] R.F. Cui, M.C. Hu, L.H. Jin, S.N. Li, Y.C. Jiang, S.P. Xia, Activity coefficient of rubidium cloride and cesium cloride in methanol-water mixtures and a comparative study of Pitzer and Pitzer-Simonson-Clegg models (298,15 K), Fluid Phase Equilib.251, 137-144(2007).
  • [25] "Türkiye Ağır Mineral Araştırması Projesi" MTA Müdürlüğü (devam ediyor).
  • [26] "Manisa-Gördes Bölgesi'nde Titanyum Minerallerinin Araştırılması Ön Etüdleri" İpekoğlu, B., Du Pont (ABD) Ortaklığı
There are 26 citations in total.

Details

Primary Language Turkish
Subjects Engineering
Journal Section Articles
Authors

Bengü Ertan This is me

Yunus Erdoğan This is me

Publication Date April 15, 2014
Published in Issue Year 2014 Issue: 033

Cite

APA Ertan, B., & Erdoğan, Y. (2014). EMET - ESPEY BÖLGESİNDEKİ BORLU KİLLERDE ESER ELEMENT TAYİNİ. Journal of Science and Technology of Dumlupınar University(033), 25-32.

HAZİRAN 2020'den itibaren Journal of Scientific Reports-A adı altında ingilizce olarak yayın hayatına devam edecektir.